skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Three-Dimensional Modeling of the Reactive Transport of CO2 and Its Impact on Geomechanical Properties of Reservoir Rocks and Seals

Journal Article · · International Journal of Greenhouse Gas Control

This article develops a novel multiscale modeling approach to analyze CO2 reservoirs using Pacific Northwest National Laboratory’s STOMP-CO2-R code that is interfaced with the ABAQUS® finite element package. The STOMP-CO2-R/ABAQUS® sequentially coupled simulator accounts for the reactive transport of CO2 causing mineral composition changes that modify the geomechanical properties of reservoir rocks and seals. Formation rocks’ elastic properties that vary during CO2 injection and govern the poroelastic behavior of rocks are modeled by an Eshelby-Mori-Tanka approach (EMTA) implemented in ABAQUS® via user-subroutines. The computational tool incorporates the change in rock permeability due to both geochemistry and geomechanics. A three-dimensional (3D) STOMP-CO2-R model for a model CO2 reservoir containing a vertical fault is built to analyze a formation containing a realistic geochemical reaction network with 5 minerals: albite, anorthite, calcite, kaolinite and quartz. A 3D ABAQUS® model that maps the above STOMP-CO2-R model is built for the analysis using STOMP-CO2-R/ABAQUS®. The results show that the changes in volume fraction of minerals include dissolution of anorthite, precipitation of calcite and kaolinite, with little change in the albite volume fraction. After a long period of CO2 injection the mineralogical and geomechanical changes significantly reduced the permeability and elastic modulus of the reservoir (between the base and caprock) in front of the fault leading to a reduction of the pressure margin to fracture at and beyond the injection location. The impact of reactive transport of CO2 on the geomechanical properties of reservoir rocks and seals are studied in terms of mineral composition changes that directly affect the rock stiffness, stress and strain distributions as well as the pressure margin to fracture.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1237802
Report Number(s):
PNNL-SA-109235; AA9010200
Journal Information:
International Journal of Greenhouse Gas Control, Vol. 46; ISSN 1750-5836
Publisher:
Elsevier
Country of Publication:
United States
Language:
English