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Title: Detailed magnetic and structural analysis mapping a robust magnetic C 4 dome in Sr 1 - x Na x Fe 2 As 2

Journal Article · · Physical Review B
 [1];  [2];  [3];  [4];  [1];  [1];  [3];  [3];  [5];  [3];  [3];  [1]
  1. Northern Illinois Univ., DeKalb, IL (United States). Dept. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Univ. of Alabama, Tuscaloosa, AL (United States). Dept. of Chemistry
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry

The recently discovered C4 tetragonal magnetic phase in hole-doped members of the iron-based superconductors provides new insights into the origin of unconventional superconductivity. Previously observed in Ba1-xNaxFe2As2 (with A = K, Na), the C4 magnetic phase exists within the well studied C2 spin-density wave (SDW) dome, arising just before the complete suppression of antiferromagnetic (AFM) order but after the onset of superconductivity. Here in this paper, we present detailed x-ray and neutron diffraction studies of Sr1-xNaxFe2As2 (0.10 ≤ x ≤ 0.60) to determine their structural evolution and the extent of the C4 phase. Spanning Δx ~ 0.14 in composition, the C4 phase is found to extend over a larger range of compositions, and to exhibit a significantly higher transition temperature, Tr ~ 65K, than in either of the other systems in which it has been observed. The onset of this phase is seen near a composition (x~0:30) where the bonding angles of the Fe2As2 layers approach the perfect 109.46° tetrahedral angle. We discuss the possible role of this return to a higher symmetry environment for the magnetic iron site in triggering the magnetic reorientation and the coupled re-entrance to the tetragonal structure. Finally, we present a new phase diagram, complete with the C4 phase, and use its observation in a third hole-doped 122 system to suggest the universality of this phase.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1352600
Alternate ID(s):
OSTI ID: 1248253
Journal Information:
Physical Review B, Vol. 93, Issue 13; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 31 works
Citation information provided by
Web of Science

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Cited By (5)

Strong spin resonance mode associated with suppression of soft magnetic ordering in hole-doped Ba1-xNaxFe2As2 journal December 2019
Single-crystal growth of the iron-based superconductor La 0.34 Na 0.66 Fe 2 As 2 journal October 2018
Optical and photoemission investigation of structural and magnetic transitions in the iron-based superconductor Sr 0.67 Na 0.33 Fe 2 As 2 journal December 2019
Preferred Magnetic Excitations in the Iron-Based Sr 1 x Na x Fe 2 As 2 Superconductor journal January 2019
Strong Spin Resonance Mode associated with suppression of soft magnetic ordering in Hole-doped Ba1-xNaxFe2As2 text January 2019

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