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Title: Proton in SRF Niobium

Journal Article · · AIP Conference Proceedings
DOI:https://doi.org/10.1063/1.3580646· OSTI ID:21516671
 [1]
  1. Casting Analysis Corp, Weyers Cave, VA. 24486 (United States)

Hydrogen is a difficult impurity to physically deal with in superconducting radio frequency (SRF) niobium, therefore, its properties in the metals should be well understood to allow the metal's superconducting properties to be optimized for minimum loss in the construction of resonant accelerator cavities. It is known that hydrogen is a paramagnetic impurity in niobium from NMR studies. This paramagnetism and its effect on superconducting properties are important to understand. To that end analytical induction measurements aimed at isolating the magnetic properties of hydrogen in SRF niobium are introduced along with optical reflection spectroscopy which is also sensitive to the presence of hydrogen. From the variety, magnitude and rapid kinetics found in the optical and magnetic properties of niobium contaminated with hydrogen forced a search for an atomic model. This yielded quantum mechanical description that correctly generates the activation energy for diffusion of the proton and its isotopes not only in niobium but the remaining metals for which data is available. This interpretation provides a frame work for understanding the individual and collective behavior of protons in metals.

OSTI ID:
21516671
Journal Information:
AIP Conference Proceedings, Vol. 1352, Issue 1; Conference: 1. international symposium on the superconducting science and technology of ingot niobium, Newport News, VA (United States), 22-24 Sep 2010; Other Information: DOI: 10.1063/1.3580646; (c) 2011 American Institute of Physics; ISSN 0094-243X
Country of Publication:
United States
Language:
English