skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of chiral heterobimetallic tris(phosphinoamide) Zr/Co complexes

Journal Article · · Polyhedron

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0004019
OSTI ID:
1256783
Journal Information:
Polyhedron, Journal Name: Polyhedron Vol. 114 Journal Issue: C; ISSN 0277-5387
Publisher:
ElsevierCopyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

References (46)

[TiPHOS(Rh)]+:  A Fortuitous Coordination Mode and an Effective Hydrosilylation Bimetallic Catalyst journal February 2005
Metal-Metal Multiple Bonds in Early/Late Heterobimetallic Complexes: Applications Toward Small Molecule Activation and Catalysis journal January 2011
Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation journal September 2014
Structure and Reactivity of Early−Late Heterobimetallic Complexes journal December 1999
Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights journal March 2012
Catalytic Asymmetric Hydrosilation of Aryl Alkyl Ketones with C2-Symmetric Chiral Metallocene Complexes journal May 1994
Chiral ligand control in enantioselective reduction of ketones by SmI2 for ketyl radical addition to olefins journal June 1998
Highly Polar Metal-Metal Bonds in “Early-Late” Heterodimetallic Complexes journal August 2000
Advances in the Enzymatic Reduction of Ketones journal December 2007
Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis journal June 2008
Early-late heterobimetallics journal June 1989
Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes journal January 2010
Interaction and Activation of Carbon–Heteroatom π Bonds with a Zr/Co Heterobimetallic Complex journal April 2014
Diastereo- and enantioselective hydrodimerization of β-monosubstituted acrylic acid amides induced by chiral samarium(II) complexes journal October 1999
Activation of CO 2 by a Heterobimetallic Zr/Co Complex journal September 2011
Studies on the SmI2-Promoted Pinacol-Type Cyclization:  Synthesis of the Hexahydroazepine Ring of Balanol journal July 2000
Metal–metal multiple bonding in C3-symmetric bimetallic complexes of the first row transition metals journal January 2014
Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation:  The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity journal June 1999
Catalytic asymmetric hydrosilylation of ketones with new chiral ferrocenylphosphine-imine ligands journal October 1995
Chiral and C2-symmetrical bis(oxazolinylpyridine)rhodium(III) complexes: effective catalysts for asymmetric hydrosilylation of ketones journal March 1989
An iron-catalysed hydrosilylation of ketones journal January 2007
Assignment of the oxidation states of Zr and Co in a highly reactive heterobimetallic Zr/Co complex using X-ray absorption spectroscopy (XANES) journal January 2014
Enantioselective Organocatalysis journal October 2001
Copper(I) Hydride-Catalyzed Asymmetric Hydrosilylation of Heteroaromatic Ketones journal October 2002
Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes 1 journal January 1965
Asymmetric hydrosilylation, transfer hydrogenation and hydrogenation of ketones catalyzed by iridium complexes journal March 2010
Synthesis, Molecular Structure and Catalytic Activity of Six‐Coordinate Chloro(hydrido)‐ and Dihydridoruthenium( II ) and ‐osmium( II ) Complexes with the Chiral Ligands P i Pr 2 NH(Me)Ph, ( S , S )‐Chiraphos and ( S , S ,)‐Diop journal June 2004
Activation of E-H and E-E (E = S, O) Bonds by Heterobimetallic Zr/Co Complexes: Evidence for Both One- and Two-Electron Processes journal May 2013
A New Chiral Bis(oxazolinylmethyl)amine Ligand for Ru-Catalyzed Asymmetric Transfer Hydrogenation of Ketones journal April 1998
Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands journal July 2009
Effect of ligand modification on the reactivity of phosphinoamide-bridged heterobimetallic Zr/Co complexes journal January 2014
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co journal January 2010
Zirconium(IV) Tris(phosphinoamide) Complexes as a Tripodal-Type Metalloligand: A Route to Zr–M (M = Cu, Mo, Pt) Heterodimetallic Complexes journal June 2007
Iron-Catalyzed Enantioselective Hydrosilylation of Ketones journal March 2008
Reduction of Carbonyl Compounds with Various Hydrosilane-Rhodium(I) Complex Combinations journal November 1972
Enantioselective Hydrosilylation of Ketones with a Chiral Titanocene Catalyst journal December 1994
Asymmetric Hydrosilylation of Aryl Ketones Catalyzed by Copper Hydride Complexed by Nonracemic Biphenyl Bis - phosphine Ligands journal July 2003
N–H activation of hydrazines by a heterobimetallic Zr–Co complex: promotion of one-electron chemistry at Zr journal January 2013
Enantioselective Hydrosilylation of Acetophenone with Rhodium/Thiazolidine Catalysts journal April 1983
Catalytic Applications of Early/Late Heterobimetallic Complexes journal January 2012
Phosphido-bridged Ta/Rh bimetallic complex: synthesis, structure, and catalytic hydrosilylation of acetophenone journal January 2010
Enantioselective Radical Processes journal August 2003
Niobium/Rhodium Bimetallic Complexes: Synthesis, Structure, and Catalytic Hydrosilylation of Acetophenone and Benzaldehyde journal July 2009
CuH in a Bottle: A Convenient Reagent for Asymmetric Hydrosilylations journal October 2005
Catalytic Hydrosilylation of Ketones Using a Co/Zr Heterobimetallic Complex: Evidence for an Unusual Mechanism Involving Ketyl Radicals journal February 2013
Rhodium complex catalysed hydrosilylation of carbonyl compounds journal January 1972