Structural investigation of phosphate - bismuth glasses with vanadium
- Babes-Bolyai University, Faculty of Physics, Kogalniceanu 1, 400084 Cluj-Napoca (Romania)
- Iuliu Hatieganu University of Medicine and Pharmacy, Biophysics Department, Faculty of Pharmacy, RO-400023 Cluj-Napoca (Romania)
- National Institute for Research and Development of Isotopic and Molecular Technologies, RO-400293 Cluj-Napoca (Romania)
The xV{sub 2}O{sub 5}(1−dx)[0.5P{sub 2}O{sub 5}⋅0.5Bi{sub 2}O{sub 3}] glass system with 0 ≤ x ≤ 50 mol% is investigated by IR and Raman spectroscopy. Both P{sub 2}O{sub 5} and Bi{sub 2}O{sub 3} oxides are known as network formers, but Bi{sub 2}O{sub 3} is an unconventional one. At low content of vanadium oxide (x ≤ 5 mol%), both IR and Raman spectra are dominated by vibration bands characteristics to structural groups of phosphate and bismuthate lattices. Due to the network modifier role, vanadium oxide acts mainly on the Bi{sub 2}O{sub 3} network allowing the phosphate groups to impose their characteristics absorption bands in spectra. These bands are strongly reduced for x ≥ 20 mol% due to the phosphate network depolymerization and the appearance of new vibrations characteristic to P-O-V, Bi-O-V and V-O-V groups showing the network former role of V{sub 2}O{sub 5}.
- OSTI ID:
- 22257171
- Journal Information:
- AIP Conference Proceedings, Vol. 1565, Issue 1; Conference: PIM 2013: International conference on processes in isotopes and molecules, Cluj Napoca (Romania), 25-27 Sep 2013; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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