Materials Data on OsC3IO3 by Materials Project
IOs(CO)3 crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of twelve formaldehyde molecules and two IOs clusters. In each IOs cluster, Os3+ is bonded in a 2-coordinate geometry to two I1- atoms. There are one shorter (2.78 Å) and one longer (2.80 Å) Os–I bond lengths. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a 6-coordinate geometry to two equivalent Os3+ atoms. In the second I1- site, I1- is bonded in a 4-coordinate geometry to two equivalent Os3+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1277620
- Report Number(s):
- mp-608354
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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