Electroless (autocatalytic) nickel-cobalt thin films as solar control coatings
- Central Electrochemical Research Inst., Tamilnadu (India)
- Alagappa Univ., Tamilnadu (India). Dept. of Physics
This paper describes the deposition of nickel-cobalt-phosphorus coatings by the electroless deposition technique for use as solar control coatings in architectural glazing of buildings. Electroless deposition is characterized by the autocatalytic deposition of a metal/alloy from an aqueous solution of its ions by interaction with a chemical reducing agent. The reducing agent provides electrons for the metal ions to be neutralized. The reduction is initiated by the catalyzed surface of the substrate and continued by the self catalytic activity of the deposited metal/alloy as long as the substrate is immersed in the electroless bath and operating conditions are maintained. Electroless nickel-cobalt-phosphorus thin films were deposited from a solution containing 15 g/l nickel sulphate, 5 g/l cobalt sulphate, 60 g/l ammonium citrate and 25 g/l sodium hypophosphite operating at 30 C, at a pH of 9.5 for two minutes. Electroless nickel-cobalt-phosphorus coatings are found to satisfy the basic requirements of solar control coatings. Autocatalytic deposition technique offers the possibilities of producing large area coatings with low capital investment, stability and good adhesion to glass substrates.
- OSTI ID:
- 194838
- Report Number(s):
- CONF-9404167-; ISBN 0-8194-1564-2; TRN: IM9611%%340
- Resource Relation:
- Conference: SPIE 13: international symposium on optical materials technology for energy efficiency and solar energy conversion, Freiburg (Germany), 18-22 Apr 1994; Other Information: PBD: 1994; Related Information: Is Part Of Optical materials technology for energy efficiency and solar energy conversion XIII; Wittwer, V. [ed.] [Fraunhofer Inst. for Solar Energy Systems, Freiburg (Germany)]; Granqvist, C.G. [ed.] [Uppsala Univ. (Sweden). Dept. of Technology]; Lampert, C. [ed.] [Lawrence Berkeley Lab., Berkeley, CA (United States). Energy and Environment Div.]; PB: 863 p.; Proceedings/SPIE, Volume 2255
- Country of Publication:
- United States
- Language:
- English
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