Phosphorene: Fabrication, properties, and applications

Kou, Liangzhi; Chen, Changfeng; Smith, Sean C.

doi:10.1021/acs.jpclett.5b01094

Title: Phosphorene: Fabrication, properties, and applications

Journal Article · Wed Jun 24 00:00:00 EDT 2015 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.5b01094· OSTI ID:1332445

Kou, Liangzhi ^[1]; Chen, Changfeng ^[2]; Smith, Sean C. ^[1]

Univ. of New South Wales, Sydney, NSW (Australia)
Univ. of Nevada, Las Vegas, NV (United States)

Phosphorene, the single- or few-layer form of black phosphorus, was recently rediscovered as a two-dimensional layered material holding great promise for applications in electronics and optoelectronics. Research into its fundamental properties and device applications has since seen exponential growth. In this Perspective, we review recent progress in phosphorene research, touching upon topics on fabrication, properties, and applications; we also discuss challenges and future research directions. We highlight the intrinsically anisotropic electronic, transport, optoelectronic, thermoelectric, and mechanical properties of phosphorene resulting from its puckered structure in contrast to those of graphene and transition-metal dichalcogenides. The facile fabrication and novel properties of phosphorene have inspired design and demonstration of new nanodevices; however, further progress hinges on resolutions to technical obstructions like surface degradation effects and nonscalable fabrication techniques. We also briefly describe the latest developments of more sophisticated design concepts and implementation schemes that address some of the challenges in phosphorene research. As a result, it is expected that this fascinating material will continue to offer tremendous opportunities for research and development for the foreseeable future.

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Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001982

OSTI ID:: 1332445

Journal Information:: Journal of Physical Chemistry Letters, Vol. 6, Issue 14; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 586 works

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Solar‐Inspired Water Purification Based on Emerging 2D Materials: Status and Challenges Xie, Zhongjian; Peng, Ya-Pei; Yu, Li Solar RRL, Vol. 4, Issue 3 https://doi.org/10.1002/solr.201900400	journal	January 2020
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Recent Progress on Stability and Passivation of Black Phosphorus Abate, Yohannes; Akinwande, Deji; Gamage, Sampath Advanced Materials, Vol. 30, Issue 29 https://doi.org/10.1002/adma.201704749	journal	May 2018
Oxygen Evolution Reaction on 2D Ferromagnetic Fe ₃ GeTe ₂ : Boosting the Reactivity by the Self‐Reduction of Surface Hydroxyl Zhao, Yinghe; Gu, Jinxing; Chen, Zhongfang Advanced Functional Materials, Vol. 29, Issue 44 https://doi.org/10.1002/adfm.201904782	journal	August 2019
Periodic and fragment models based on the local correlation approach Usvyat, Denis; Maschio, Lorenzo; Schütz, Martin Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 8, Issue 4 https://doi.org/10.1002/wcms.1357	journal	January 2018
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Recent advances in inorganic 2D materials and their applications in lithium and sodium batteries Shi, Le; Zhao, Tianshou Journal of Materials Chemistry A, Vol. 5, Issue 8 https://doi.org/10.1039/c6ta09831b	journal	January 2017
Omnipotent phosphorene: a next-generation, two-dimensional nanoplatform for multidisciplinary biomedical applications Qiu, Meng; Ren, Wen Xiu; Jeong, Taeho Chemical Society Reviews, Vol. 47, Issue 15 https://doi.org/10.1039/c8cs00342d	journal	January 2018
In-plane thermal transport in black phosphorene/graphene layered heterostructures: a molecular dynamics study Liang, Ting; Zhang, Ping; Yuan, Peng Physical Chemistry Chemical Physics, Vol. 20, Issue 32 https://doi.org/10.1039/c8cp02831a	journal	January 2018
Novel two-dimensional molybdenum carbides as high capacity anodes for lithium/sodium-ion batteries Yu, Yadong; Guo, Zhonglu; Peng, Qiong Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c9ta02650a	journal	January 2019
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Ultralow-Frequency Collective Compression Mode and Strong Interlayer Coupling in Multilayer Black Phosphorus Dong, Shan; Zhang, Anmin; Liu, Kai Physical Review Letters, Vol. 116, Issue 8 https://doi.org/10.1103/physrevlett.116.087401	journal	February 2016
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First-Principles Study of Gas Molecule Adsorption on C-doped Zigzag Phosphorene Nanoribbons Yang, Shuai; Wang, Zhiyong; Dai, Xueqiong Coatings, Vol. 9, Issue 11 https://doi.org/10.3390/coatings9110763	journal	November 2019
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Advanced Phosphorus-Based Materials for Lithium/Sodium-Ion Batteries: Recent Developments and Future Perspectives Fu, Yanqing; Wei, Qiliang; Zhang, Gaixia Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702849	journal	January 2018
The potential application of black and blue phosphorene as cathode materials in rechargeable aluminum batteries: a first-principles study Xiao, Xiang; Wang, Mingyong; Tu, Jiguo Physical Chemistry Chemical Physics, Vol. 21, Issue 13 https://doi.org/10.1039/c9cp00453j	journal	January 2019
Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light Zhu, Mingshan; Sun, Zhichao; Fujitsuka, Mamoru Angewandte Chemie, Vol. 130, Issue 8 https://doi.org/10.1002/ange.201711357	journal	January 2018
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2D Black Phosphorus for Energy Storage and Thermoelectric Applications Zhang, Yu; Zheng, Yun; Rui, Kun Small, Vol. 13, Issue 28 https://doi.org/10.1002/smll.201700661	journal	June 2017
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Electrostatic-Driven Exfoliation and Hybridization of 2D Nanomaterials Guan, Guijian; Xia, Jing; Liu, Shuhua Advanced Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adma.201700326	journal	June 2017
2D V‐V Binary Materials: Status and Challenges Guo, Shiying; Zhang, Yupeng; Ge, Yanqi Advanced Materials, Vol. 31, Issue 39 https://doi.org/10.1002/adma.201902352	journal	August 2019
Strong temperature-strain coupling in the interface of Sb thin film on flexible PDMS substrate Lu, Donglin; Li, Zhenqing; Luo, Siwei Applied Physics Letters, Vol. 115, Issue 12 https://doi.org/10.1063/1.5120329	journal	September 2019
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Metal‐Free 2D/2D Phosphorene/g‐C ₃ N ₄ Van der Waals Heterojunction for Highly Enhanced Visible‐Light Photocatalytic H ₂ Production Ran, Jingrun; Guo, Weiwei; Wang, Hailong Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201800128	journal	April 2018
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Te-Doped Black Phosphorus Field-Effect Transistors Yang, Bingchao; Wan, Bensong; Zhou, Qionghua Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201603723	journal	September 2016
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Phosphorene Is the New Graphene in Biomedical Applications Tatullo, Marco; Genovese, Fabio; Aiello, Elisabetta Materials, Vol. 12, Issue 14 https://doi.org/10.3390/ma12142301	journal	July 2019
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Strain-tunable CO ₂ storage by black phosphorene and α-PC from combined first principles and molecular dynamics studies Song, Xiaohan; Liu, Yang; Yang, Yanmei Physical Chemistry Chemical Physics, Vol. 21, Issue 36 https://doi.org/10.1039/c9cp03676h	journal	January 2019
Self-doped p–n junctions in two-dimensional In ₂ X ₃ van der Waals materials Peng, Rui; Ma, Yandong; Zhang, Shuai Materials Horizons, Vol. 7, Issue 2 https://doi.org/10.1039/c9mh01109a	journal	January 2020
Non-aqueous solution-processed phosphorene by controlled low-potential electrochemical exfoliation and thin film preparation Kovalska, Evgeniya; Luxa, Jan; Hartman, Tomáš Nanoscale, Vol. 12, Issue 4 https://doi.org/10.1039/c9nr10257d	journal	January 2020
The electrical properties and modulation of g-C ₃ N ₄ /β-As and g-C ₃ N ₄ /β-Sb heterostructures: a first principles study Liang, Bo; Rao, Yongchao; Duan, Xiangmei RSC Advances, Vol. 9, Issue 66 https://doi.org/10.1039/c9ra06357a	journal	January 2019
The rising star of 2D black phosphorus beyond graphene: synthesis, properties and electronic applications Chen, Pengfei; Li, Neng; Chen, Xingzhu 2D Materials, Vol. 5, Issue 1 https://doi.org/10.1088/2053-1583/aa8d37	journal	October 2017
The electronic and transport properties of the phosphorene nanoribbons Jin, Junchao; Wang, Zhiyong; Dai, Xueqiong Materials Research Express, Vol. 6, Issue 9 https://doi.org/10.1088/2053-1591/ab33a7	journal	July 2019
Quantum transport in defective phosphorene nanoribbons: Effects of atomic vacancies Li, L. L.; Peeters, F. M. Physical Review B, Vol. 97, Issue 7 https://doi.org/10.1103/physrevb.97.075414	journal	February 2018
New two-dimensional phase of tin chalcogenides: Candidates for high-performance thermoelectric materials Dong, Baojuan; Wang, Zhenhai; Hung, Nguyen T. Physical Review Materials, Vol. 3, Issue 1 https://doi.org/10.1103/physrevmaterials.3.013405	journal	January 2019
2D Materials for Gas Sensing Applications: A Review on Graphene Oxide, MoS2, WS2 and Phosphorene Donarelli, Maurizio; Ottaviano, Luca Sensors, Vol. 18, Issue 11 https://doi.org/10.3390/s18113638	journal	October 2018
Ice‐Assisted Synthesis of Black Phosphorus Nanosheets as a Metal‐Free Photocatalyst: 2D/2D Heterostructure for Broadband H ₂ Evolution Zhang, Qingzhe; Huang, Shengyun; Deng, Jiujun Advanced Functional Materials, Vol. 29, Issue 28 https://doi.org/10.1002/adfm.201902486	journal	May 2019
Preparation of large size, few-layer black phosphorus nanosheets via phytic acid-assisted liquid exfoliation Xu, Jing-Yin; Gao, Lin-Feng; Hu, Chen-Xia Chemical Communications, Vol. 52, Issue 52 https://doi.org/10.1039/c6cc03206k	journal	January 2016
Two-dimensional materials with intrinsic auxeticity: progress and perspectives Peng, Rui; Ma, Yandong; Wu, Qian Nanoscale, Vol. 11, Issue 24 https://doi.org/10.1039/c9nr03546j	journal	January 2019
Transport characteristics and dwell time in a bilayer phosphorene barrier Hedayati Kh, Hamed; Faizabadi, Edris Journal of Physics: Condensed Matter, Vol. 31, Issue 3 https://doi.org/10.1088/1361-648x/aaefbd	journal	December 2018
Two-dimensional SiP: an unexplored direct band-gap semiconductor Zhang, Shengli; Guo, Shiying; Huang, Yaxin 2D Materials, Vol. 4, Issue 1 https://doi.org/10.1088/2053-1583/4/1/015030	journal	December 2016
Spin polarized electronic and optical properties of vacancy defects in armchair phosphorene nanoribbons Notash, Soroush; Fotoohi, Somayeh Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab47a7	journal	September 2019
Light-Induced Ambient Degradation of Few-Layer Black Phosphorus: Mechanism and Protection Zhou, Qionghua; Chen, Qian; Tong, Yilong Angewandte Chemie International Edition, Vol. 55, Issue 38 https://doi.org/10.1002/anie.201605168	journal	August 2016
Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light Zhu, Mingshan; Sun, Zhichao; Fujitsuka, Mamoru Angewandte Chemie International Edition, Vol. 57, Issue 8 https://doi.org/10.1002/anie.201711357	journal	January 2018
Acute mechano-electronic responses in twisted phosphorene nanoribbons Jang, Woosun; Kang, Kisung; Soon, Aloysius Nanoscale, Vol. 8, Issue 31 https://doi.org/10.1039/c6nr04354b	journal	January 2016
Theoretical discovery of novel two-dimensional V ^A -N binary compounds with auxiticity Xiao, Wen-Zhi; Xiao, Gang; Rong, Qing-Yan Physical Chemistry Chemical Physics, Vol. 20, Issue 34 https://doi.org/10.1039/c8cp04158j	journal	January 2018
Kagome-like group-VA monolayers with indirect–direct band gap transition and anisotropic mobility Zhu, Jiajun; He, Chao; Zhao, Yong-Hong Journal of Materials Chemistry C, Vol. 8, Issue 8 https://doi.org/10.1039/c9tc06132k	journal	January 2020
Tunable optical and excitonic properties of phosphorene via oxidation Sadki, S.; Drissi, L. B. Journal of Physics: Condensed Matter, Vol. 30, Issue 25 https://doi.org/10.1088/1361-648x/aac403	journal	June 2018
Controlling electron flow in anisotropic Dirac materials heterojunctions: a super-diverging lens Betancur-Ocampo, Y. Journal of Physics: Condensed Matter, Vol. 30, Issue 43 https://doi.org/10.1088/1361-648x/aae28a	journal	October 2018
Covalent Functionalization and Passivation of Exfoliated Black Phosphorus via Aryl Diazonium Chemistry Ryder, Christopher R.; Wood, Joshua D.; Wells, Spencer A. arXiv https://doi.org/10.48550/arxiv.1605.01012	text	January 2016
Electric-field modulation of linear dichroism and Faraday rotation in few-layer phosphorene Li, L. L.; Partoens, B.; Xu, W. arXiv https://doi.org/10.48550/arxiv.1811.12072	text	January 2018
CO Adsorption on Metal-Decorated Phosphorene Lei, Shuang Ying; Yu, Zhi Yuan; Shen, Hai Yun ACS Omega, Vol. 3, Issue 4 https://doi.org/10.1021/acsomega.8b00133	journal	April 2018
Polymer-based black phosphorus (bP) hybrid materials by in situ radical polymerization: an effective tool to exfoliate bP and stabilize bP nanoflakes Passaglia, Elisa; Cicogna, Francesca; Costantino, Federica arXiv https://doi.org/10.48550/arxiv.1804.03907	text	January 2018
Black Phosphorus and its Biomedical Applications Choi, Jane Ru; Yong, Kar Wey; Choi, Jean Yu Theranostics, Vol. 8, Issue 4 https://doi.org/10.7150/thno.22573	journal	January 2018

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