Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)

Zhong, J. Q.; Shete, M.; Waluyo, I.; Sadowski, J. T.; Stacchiola, D. J.; Tsapatsis, M.; Boscoboinik, J. A.

doi:10.1016/j.cattod.2016.07.015

Title: Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)

Journal Article · Tue Jul 26 00:00:00 EDT 2016 · Catalysis Today

DOI:https://doi.org/10.1016/j.cattod.2016.07.015· OSTI ID:1303014

Zhong, J. Q. ^[1]; Shete, M. ^[2]; Waluyo, I. ^[3]; Sadowski, J. T. ^[1]; Stacchiola, D. J. ^[1]; Tsapatsis, M. ^[2]; Boscoboinik, J. A. ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Minnesota, Minneapolis, MN (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

While surface science has provided fundamental insights into a variety a materials, the most used catalysts in the industry, namely zeolites, still remain a challenge. The recent preparation of two-dimensional versions of MFI zeolite frameworks and the possibility of their deposition on electrically conductive supports provides for the first time a viable strategy to perform detailed studies on industrially relevant zeolites using the vast toolkit of surface science. In this work we demonstrate the use of infrared reflection absorption spectroscopy (IRRAS) and synchrotron-based x-ray photoelectron spectroscopy (XPS) to study these materials. Furthermore, polarization modulation IRRAS is used to study the adsorption of methanol and its effect in phonon vibrations of the zeolite framework. The possibility of using surface science methods, in particular under ambient pressure conditions, for the study of well-defined zeolites and other microporous structures opens new avenues to understand structural and mechanistic aspects of these materials as catalysts, adsorbents and molecular sieves.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; SC0012704; SC000105; 15-010

OSTI ID:: 1303014

Alternate ID(s):: OSTI ID: 1416652

Report Number(s):: BNL-112489-2016-JA; R&D Project: 16083; KC0403020

Journal Information:: Catalysis Today, Journal Name: Catalysis Today; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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Cationic two-dimensional inorganic networks of antimony oxide hydroxide for Lewis acid catalysis Yin, Jinlin; Fei, Honghan Dalton Transactions, Vol. 47, Issue 12 https://doi.org/10.1039/c8dt00188j	journal	January 2018
Highly Oriented Growth of Catalytically Active Zeolite ZSM-5 Films with a Broad Range of Si/Al Ratios Fu, Donglong; Schmidt, Joel E.; Ristanović, Zoran Angewandte Chemie, Vol. 129, Issue 37 https://doi.org/10.1002/ange.201704846	journal	July 2017
Chemistry in confined space through the eyes of surface science—2D porous materials Boscoboinik, J. Anibal Journal of Physics: Condensed Matter, Vol. 31, Issue 6 https://doi.org/10.1088/1361-648x/aaf2ce	journal	December 2018
Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles Wang, Mengen; Zhong, Jian-Qiang; Kestell, John Topics in Catalysis, Vol. 60, Issue 6-7 https://doi.org/10.1007/s11244-016-0704-x	journal	September 2016

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77 NANOSCIENCE AND NANOTECHNOLOGY
Zeolites
Surface Science
X-ray Photoelectron Spectroscopy
Infrared Reflection Absorption Spectroscopy

Title: Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)

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