Improved precision and accuracy in quantifying plutonium isotope ratios by RIMS

Isselhardt, B. H.; Savina, M. R.; Kucher, A.; Gates, S. D.; Knight, K. B.; Hutcheon, I. D.

doi:10.1007/s10967-015-4393-x

Title: Improved precision and accuracy in quantifying plutonium isotope ratios by RIMS

Journal Article · Tue Sep 01 00:00:00 EDT 2015 · Journal of Radioanalytical and Nuclear Chemistry

DOI:https://doi.org/10.1007/s10967-015-4393-x· OSTI ID:1357770

Isselhardt, B. H.; Savina, M. R.; Kucher, A.; Gates, S. D.; Knight, K. B.; Hutcheon, I. D.

Resonance ionization mass spectrometry (RIMS) holds the promise of rapid, isobar-free quantification of actinide isotope ratios in as-received materials (i.e. not chemically purified). Recent progress in achieving this potential using two Pu test materials is presented. RIMS measurements were conducted multiple times over a period of two months on two different Pu solutions deposited on metal surfaces. Measurements were bracketed with a Pu isotopic standard, and yielded absolute accuracies of the measured Pu-240/Pu-239 ratios of 0.7 and 0.58 %, with precisions (95 % confidence intervals) of 1.49 and 0.91 %. The minor isotope Pu-238 was also quantified despite the presence of a significant quantity of U-238 in the samples.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1357770

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3; ISSN 0236-5731

Publisher:: Springer

Country of Publication:: United States

Language:: English

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