In-pore exchange and diffusion of carbonate solvent mixtures in nanoporous carbon

Alam, Todd M.; Osborn Popp, Thomas M.

doi:10.1016/j.cplett.2016.06.014

Title: In-pore exchange and diffusion of carbonate solvent mixtures in nanoporous carbon

Journal Article · Sat Jun 04 00:00:00 EDT 2016 · Chemical Physics Letters

DOI:https://doi.org/10.1016/j.cplett.2016.06.014· OSTI ID:1257785

Alam, Todd M. ^[1]; Osborn Popp, Thomas M. ^[2]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of California, Berkeley, CA (United States)

High resolution magic angle spinning (HRMAS) ¹H NMR spectroscopy has been used to resolve different surface and in-pore solvent environments of ethylene carbonate (EC) and dimethyl carbonate (DMC) mixtures absorbed within nanoporous carbon (NPC). Two dimensional (2D) ¹H HRMAS NMR exchange measurements revealed that the inhomogeneous broadened in-pore resonances have pore-to-pore exchange rates on the millisecond timescale. Pulsed-field gradient (PFG) NMR diffusometry revealed the in-pore self-diffusion constants for both EC and DMC were reduced by up to a factor of five with respect to the diffusion in the non-absorbed solvent mixtures.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1257785

Alternate ID(s):: OSTI ID: 1429517

Report Number(s):: SAND2016-3352J; PII: S0009261416304092

Journal Information:: Chemical Physics Letters, Vol. 658, Issue C; ISSN 0009-2614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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