Evaluation of reaction mechanism of coal-metal oxide interactions in chemical-looping combustion

Journal Article · Mon Nov 15 00:00:00 EST 2010 · Combustion and Flame

DOI:https://doi.org/10.1016/J.COMBUSTFLAME.2010.06.008· OSTI ID:21379825

Siriwardane, Ranjani; Richards, George; Poston, James ^[1]; Tian, Hanjing; Miller, Duane; Simonyi, Thomas ^[1]

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1. US Department of Energy, National Energy Technology Laboratory, 3610 Collins Ferry Road, P.O. Box 880, Morgantown, WV 26507-0880 (United States)

The knowledge of reaction mechanism is very important in designing reactors for chemical-looping combustion (CLC) of coal. Recent CLC studies have considered the more technically difficult problem of reactions between abundant solid fuels (i.e. coal and waste streams) and solid metal oxides. A definitive reaction mechanism has not been reported for CLC reaction of solid fuels. It has often been assumed that the solid/solid reaction is slow and therefore requires that reactions be conducted at temperatures high enough to gasify the solid fuel, or decompose the metal oxide. In contrast, data presented in this paper demonstrates that solid/solid reactions can be completed at much lower temperatures, with rates that are technically useful as long as adequate fuel/metal oxide contact is achieved. Density functional theory (DFT) simulations as well as experimental techniques such as thermo-gravimetric analysis (TGA), flow reactor studies, in situ X-ray photo electron spectroscopy (XPS), in situ X-ray diffraction (XRD) and scanning electron microscopy (SEM) are used to evaluate how the proximal interaction between solid phases proceeds. The data indicate that carbon induces the Cu-O bond breaking process to initiate the combustion of carbon at temperatures significantly lower than the spontaneous decomposition temperature of CuO, and the type of reducing medium in the vicinity of the metal oxide influences the temperature at which the oxygen release from the metal oxide takes place. Surface melting of Cu and wetting of carbon may contribute to the solid-solid contacts necessary for the reaction. (author)

• OSTI ID: 21379825
• Journal Information: Combustion and Flame, Vol. 157, Issue 11; Other Information: Elsevier Ltd. All rights reserved; ISSN 0010-2180
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON DIOXIDE
COPPER OXIDES
COAL
COMBUSTION
COPPER
COMBUSTION KINETICS
THERMAL GRAVIMETRIC ANALYSIS
X-RAY PHOTOELECTRON SPECTROSCOPY
X-RAY DIFFRACTION
CARBON
SCANNING ELECTRON MICROSCOPY
DENSITY FUNCTIONAL METHOD
OXYGEN
TEMPERATURE RANGE 0400-1000 K
EVALUATION
MELTING
SIMULATION
SURFACES
CHEMICAL BONDS
Chemical-looping combustion