A Sacrificial Coating Strategy Toward Enhancement of Metal-Support Interaction for Ultrastable Au Nanocatalysts

Zhan, Wangcheng; He, Qian; Liu, Xiaofei; Guo, Yanglong; Wang, Yanqin; Wang, li; Guo, Yun; Borisevich, Albina Y.; Zhang, Jinshui; Lu, Guanzhong; Dai, Sheng

doi:10.1021/jacs.6b10472

Title: A Sacrificial Coating Strategy Toward Enhancement of Metal-Support Interaction for Ultrastable Au Nanocatalysts

Journal Article · Tue Nov 22 00:00:00 EST 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b10472· OSTI ID:1337043

Zhan, Wangcheng ^[1]; He, Qian ^[1]; Liu, Xiaofei ^[1]; Guo, Yanglong ^[2]; Wang, Yanqin ^[2]; Wang, li ^[2]; Guo, Yun ^[2]; Borisevich, Albina Y. ^[1]; Zhang, Jinshui ^[1]; Lu, Guanzhong ^[2]; Dai, Sheng ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
East China Univ. of Science and Technology (ECUST), Shanghai (China)

Supported gold (Au) nanocatalysts hold great promise for heterogeneous catalysis; however, their practical application is greatly hampered by poor thermodynamic stability. Herein, a general synthetic strategy is reported where discrete metal nanoparticles are made resistant to sintering, preserving their catalytic activities in high-temperature oxidation processes. Taking advantage of the unique coating chemistry of dopamine, sacrificial carbon layers are constructed on the material surface, stabilizing the supported catalyst. Upon annealing at high temperature under an inert atmosphere, the interactions between support and metal nanoparticle are dramatically enhanced, while the sacrificial carbon layers can be subsequently removed through oxidative calcination in air. Owing to the improved metal-support contact and strengthened electronic interactions, the resulting Au nanocatalysts are resistant to sintering and exhibit excellent durability for catalytic combustion of propylene at elevated temperatures. Moreover, the facile synthetic strategy can be extended to the stabilization of other supported catalysts on a broad range of supports, providing a general approach to enhancing the thermal stability and sintering resistance of supported nanocatalysts.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1337043

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 49; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 189 works

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Title: A Sacrificial Coating Strategy Toward Enhancement of Metal-Support Interaction for Ultrastable Au Nanocatalysts

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