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Title: IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu)

This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1more » of the volume.« less
Authors:
 [1] ;  [2] ;  [3]
  1. Institute of Nuclear Chemistry and Technology, 03195 Warszawa (Poland)
  2. Department of Chemistry, University of Warsaw, 02093 Warszawa (Poland)
  3. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China)
Publication Date:
OSTI Identifier:
22413364
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Physical and Chemical Reference Data; Journal Volume: 44; Journal Issue: 2; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; AQUEOUS SOLUTIONS; EQUILIBRIUM; FLUORIDES; MIXED SOLVENTS; NOBELIUM COMPLEXES; PH VALUE; SALTS; SOLIDS; SOLUBILITY; TEMPERATURE DEPENDENCE; TERBIUM FLUORIDES; VALENCE; WATER; YTTERBIUM FLUORIDES