Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

Boteju, Kasuni C.; Ellern, Arkady; Sadow, Aaron D.

doi:10.1039/C6CC09304C

Title: Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

Journal Article · Mon Dec 19 00:00:00 EST 2016 · ChemComm

DOI:https://doi.org/10.1039/C6CC09304C· OSTI ID:1342922

Boteju, Kasuni C. ^[1]; Ellern, Arkady ^[1]; Sadow, Aaron D. ^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Chemistry

Here, a β-SiH functionalized benzyl anion [C(SiHMe₂)₂Ph]$$-$$s obtained by deprotonation of HC(SiHMe₂)₂Ph with KCH₂Ph or by reaction of KOtBu and (Me₂HSi)₃CPh; LnI₃(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe₂)₂Ph}₃ (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.

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Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1342922

Report Number(s):: IS-J-9147; CHCOFS

Journal Information:: ChemComm, Vol. 53, Issue 4; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Synthesis of Polyfunctionalized Triaryllanthanum Reagents by Using Ph ₃ La and Related Species as Exchange Reagents Benischke, Andreas D.; Anthore-Dalion, Lucile; Kohl, Fabien Chemistry - A European Journal, Vol. 24, Issue 43 https://doi.org/10.1002/chem.201801527	journal	June 2018
Rare earth arylsilazido compounds with inequivalent secondary interactions Boteju, Kasuni C.; Wan, Suchen; Venkatesh, Amrit Chemical Communications, Vol. 54, Issue 53 https://doi.org/10.1039/c8cc03186j	journal	January 2018

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