Enhanced optophysical properties of poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3] thiadiazol-4,8-diyl)] via addition of TiO{sub 2} nanoparticles

Journal Article · Fri Sep 25 00:00:00 EDT 2015 · AIP Conference Proceedings

DOI:https://doi.org/10.1063/1.4931266· OSTI ID:22488976

Fuzi, Siti Aishah Ahmad, E-mail: [e-mail]; Jumali, Mohammad Hafizuddin Hj, E-mail: [e-mail]; Al-Asbahi, Bandar Ali Abdulqader, E-mail: [e-mail] ^[1]

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1. School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor. Malaysia (Malaysia)

This work investigated the effect on 5 wt% addition of TiO{sub 2} nanoparticles (NPs) on the optical absorption characteristics of Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3] thiadiazol-4,8-diyl)] (F8BT). Both materials were mixed using solution blending method and then spin coated onto ITO-coated glass substrate at 1000 rpm for 30s. The optical properties of the nanocomposite were determined using UV-Vis spectroscopy. Compares to pristine film, the absorption peak of the nanocomposite film improved and shifted to longer wavelength indicating reduction in the direct and indirect band gaps. Better optophysical properties of F8BT/TiO{sub 2} nanocomposites is believed due to compatible band structures and efficient charge trapping effect displayed by the NPs.

• OSTI ID: 22488976
• Journal Information: AIP Conference Proceedings, Vol. 1678, Issue 1; Conference: Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2015 Postgraduate Colloquium, Selangor (Malaysia), 15-16 Apr 2015; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
• Country of Publication: United States
• Language: English

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
ABSORPTION
ABSORPTION SPECTROSCOPY
COMPARATIVE EVALUATIONS
DIAZO COMPOUNDS
ELECTRONIC STRUCTURE
ENERGY GAP
FILMS
GLASS
INDIUM COMPOUNDS
NANOCOMPOSITES
NANOPARTICLES
OPTICAL PROPERTIES
ORGANIC POLYMERS
REDUCTION
SOLUTIONS
SPIN
SUBSTRATES
TIN OXIDES
TITANIUM OXIDES
TRAPPING