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Title: Ion-modulated nonlinear electronic transport in carbon nanotube bundle/RbAg{sub 4}I{sub 5} thin film composite nanostructures

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4861728· OSTI ID:22275673
 [1];  [2];  [3];  [1]
  1. State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China)
  2. Institute of Applied Physics and Computational Mathematics, P.O. Box 8009(28), Beijing 100088 (China)
  3. Key Laboratory for Advanced Materials Processing Technology of Education Ministry, Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China)

We have explored the ion-modulated electronic transport properties of mixed ionic-electronic conductor (MIEC) composite nanostructures made of superionic conductor RbAg{sub 4}I{sub 5} films and carbon nanotube (CNT) bundle spiderwebs. Our experimental and theoretical studies indicate that the formation of ion-electron bound states (IEBSs) leads to strong ion-electron interference effect and interesting electronic transport of CNT, such as nonlinear current-voltage (I–V) characteristics and novel temperature dependence of the current. With increasing temperature, the hybrid nanostructures show rich phases with different dependence of current on temperature, which is related to the structural phase transition of RbAg{sub 4}I{sub 5} and the transition of dissociation of IEBSs. The ion-modulation of the electric conductivity in such MIEC composite nanostructures with great tunability has been used to design new ionic-electronic composite nano-devices with function like field effect transistor.

OSTI ID:
22275673
Journal Information:
Journal of Applied Physics, Vol. 115, Issue 4; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English