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Title: Long-lived coherences: Improved dispersion in the frequency domain using continuous-wave and reduced-power windowed sustaining irradiation

Long-lived coherences (LLC’s) are detectable magnetisation modes with favourable relaxation times that translate as sharp resonances upon Fourier transform. The frequency domain of LLC's was previously limited to the range of J-couplings within pairs of homonuclear spins. LLC evolution at high magnetic fields needs to be sustained by radio-frequency irradiation. We show that LLC-based spectral dispersion can be extended beyond the J-couplings domain using adapted carrier offsets and introduce a new reduced-power sustaining method to preserve LLC's within the required range of offsets. Spectral resolution is enhanced as the natively narrow lines of LLC's are further dispersed, making them potential probes for the study of biomolecules featuring strong resonance overlap and for media where NMR spectroscopy is commonly hindered by line broadening.
Authors:
; ; ; ;  [1]
  1. Laboratoire de Chimie et Biochimie Toxicologiques et Pharmacologiques UMR-8601, Université Paris Descartes - CNRS, PRES Paris Sorbonne Cité, 75006 Paris (France)
Publication Date:
OSTI Identifier:
22419990
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 141; Journal Issue: 5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COUPLINGS; DISPERSIONS; FOURIER TRANSFORMATION; IRRADIATION; LINE BROADENING; MAGNETIC FIELDS; MAGNETIZATION; NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY; SPIN