Materials Data on RbEu3F10 by Materials Project

Dataset · Thu Jul 23 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1261758· OSTI ID:1261758

The Materials Project

RbEu3F10 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to sixteen F1- atoms to form distorted edge-sharing RbF16 tetrahedra. There are four shorter (2.89 Å) and twelve longer (3.33 Å) Rb–F bond lengths. Eu3+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are four shorter (2.30 Å) and four longer (2.44 Å) Eu–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded to one Rb1+ and three equivalent Eu3+ atoms to form a mixture of distorted edge and corner-sharing FRbEu3 tetrahedra. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Rb1+ and two equivalent Eu3+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1261758
• Report Number(s): mp-504520
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
RbEu3F10
Eu-F-Rb