Materials Data on SbI(ClF3)2 by Materials Project
SbI(ClF3)2 crystallizes in the orthorhombic Cmce space group. The structure is two-dimensional and consists of two SbI(ClF3)2 sheets oriented in the (0, 1, 0) direction. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.91–1.96 Å. I5+ is bonded in a rectangular see-saw-like geometry to two equivalent Cl1- and two equivalent F1- atoms. Both I–Cl bond lengths are 2.30 Å. Both I–F bond lengths are 2.62 Å. Cl1- is bonded in a 2-coordinate geometry to one I5+ and one F1- atom. The Cl–F bond length is 2.95 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ and one I5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ and two equivalent Cl1- atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1271658
- Report Number(s):
- mp-560789
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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