Materials Data on CeF4 by Materials Project
CeF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Ce–F bond distances ranging from 2.23–2.33 Å. In the second Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are six shorter (2.26 Å) and two longer (2.37 Å) Ce–F bond lengths. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Ce4+ atoms. In the second F1- site, F1- is bonded in a distorted linear geometry to two equivalent Ce4+ atoms. In the third F1- site, F1- is bonded in a linear geometry to two Ce4+ atoms. In the fourth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ce4+ atoms. In the fifth F1- site, F1- is bonded in a linear geometry to two equivalent Ce4+ atoms. In the sixth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Ce4+ atoms. In the seventh F1- site, F1- is bonded in a distorted linear geometry to two Ce4+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1266352
- Report Number(s):
- mp-542001
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
Similar Records
Materials Data on Y6O5F8 by Materials Project
Materials Data on CsCeF5 by Materials Project