skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: KETENE FORMATION IN INTERSTELLAR ICES: A LABORATORY STUDY

Journal Article · · Astrophysical Journal

The formation of ketene (H{sub 2}CCO, ethenone) in polar and apolar ices was studied with in situ 0.8 MeV proton irradiation, far-UV photolysis, and infrared spectroscopic analyses at 10-20 K. Using isotopically enriched reagents, unequivocal evidence was obtained for ketene synthesis in H{sub 2}O-rich and CO{sub 2}-rich ices, and several reaction products were identified. Results from scavenging experiments suggested that ketene was formed by free-radical pathways, as opposed to acid-base processes or redox reactions. Finally, we use our results to draw conclusions about the formation and stability of ketene in the interstellar medium.

OSTI ID:
22131011
Journal Information:
Astrophysical Journal, Vol. 773, Issue 2; Other Information: Country of input: International Atomic Energy Agency (IAEA); ISSN 0004-637X
Country of Publication:
United States
Language:
English