skip to main content

SciTech ConnectSciTech Connect

Title: Magnetic properties of the Nd{sub 0.95}Dy{sub 0.05}Fe{sub 3}(BO{sub 3}){sub 4} ferroborate with small substitution in the rare-earth element subsystem

The magnetic properties of a substituted Nd{sub 0.95}Dy{sub 0.05}Fe{sub 3}(BO{sub 3}){sub 4} ferroborate single crystal with competing Nd-Fe and Dy-Fe exchange interactions are studied experimentally and theoretically. A spontaneous spin-reorientation transition is detected near T = 4.3 K, and anomalies are observed in the low-temperature magnetization curves along trigonal axis c and in basal plane ab. The measured properties and the detected effects are interpreted in terms of a general theoretical approach, which is based on the molecular field approximation and crystal field calculations for a rare-earth ion. The experimental temperature dependences of the initial magnetic susceptibility in the range 2–300 K, the anomalies in the magnetization curves for B ‖ c and B ⊥ c in fields up to 1.5 T, and the field and temperature dependences of magnetization in fields up to 9 T are described. The effect of small substitution in the rare-earth subsystem on the magnetic properties is analyzed. The crystal field parameters and the parameters of the R-Fe and Fe-Fe exchange interactions are determined from the experimental data.
Authors:
;  [1] ; ;  [2]
  1. Bryansk State Technical University (Russian Federation)
  2. Russian Academy of Sciences, Kirensky Institute of Physics, Siberian Branch (Russian Federation)
Publication Date:
OSTI Identifier:
22309124
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Experimental and Theoretical Physics; Journal Volume: 117; Journal Issue: 5; Other Information: Copyright (c) 2013 Pleiades Publishing, Inc.; http://www.springer-ny.com; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; BORATES; CRYSTAL FIELD; DYSPROSIUM COMPOUNDS; EXCHANGE INTERACTIONS; EXPERIMENTAL DATA; IRON COMPOUNDS; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION; MONOCRYSTALS; NEODYMIUM COMPOUNDS; RARE EARTHS; SPIN ORIENTATION