Detailed magnetic and structural analysis mapping a robust magnetic dome in
- Northern Illinois Univ., DeKalb, IL (United States). Dept. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Univ. of Alabama, Tuscaloosa, AL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
The recently discovered C4 tetragonal magnetic phase in hole-doped members of the iron-based superconductors provides new insights into the origin of unconventional superconductivity. Previously observed in Ba1-xNaxFe2As2 (with A = K, Na), the C4 magnetic phase exists within the well studied C2 spin-density wave (SDW) dome, arising just before the complete suppression of antiferromagnetic (AFM) order but after the onset of superconductivity. Here in this paper, we present detailed x-ray and neutron diffraction studies of Sr1-xNaxFe2As2 (0.10 ≤ x ≤ 0.60) to determine their structural evolution and the extent of the C4 phase. Spanning Δx ~ 0.14 in composition, the C4 phase is found to extend over a larger range of compositions, and to exhibit a significantly higher transition temperature, Tr ~ 65K, than in either of the other systems in which it has been observed. The onset of this phase is seen near a composition (x~0:30) where the bonding angles of the Fe2As2 layers approach the perfect 109.46° tetrahedral angle. We discuss the possible role of this return to a higher symmetry environment for the magnetic iron site in triggering the magnetic reorientation and the coupled re-entrance to the tetragonal structure. Finally, we present a new phase diagram, complete with the C4 phase, and use its observation in a third hole-doped 122 system to suggest the universality of this phase.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1352600
- Alternate ID(s):
- OSTI ID: 1248253
- Journal Information:
- Physical Review B, Vol. 93, Issue 13; ISSN 2469-9950
- Publisher:
- American Physical Society (APS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
Strong spin resonance mode associated with suppression of soft magnetic ordering in hole-doped Ba1-xNaxFe2As2
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journal | December 2019 |
Single-crystal growth of the iron-based superconductor La 0.34 Na 0.66 Fe 2 As 2
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journal | October 2018 |
Optical and photoemission investigation of structural and magnetic transitions in the iron-based superconductor
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journal | December 2019 |
Preferred Magnetic Excitations in the Iron-Based Superconductor
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journal | January 2019 |
Strong Spin Resonance Mode associated with suppression of soft magnetic ordering in Hole-doped Ba1-xNaxFe2As2 | text | January 2019 |
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