Growth rate of crystalline ice and the diffusivity of supercooled water from 126 to 262 K

Xu, Yuntao; Petrik, Nikolay G.; Smith, R. Scott; Kay, Bruce D.; Kimmel, Greg A.

doi:10.1073/pnas.1611395114

Title: Growth rate of crystalline ice and the diffusivity of supercooled water from 126 to 262 K

Journal Article · Mon Dec 12 00:00:00 EST 2016 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1611395114· OSTI ID:1335529

Xu, Yuntao ^[1];

^[1]; Smith, R. Scott ^[1]; Kay, Bruce D. ^[1];

^[1]

Chemical Physics &, Analysis, Physical Sciences Division, Physical &, Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352

Understanding deeply supercooled water is key to unraveling many of water’s anomalous properties. However, this has proven difficult due to rapid and uncontrolled crystallization. Using a pulsed laser heating technique, we measure the growth rate of crystalline ice, G(T), for 180 K < T < 262 K, i.e. deep within water’s “no man’s land.” The self-diffusion of supercooled liquid water, D(T), is obtained from G(T) using the Wilson-Frenkel model of crystal growth. For T > 237 K, G(T) and D(T) have super-Arrhenius (“fragile”) temperature dependences, but both crossover to Arrhenius (“strong”) behavior with a large activation energy in “no man’s land.” The fact that G(T) and D(T) are smoothly varying rules out the hypothesis that liquid water’s properties have a singularity at or near 228 K. Furthermore the results are consistent with a previous prediction for D(T) that assumed no thermodynamic transitions occur in “no man’s land.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: KC0301050-16248; AC05-76RL01830

OSTI ID:: 1335529

Alternate ID(s):: OSTI ID: 1344658

Report Number(s):: PNNL-SA-119195

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Vol. 113 Journal Issue: 52; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 112 works

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Title: Growth rate of crystalline ice and the diffusivity of supercooled water from 126 to 262 K

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