Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111
We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within approximate to 75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g(-1) and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H-2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.
- Sponsoring Organization:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI ID:
- 1211243
- Journal Information:
- ChemComm, Vol. 49, Issue 29; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
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