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Title: Structure Tracking Aided Design and Synthesis of Li3V2 PO4)3 Nanocrystals as High-Power Cathodes for Lithium Ion Batteries

Journal Article · · Chemistry of Materials

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC00112704
OSTI ID:
1229409
Report Number(s):
BNL-111485-2015-JA
Journal Information:
Chemistry of Materials, Vol. 27, Issue 16; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (27)

Electrical Energy Storage for the Grid: A Battery of Choices journal November 2011
Mapping of Transition Metal Redox Energies in Phosphates with NASICON Structure by Lithium Intercalation journal January 1997
Challenges for Rechargeable Li Batteries journal February 2010
Nanostructured Composites: A High Capacity, Fast Rate Li3V2(PO4)3/Carbon Cathode for Rechargeable Lithium Batteries journal November 2002
Electrochemical Property:  Structure Relationships in Monoclinic Li 3 - y V 2 (PO 4 ) 3 journal August 2003
Rhombohedral Form of Li 3 V 2 (PO 4 ) 3 as a Cathode in Li-Ion Batteries journal November 2000
Aluminum-stabilized NASICON-structured Li 3 V 2 (PO 4 ) 3 journal January 2013
Pyro-synthesis of a high rate nano-Li3V2(PO4)3/C cathode with mixed morphology for advanced Li-ion batteries journal February 2014
Enhancement of discharge capacity of Li3V2(PO4)3 by stabilizing the orthorhombic phase at room temperature journal November 2000
A novel synthesis of Li3V2(PO4)3/C nanocomposite with excellent high-rate capacity and cyclability journal December 2012
Hydrothermal Synthesis and Electrochemical Properties of Li 3 V 2 (PO 4 ) 3 /C-Based Composites for Lithium-Ion Batteries journal August 2011
Li3V2(PO4)3@C core–shell nanocomposite as a superior cathode material for lithium-ion batteries journal January 2013
Nanostructured Li3V2(PO4)3 cathode supported on reduced graphene oxide for lithium-ion batteries journal October 2013
Ionothermal synthesis and rate performance studies of nanostructured Li3V2(PO4)3/C composites as cathode materials for lithium-ion batteries journal March 2013
A fast synthesis of Li3V2(PO4)3 crystals via glass-ceramic processing and their battery performance journal November 2011
LiFePO4 Mesocrystals for Lithium-Ion Batteries journal March 2011
Electrochemical Properties of VPO 4 /C Nanosheets and Microspheres As Anode Materials for Lithium-Ion Batteries journal April 2014
Electrochemical performance of LiVPO4F/C composite cathode prepared through amorphous vanadium phosphorus oxide intermediate journal August 2011
Layered Lithium Vanadium Fluorophosphate, Li 5 V(PO 4 ) 2 F 2 : A 4 V Class Positive Electrode Material for Lithium-Ion Batteries journal July 2008
Structural Transformation of LiVOPO 4 to Li 3 V 2 (PO 4 ) 3 with Enhanced Capacity journal September 2008
Relationship between short-range order and ease of nucleation in Na2Ca2Si3O9, CaSiO3 and PbSiO3 glasses journal February 2000
One-Pot Synthesized Bicontinuous Hierarchical Li 3 V 2 (PO 4 ) 3 /C Mesoporous Nanowires for High-Rate and Ultralong-Life Lithium-ion Batteries journal January 2014
Solvothermal Synthesis of LiMn 1– x Fe x PO 4 Cathode Materials: A Study of Reaction Mechanisms by Time-Resolved in Situ Synchrotron X-ray Diffraction journal January 2015
Li 2.5 V 2 (PO 4 ) 3 :  A Room-Temperature Analogue to the Fast-Ion Conducting High-Temperature γ-Phase of Li 3 V 2 (PO 4 ) 3 journal April 2004
A comparative study of Fd-3m and P4332 “LiNi0.5Mn1.5O4” journal June 2011
Atomistic Simulation Study of Monoclinic Li 3 V 2 (PO 4 ) 3 as a Cathode Material for Lithium Ion Battery: Structure, Defect Chemistry, Lithium Ion Transport Pathway, and Dynamics journal November 2012
Kinetic analysis on LiFePO4 thin films by CV, GITT, and EIS journal May 2011

Cited By (11)

In Situ Probing and Synthetic Control of Cationic Ordering in Ni-Rich Layered Oxide Cathodes journal October 2016
Rhombohedral Li2.4Na0.6V2(PO4)3@C nanoplates as high-rate and long-life cathode materials for lithium-ion batteries journal April 2018
Towards enhanced sodium storage by investigation of the Li ion doping and rearrangement mechanism in Na 3 V 2 (PO 4 ) 3 for sodium ion batteries journal January 2018
An Advanced All Phosphate Lithium-Ion Battery Providing High Electrochemical Stability, High Rate Capability and Long-Term Cycling Performance journal December 2016
Nanostructured Li 3 V 2 (PO 4 ) 3 Cathodes journal April 2018
F-Doping effects on carbon-coated Li 3 V 2 (PO 4 ) 3 as a cathode for high performance lithium rechargeable batteries: combined experimental and DFT studies journal January 2018
Atomic-scale structural and chemical evolution of Li3V2(PO4)3 cathode cycled at high voltage window journal May 2019
NASICON-Structured Materials for Energy Storage journal February 2017
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries journal January 2020
Organic-phase synthesis of Li 3 V 2 (PO 4 ) 3 @Carbon nanocrystals and their lithium storage properties journal January 2018
An Advanced All Phosphate Lithium-Ion Battery Providing High Electrochemical Stability, High Rate Capability and Long-Term Cycling Performance text January 2017

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