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Title: Thermal activation mechanisms and Labusch-type strengthening analysis for a family of high-entropy and equiatomic solid-solution alloys

Journal Article · · Acta Materialia
 [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

To understand the underlying strengthening mechanisms, thermal activation processes are investigated from stress-strain measurements with varying temperatures and strain rates for a family of equiatomic quinary, quaternary, ternary, and binary, face-center-cubic-structured, single phase solid-solution alloys, which are all subsystems of the FeNiCoCrMn high-entropy alloy. Our analysis suggests that the Labusch-type solution strengthening mechanism, rather than the lattice friction (or lattice resistance), governs the deformation behavior in equiatomic alloys. First, upon excluding the Hall-Petch effects, the activation volumes for these alloys are found to range from 10 to 1000 times the cubic power of Burgers vector, which are much larger than that required for kink pairs (i.e., the thermal activation process for the lattice resistance mechanism in body-center-cubic-structured metals). Second, the Labusch-type analysis for an N-element alloy is conducted by treating M-elements (M < N) as an effective medium and summing the strengthening contributions from the rest of N-M elements as individual solute species. For all equiatomic alloys investigated, a qualitative agreement exists between the measured strengthening effect and the Labusch strengthening factor from arbitrary M to N elements based on the lattice and modulus mismatches. Furthermore, the Labusch strengthening factor provides a practical critique to understand and design such compositionally complex but structurally simple alloys.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1324176
Alternate ID(s):
OSTI ID: 1358720
Journal Information:
Acta Materialia, Vol. 120, Issue C; ISSN 1359-6454
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 183 works
Citation information provided by
Web of Science

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Cited By (15)

Intermediate-Temperature Creep Deformation and Microstructural Evolution of an Equiatomic FCC-Structured CoCrFeNiMn High-Entropy Alloy journal December 2018
Dynamically reinforced heterogeneous grain structure prolongs ductility in a medium-entropy alloy with gigapascal yield strength journal June 2018
Microstructure and mechanical properties of AlCoCrFeNi high entropy alloys produced by spark plasma sintering journal June 2019
Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy journal February 2018
Strengthening in multi-principal element alloys with local-chemical-order roughened dislocation pathways journal August 2019
Tailoring heterogeneities in high-entropy alloys to promote strength–ductility synergy journal December 2019
On Lattice Distortion in High Entropy Alloys journal July 2018
Advanced Nanoindentation Testing for Studying Strain-Rate Sensitivity and Activation Volume journal August 2017
Enhanced strength and ductility of a tungsten-doped CoCrNi medium-entropy alloy journal July 2018
An as-cast high-entropy alloy with remarkable mechanical properties strengthened by nanometer precipitates journal January 2020
Strain-rate sensitivity of high-entropy alloys and its significance in deformation journal September 2019
Can Ordered Precursors Promote the Nucleation of Solid Solutions? journal November 2019
Strengthening in multi-principal element alloys with local-chemical-order roughened dislocation pathways text January 2019
Can Ordered Precursors Promote the Nucleation of Solid Solutions? text January 2021
Ab Initio Study of Elastic and Mechanical Properties in FeCrMn Alloys journal April 2019