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Title: N-doping of organic semiconductors by bis-metallosandwich compounds

Patent ·
OSTI ID:1234678

The various inventions disclosed, described, and/or claimed herein relate to the field of methods for n-doping organic semiconductors with certain bis-metallosandwich compounds, the doped compositions produced, and the uses of the doped compositions in organic electronic devices. Metals can be manganese, rhenium, iron, ruthenium, osmium, rhodium, or iridium. Stable and efficient doping can be achieved.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-07ER46467
Assignee:
Georgia Tech Research Corporation (Atlanta, GA)
Patent Number(s):
9,231,219
Application Number:
14/126,319
OSTI ID:
1234678
Resource Relation:
Patent File Date: 2012 Jun 13
Country of Publication:
United States
Language:
English

References (20)

N-doping of pentacene by decamethylcobaltocene journal December 2008
Decamethylcobaltocene as an efficient n-dopant in organic electronic materials and devices journal October 2008
Influence of chemical doping on the performance of organic photovoltaic cells journal May 2009
N-type doping of an electron-transport material by controlled gas-phase incorporation of cobaltocene journal November 2006
Chemical Redox Agents for Organometallic Chemistry journal January 1996
The structure of fullerene films and their metallocene doping journal August 1994
Hole Injection in a Model Fluorene-Triarylamine Copolymer journal January 2009
Electrochemical generation of 19- and 20-electron rhodocenium complexes and their properties journal June 1993
Reduction of ruthenium arenecyclopentadienyl complexes reactions induced by electron transfer journal April 1997
High-Performance Polymer-Small Molecule Blend Organic Transistors journal March 2009
Syntheses, characterizations, and stereoelectronic stabilization of organometallic electron reservoirs: the 19-electron d7 redox catalysts .eta.5-C5R5Fe-.eta.6-C6R'6 journal February 1981
Photoelectron Spectroscopic Study of the Electronic Band Structure of Polyfluorene and Fluorene-Arylamine Copolymers at Interfaces journal December 2006
Improvements in the Preparation of Cyclopentadienyl Thallium and Methylcyclopentadienylthallium and in Their Use in Organometallic Chemistry journal October 1997
A Molybdenum Dithiolene Complex as p -Dopant for Hole-Transport Materials: A Multitechnique Experimental and Theoretical Investigation journal January 2010
Charge Carrier Transporting Molecular Materials and Their Applications in Devices journal April 2007
Convenient Synthesis of [(η 5 -C 5 Me 5 )Ru(NCMe) 3 ]PF 6 and the Phosphine Derivatives [(η 5 -C 5 Me 5 )Ru(PR 3 ) 2 (NCMe)]PF 6 journal March 1999
Highly Efficient Organic Devices Based on Electrically Doped Transport Layers journal April 2007
Electron-hole interaction energy in the organic molecular semiconductor PTCDA journal June 1997
A high-mobility electron-transporting polymer for printed transistors journal January 2009
Novel NIR-absorbing conjugated polymers for efficient polymer solar cells: effect of alkyl chain length on device performance journal January 2009