Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures

Ashton, Thomas E.; Borras, David Hevia; Iadecola, Antonella; Wiaderek, Kamila Magdalena; Chapman, Karena W.; Corr, Serena A.

doi:10.1107/S2052520615021289

Title: Microwave-assisted synthesis and electrochemical evaluation of VO₂ (B) nanostructures

Journal Article · Tue Dec 01 00:00:00 EST 2015 · Acta Crystallographica. Section B: Structural Science

DOI:https://doi.org/10.1107/S2052520615021289· OSTI ID:1240688

Ashton, Thomas E. ^[1]; Borras, David Hevia ^[1]; Iadecola, Antonella ^[2]; Wiaderek, Kamila Magdalena ^[3]; Chapman, Karena W. ^[3]; Corr, Serena A. ^[1]

Univ. of Glasgow, Scotland (United Kingdom). School of Chemistry
European Synchrotron, Grenoble (France); Network on the Electrochemical Storage of Energy (France); Synchrotron SOLEIL, Saint Aubin, Gif sur Yvette (France)
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division

Understanding how intercalation materials change during electrochemical operation is paramount to optimising their behaviour and function and in situ characterisation methods allow us to observe these changes without sample destruction. Here, we first report the improved intercalation properties of bronze phase vanadium dioxide VO2 (B) prepared by a microwave assisted route which exhibits a larger electrochemical capacity (232 mAh g^-1) compared to VO₂ (B) prepared by a solvothermal route (197 mAh g^-1). These electrochemical differences have also been followed using in situ X-ray absorption spectroscopy allowing us to follow oxidation state changes as they occur during battery operation.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Royal Society

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1240688

Journal Information:: Acta Crystallographica. Section B: Structural Science, Vol. 71, Issue 6; ISSN 0108-7681

Publisher:: International Union of CrystallographyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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Vanadium (III) Oxide/Carbon Core/Shell Hybrids as an Anode for Lithium-Ion Batteries Budak, Öznil; Srimuk, Pattarachai; Tolosa, Aura Universität des Saarlandes https://doi.org/10.22028/d291-28898	collection	January 2018

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Title: Microwave-assisted synthesis and electrochemical evaluation of VO₂ (B) nanostructures