Separating hyperfine from spin-orbit interactions in organic semiconductors by multi-octave magnetic resonance using coplanar waveguide microresonators

Joshi, G.; Miller, R.; Ogden, L.; Kavand, M.; Jamali, S.; Ambal, K.; Malissa, H.; Venkatesh, S.; Schurig, D.; Lupton, J. M.

doi:10.1063/1.4960158

Title: Separating hyperfine from spin-orbit interactions in organic semiconductors by multi-octave magnetic resonance using coplanar waveguide microresonators

Journal Article · Mon Sep 05 00:00:00 EDT 2016 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4960158· OSTI ID:22594299

Joshi, G.; Miller, R.; Ogden, L.; Kavand, M.; Jamali, S.; Ambal, K.; Malissa, H.; Venkatesh, S.; Schurig, D. ^[1]; Lupton, J. M. ^[2]

Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, Utah 84112 (United States)
Department of Physics and Astronomy, University of Utah, Salt Lake City, Utah 84112 (United States)

Separating the influence of hyperfine from spin-orbit interactions in spin-dependent carrier recombination and dissociation processes necessitates magnetic resonance spectroscopy over a wide range of frequencies. We have designed compact and versatile coplanar waveguide resonators for continuous-wave electrically detected magnetic resonance and tested these on organic light-emitting diodes. By exploiting both the fundamental and higher-harmonic modes of the resonators, we cover almost five octaves in resonance frequency within a single setup. The measurements with a common π-conjugated polymer as the active material reveal small but non-negligible effects of spin-orbit interactions, which give rise to a broadening of the magnetic resonance spectrum with increasing frequency.

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OSTI ID:: 22594299

Journal Information:: Applied Physics Letters, Vol. 109, Issue 10; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951

Country of Publication:: United States

Language:: English

References (30)

Optically detected magnetic resonance studies of luminescence-quenching processes in π-conjugated materials and organic light-emitting devices Shinar, J. Laser & Photonics Reviews, Vol. 6, Issue 6 https://doi.org/10.1002/lpor.201100026	journal	April 2012
Broadband electrically detected magnetic resonance using adiabatic pulses Hrubesch, F. M.; Braunbeck, G.; Voss, A. Journal of Magnetic Resonance, Vol. 254 https://doi.org/10.1016/j.jmr.2015.02.010	journal	May 2015
A broadband superconducting detector suitable for use in large arrays Day, Peter K.; LeDuc, Henry G.; Mazin, Benjamin A. Nature, Vol. 425, Issue 6960 https://doi.org/10.1038/nature02037	journal	October 2003
Strong coupling of a single photon to a superconducting qubit using circuit quantum electrodynamics Wallraff, A.; Schuster, D. I.; Blais, A. Nature, Vol. 431, Issue 7005 https://doi.org/10.1038/nature02851	journal	September 2004
Superconducting quantum bits Clarke, John; Wilhelm, Frank K. Nature, Vol. 453, Issue 7198 https://doi.org/10.1038/nature07128	journal	June 2008
Probing long-range carrier-pair spin–spin interactions in a conjugated polymer by detuning of electrically detected spin beating van Schooten, Kipp J.; Baird, Douglas L.; Limes, Mark E. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7688	journal	April 2015
Spin-dependent recombination probed through the dielectric polarizability Bayliss, Sam L.; Greenham, Neil C.; Friend, Richard H. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9534	journal	October 2015
Magnetoresistance in organic semiconductors Lupton, John M.; Boehme, Christoph Nature Materials, Vol. 7, Issue 8 https://doi.org/10.1038/nmat2248	journal	August 2008
The spin-Dicke effect in OLED magnetoresistance Waters, D. P.; Joshi, G.; Kavand, M. Nature Physics, Vol. 11, Issue 11 https://doi.org/10.1038/nphys3453	journal	September 2015
Spin-locking in low-frequency reaction yield detected magnetic resonance Wedge, C. J.; Lau, Jason C. S.; Ferguson, Kelly-Anne Physical Chemistry Chemical Physics, Vol. 15, Issue 38 https://doi.org/10.1039/c3cp52019f	journal	January 2013
Modulation Effects in Magnetic Resonance: Widths and Amplitudes for Lorentzian and Gaussian Lines Smith, George W. Journal of Applied Physics, Vol. 35, Issue 4 https://doi.org/10.1063/1.1713596	journal	April 1964
Coplanar waveguide resonators for circuit quantum electrodynamics Göppl, M.; Fragner, A.; Baur, M. Journal of Applied Physics, Vol. 104, Issue 11 https://doi.org/10.1063/1.3010859	journal	December 2008
Superconducting coplanar waveguide resonators for low temperature pulsed electron spin resonance spectroscopy Malissa, H.; Schuster, D. I.; Tyryshkin, A. M. Review of Scientific Instruments, Vol. 84, Issue 2 https://doi.org/10.1063/1.4792205	journal	February 2013
Fast, low-power manipulation of spin ensembles in superconducting microresonators Sigillito, A. J.; Malissa, H.; Tyryshkin, A. M. Applied Physics Letters, Vol. 104, Issue 22 https://doi.org/10.1063/1.4881613	journal	June 2014
Polaron-pair generation in poly(phenylene vinylenes) Frankevich, E. L.; Lymarev, A. A.; Sokolik, I. Physical Review B, Vol. 46, Issue 15 https://doi.org/10.1103/physrevb.46.9320	journal	October 1992
Theory of time-domain measurement of spin-dependent recombination with pulsed electrically detected magnetic resonance Boehme, Christoph; Lips, Klaus Physical Review B, Vol. 68, Issue 24 https://doi.org/10.1103/physrevb.68.245105	journal	December 2003
Electrical detection and magnetic-field control of spin states in phosphorus-doped silicon Morishita, H.; Vlasenko, L. S.; Tanaka, H. Physical Review B, Vol. 80, Issue 20 https://doi.org/10.1103/physrevb.80.205206	journal	November 2009
Spin-dependent dynamics of polaron pairs in organic semiconductors McCamey, D. R.; Lee, S. -Y.; Paik, S. -Y. Physical Review B, Vol. 82, Issue 12 https://doi.org/10.1103/physrevb.82.125206	journal	September 2010
Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating Baker, W. J.; McCamey, D. R.; van Schooten, K. J. Physical Review B, Vol. 84, Issue 16 https://doi.org/10.1103/physrevb.84.165205	journal	October 2011
Modulation frequency dependence of continuous-wave optically/electrically detected magnetic resonance Lee, Sang-Yun; Paik, Seoyoung; McCamey, Dane R. Physical Review B, Vol. 86, Issue 11 https://doi.org/10.1103/physrevb.86.115204	journal	September 2012
Investigating the influence of traps on organic magnetoresistance by molecular doping Cox, M.; van der Heijden, E. H. M.; Janssen, P. Physical Review B, Vol. 89, Issue 8 https://doi.org/10.1103/physrevb.89.085201	journal	February 2014
Hyperfine-Field-Mediated Spin Beating in Electrostatically Bound Charge Carrier Pairs McCamey, D. R.; van Schooten, K. J.; Baker, W. J. Physical Review Letters, Vol. 104, Issue 1, Article No. 017601 https://doi.org/10.1103/PhysRevLett.104.017601	journal	January 2010
Importance of Spin-Orbit Interaction for the Electron Spin Relaxation in Organic Semiconductors Nuccio, L.; Willis, M.; Schulz, L. Physical Review Letters, Vol. 110, Issue 21 https://doi.org/10.1103/PhysRevLett.110.216602	journal	May 2013
Bootstrap Methods: Another Look at the Jackknife Efron, B. The Annals of Statistics, Vol. 7, Issue 1 https://doi.org/10.1214/aos/1176344552	journal	January 1979
Magnetic Field Dependence of the Geminate Recombination of Radical Ion Pairs in Polar Solvents Schulten, K.; Staerk, H.; Weller, A. Zeitschrift für Physikalische Chemie, Vol. 101, Issue 1-6 https://doi.org/10.1524/zpch.1976.101.1-6.371	journal	September 1976
Robust absolute magnetometry with organic thin-film devices Baker, W. J.; Ambal, K.; Waters, D. P. Universität Regensburg https://doi.org/10.5283/epub.26688	text	January 2012
Robust absolute magnetometry with organic thin-film devices Baker, W. J.; Ambal, K.; Waters, D. P. Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1895	journal	January 2012
Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating Baker, W. J.; McCamey, D. R.; van Schooten, K. J. Universität Regensburg https://doi.org/10.5283/epub.26708	text	January 2011
Coplanar Waveguide Resonators for Circuit Quantum Electrodynamics Göppl, M.; Fragner, A.; Baur, M. arXiv https://doi.org/10.48550/arxiv.0807.4094	text	January 2008
Broadband Electrically Detected Magnetic Resonance Using Adiabatic Pulses Hrubesch, F. M.; Braunbeck, G.; Voss, A. arXiv https://doi.org/10.48550/arxiv.1412.0842	text	January 2014

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Title: Separating hyperfine from spin-orbit interactions in organic semiconductors by multi-octave magnetic resonance using coplanar waveguide microresonators

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