An ecosystem-scale perspective of the net land methanol flux: synthesis of micrometeorological flux measurements

Wohlfahrt, G.; Amelynck, C.; Ammann, Christof; Arneth, A.; Bamberger, Ines; Goldstein, Allen H.; Gu, Lianhong; Guenther, Alex B.; Hansel, A.; Heinesch, B.; Holst, Thomas; Hortnagl, Lukas; Karl, T.; Laffineur, Q.; Neftel, Albrecht; McKinney, Karena; Munger, William; Pallardy, Stephen G.; Schade, Gunner W.; Seco, Roger; Schoon, N.

doi:10.5194/acp-15-7413-2015

Title: An ecosystem-scale perspective of the net land methanol flux: synthesis of micrometeorological flux measurements

Journal Article · Thu Jul 09 00:00:00 EDT 2015 · Atmospheric Chemistry and Physics, 15(13):7413-7427

DOI:https://doi.org/10.5194/acp-15-7413-2015· OSTI ID:1221492

Wohlfahrt, G.; Amelynck, C.; Ammann, Christof; Arneth, A.; Bamberger, Ines; Goldstein, Allen H.; Gu, Lianhong; Guenther, Alex B.; Hansel, A.; Heinesch, B.; Holst, Thomas; Hortnagl, Lukas; Karl, T.; Laffineur, Q.; Neftel, Albrecht; McKinney, Karena; Munger, William; Pallardy, Stephen G.; Schade, Gunner W.; Seco, Roger more »

We present field observations made in June 2011 downwind of Dallas-Fort Worth, TX, and evaluate the role of stabilized Criegee radicals (sCIs) in gaseous sulfuric acid (H2SO4) production. Zero-dimensional model calculations show that sCI from BVOCs composed the majority of the sCIs. The main uncertainty associated with an evaluation of H2SO4 production from the sCI reaction channel is the lack of experimentally determined reaction rates for sCIs formed from isoprene ozonolysis with SO2. In general, the maximum of H2SO4 production from the sCI channel is found in the late afternoon as ozone increases towards the late afternoon. The sCI channel, however, contributes minor H2SO4 production compared with the conventional OH channel. Finally, The production and the loss rates of H2SO4 are compared. The application of the recommended mass accommodation coefficient causes significant overestimation of H2SO4 loss rates compared with H2SO4 production rates. On the other hand, the application of a lower experimental value for the mass accommodation coefficient provides good agreement between the loss and production rates of H2SO4. The results suggest that the recommended coefficient for the H2O surface may not be suitable for this relatively dry environment.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1221492

Report Number(s):: PNNL-SA-108336

Journal Information:: Atmospheric Chemistry and Physics, 15(13):7413-7427, Journal Name: Atmospheric Chemistry and Physics, 15(13):7413-7427

Country of Publication:: United States

Language:: English

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Acidotolerant Bacteria and Fungi as a Sink of Methanol-Derived Carbon in a Deciduous Forest Soil Morawe, Mareen; Hoeke, Henrike; Wissenbach, Dirk K. Frontiers in Microbiology, Vol. 8 https://doi.org/10.3389/fmicb.2017.01361	journal	July 2017
Modelling bidirectional fluxes of methanol and acetaldehyde with the FORCAsT canopy exchange model Ashworth, Kirsti; Chung, Serena H.; McKinney, Karena A. Atmospheric Chemistry and Physics, Vol. 16, Issue 24 https://doi.org/10.5194/acp-16-15461-2016	journal	January 2016
Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy Acton, W. Joe F.; Schallhart, Simon; Langford, Ben Atmospheric Chemistry and Physics, Vol. 16, Issue 11 https://doi.org/10.5194/acp-16-7149-2016	journal	January 2016
Anthropogenic and biogenic influence on VOC fluxes at an urban background site in Helsinki, Finland Rantala, Pekka; Järvi, Leena; Taipale, Risto Atmospheric Chemistry and Physics, Vol. 16, Issue 12 https://doi.org/10.5194/acp-16-7981-2016	journal	January 2016
Temporal variation of VOC fluxes measured with PTR-TOF above a boreal forest Schallhart, Simon; Rantala, Pekka; Kajos, Maija K. Atmospheric Chemistry and Physics, Vol. 18, Issue 2 https://doi.org/10.5194/acp-18-815-2018	journal	January 2018
Annual cycle of volatile organic compound exchange between a boreal pine forest and the atmosphere Rantala, P.; Aalto, J.; Taipale, R. Biogeosciences, Vol. 12, Issue 19 https://doi.org/10.5194/bg-12-5753-2015	journal	January 2015
Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy Acton, W. J. F.; Schallhart, S.; Langford, B. Atmospheric Chemistry and Physics Discussions https://doi.org/10.5194/acpd-15-29213-2015	posted_content	October 2015
Annual cycle of volatile organic compound exchange between a boreal pine forest and the atmosphere Rantala, P.; Aalto, J.; Taipale, R. Biogeosciences Discussions https://doi.org/10.5194/bgd-12-9543-2015	posted_content	June 2015
Temporal variation of VOC fluxes measured with PTR-TOF above a boreal forest Schallhart, Simon; Rantala, Pekka; Kajos, Maija K. Atmospheric Chemistry and Physics Discussions https://doi.org/10.5194/acp-2017-394	journal	June 2017

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