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Title: Metal-organic framework materials with ultrahigh surface areas

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.
Authors:
; ; ; ; ; ;
Publication Date:
OSTI Identifier:
1233374
Report Number(s):
9,216,939
13/920,828
DOE Contract Number:
FG02-08ER15967
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Jun 18
Research Org:
NORTHWESTERN UNIVERSITY, Evanston, IL (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE