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Title: Thermal Stability in the Blended Lithium Manganese Oxide ¿ Lithium Nickel Cobalt Manganese Oxide Cathode Materials: An In Situ Time-resolved X-Ray Diffraction and Mass Spectroscopy Study

Journal Article · · Journal of Power Sources
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Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC00112704
OSTI ID:
1229465
Report Number(s):
BNL-111541-2015-JA
Journal Information:
Journal of Power Sources, Vol. 277; ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

References (33)

A review of blended cathode materials for use in Li-ion batteries journal February 2014
The kinetic effect on structural behavior of mixed LiMn2O4–LiNi1/3Co1/3Mn1/3O2 cathode materials studied by in situ time-resolved X-ray diffraction technique journal February 2012
LiMn2O4 Spinel/LiNi0.8Co0.15Al0.05O2 Blends as Cathode Materials for Lithium-Ion Batteries journal January 2011
In situ X-ray diffraction studies of mixed LiMn2O4–LiNi1/3Co1/3Mn1/3O2 composite cathode in Li-ion cells during charge–discharge cycling journal July 2009
Electrochemical evaluation of mixed oxide electrode for Li-ion secondary batteries: Li1.1Mn1.9O4 and LiNi0.8Co0.15Al0.05O2 journal August 2005
Advantages of blending LiNi0.8Co0.2O2 into Li1+xMn2−xO4 cathodes journal July 2001
Electrochemical evaluation of composite cathodes base on blends of LiMn2O4 and LiNi0.8Co0.2O2 journal August 2001
Electrochemical extraction of lithium from LiMn2O4 journal February 1984
High-Temperature Storage Performance of Li-Ion Batteries Using a Mixture of Li-Mn Spinel and Li-Ni-Co-Mn Oxide as a Positive Electrode Material journal January 2005
Layered Lithium Insertion Material of LiCo 1/3 Ni 1/3 Mn 1/3 O 2 for Lithium-Ion Batteries journal July 2001
Thermodynamic Stability of Chemically Delithiated Li(Li[sub x]Mn[sub 2−x])O[sub 4] journal January 1998
Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries journal June 2003
The Impact of Zr Substitution on the Structure, Electrochemical Performance and Thermal Stability of Li[Ni1/3Mn1/3−zCo1/3Zrz]O2 journal January 2011
Synthesis, Characterization, and Thermal Stability of Li[Ni 1/3 Mn 1/3 Co 1/3− z (MnMg) z /2 ]O 2 journal September 2010
Synthesis, Characterization, and Thermal Stability of LiCo[sub 1−z][MnMg][sub z/2]O[sub 2] journal January 2010
Synthesis, Characterization, and Thermal Stability of LiNi 1/3 Mn 1/3 Co 1/3− z Mg z O 2 , LiNi 1/3− z Mn 1/3 Co 1/3 Mg z O 2 , and LiNi 1/3 Mn 1/3− z Co 1/3 Mg z O 2 † journal February 2010
Time-Resolved XRD Study on the Thermal Decomposition of Li[sub 1−x]Ni[sub 0.8]Co[sub 0.15]Al[sub 0.05]O[sub 2] Cathode Materials for Li-Ion Batteries journal January 2005
A study on the newly observed intermediate structures during the thermal decomposition of nickel-based layered cathode materials using time-resolved XRD journal May 2006
Structural changes and thermal stability of charged LiNi1/3Co1/3Mn1/3O2 cathode material for Li-ion batteries studied by time-resolved XRD journal April 2009
AlF3-coated LiCoO2 and Li[Ni1/3Co1/3Mn1/3]O2 blend composite cathode for lithium ion batteries journal August 2011
Oxygen-Release-Related Thermal Stability and Decomposition Pathways of Li x Ni 0.5 Mn 1.5 O 4 Cathode Materials journal December 2013
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries journal June 2012
Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials journal January 2013
EXPGUI , a graphical user interface for GSAS journal April 2001
X-ray/Neutron Diffraction and Electrochemical Studies of Lithium De/Re-Intercalation in Li 1 - x Co 1/ 3 Ni 1/3 Mn 1/3 O 2 ( x = 0 → 1) journal April 2006
Electronic properties of transition-metal oxides-II journal January 1957
Theory of Ionic Ordering, Crystal Distortion, and Magnetic Exchange Due to Covalent Forces in Spinels journal April 1955
Solid-phase equilibria in the system NiOMn2O3O2 journal August 1964
Oxides of the 3 d Transition Metals* journal July 1958
Preparation of a new crystal form of manganese dioxide: λ-MnO2 journal September 1981
Probing Thermally Induced Decomposition of Delithiated Li 1.2– x Ni 0.15 Mn 0.55 Co 0.1 O 2 by in Situ High-Energy X-ray Diffraction journal July 2014
Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction journal March 2013
Electronic Structure of the 3 d Transition-Metal Monoxides. I. Energy-Band Results journal January 1972

Cited By (6)

Polyhedral perspectives on the capacity limit of cathode compounds for lithium-ion batteries: a case study for Li 6 CoO 4 journal January 2018
Synergetic effects of LiNi1/3Co1/3Mn1/3O2–LiMn2O4 blended materials on lithium ionic transport for power performance journal July 2018
Thermal safety studies of high energy density lithium‐ion batteries under different states of charge journal December 2019
Enhanced Electrochemical Properties of LiNi 0.8 Co 0.1 Mn 0.1 O 2 at Elevated Temperature by Simultaneous Structure and Interface Regulating journal January 2019
Anti‐Oxygen Leaking LiCoO 2 journal April 2019
In situ Synchrotron X-ray Techniques for Structural Investigation of Electrode Materials for Li-ion Battery journal December 2019

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