Synthesis and X-ray structure analysis of a new binuclear Schiff base Co(II) complex with the ligand N,N'-bis(3-methoxysalicylidene)-1,4-butanediamine

Journal Article · Tue Dec 15 00:00:00 EST 2009 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774509070049· OSTI ID:22051275

Nasr-Esfahani, M ^[1]

---

1. Islamic Azad University, Najafabad Branch, Department of Materials Science and Engineering (Iran, Islamic Republic of)

The title binuclear complex, tris[N,N-bis(3-methoxysalicylidene)-1,4-diaminobutane] dicobalt(II), C{sub 60}H{sub 70}Co{sub 2}N{sub 6}O{sub 15}, was prepared by the reaction of the tetradentate Schiff base ligand bis(3-methoxysalicylidene)-1,4-diaminobutane and Co(CH{sub 3}COO){sub 2} . 4H{sub 2}O in a ethanol solution and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two Co(II) ions are bridged by one N{sup 0},N'-bis(3-methoxysalicylidene)-1,4-diaminobutane. The two Co(II) ions, have two distorted octahedral coordination involving two O and two N atoms.

• OSTI ID: 22051275
• Journal Information: Crystallography Reports, Vol. 54, Issue 7; Other Information: Copyright (c) 2009 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
COBALT COMPLEXES
COBALT IONS
ETHANOL
LIGANDS
MONOCRYSTALS
PUTRESCINE
SCHIFF BASES
SYNTHESIS
X-RAY DIFFRACTION