Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal-Organic Frameworks with High Surface Area

Liu, TF; Feng, DW; Chen, YP; Zou, LF; Bosch, M; Yuan, S; Wei, ZW; Fordham, S; Wang, KC; Zhou, HC

doi:10.1021/ja5111317

Title: Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal-Organic Frameworks with High Surface Area

Journal Article · Wed Jan 14 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja5111317· OSTI ID:1211174

Liu, TF; Feng, DW; Chen, YP; Zou, LF; Bosch, M; Yuan, S; Wei, ZW; Fordham, S; Wang, KC; Zhou, HC

Through a topology-guided strategy, a series of Zr-6-containing isoreticular porphyrinic metalorganic frameworks (MOFs), PCN-228, PCN-229, and PCN-230, with ftw-a topology were synthesized using the extended porphyrinic linkers. The bulky porphyrin ring ligand effectively prevents the network interpenetration which often appears in MOFs with increased linker length. The pore apertures of the structures range from 2.5 to 3.8 nm, and PCN-229 demonstrates the highest porosity and BET surface area among the previously reported Zr-MOFs. Additionally, by changing the relative direction of the terminal phenyl rings, this series replaces a Zr-8 cluster with a smaller Zr-6 cluster in a topologically identical framework. The high connectivity of the Zr-6 cluster yields frameworks with enhanced stability despite high porosity and ultralarge linker. As a representative example, PCN-230, constructed with the most extended porphyrinic linker, shows excellent stability in aqueous solutions with pH values ranging from 0 to 12 and demonstrates one of the highest pH tolerances among all porphyrinic MOFs. This work not only presents a successful example of rational design of MOFs with desired topology, but also provides a strategy for construction of stable mesoporous MOFs.

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Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: DE-AR0000249

OSTI ID:: 1211174

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 1; ISSN 0002-7863

Country of Publication:: United States

Language:: English

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Metal-Organic Framework Supported on Processable Polymer Matrix by In Situ Copolymerization for Enhanced Iron(III) Detection Liu, Chun-Sen; Chen, Min; Tian, Jia-Yue Chemistry - A European Journal, Vol. 23, Issue 16 https://doi.org/10.1002/chem.201604210	journal	January 2017
Synthesis, Structures and Fluorescence Properties of Two Novel Cadmium MOFs Based on a Tetraphenylethene(TPE)‐Core Ligand Xu, Xiu‐Dian; Liang, Yu; Mensah, Abraham ChemistrySelect, Vol. 4, Issue 42 https://doi.org/10.1002/slct.201902901	journal	November 2019
Facile synthesis of an ultra-stable metal–organic framework with excellent acid and base resistance Zhao, Nian; Li, Ping; Mu, Xin Faraday Discussions, Vol. 201 https://doi.org/10.1039/c7fd00017k	journal	January 2017
Isostructural functionalization by –OH and –NH ₂ : different contributions to CO ₂ adsorption Lu, Zhiyong; Xing, Yue; Du, Liting RSC Adv., Vol. 7, Issue 75 https://doi.org/10.1039/c7ra10369g	journal	January 2017
Out-of-Plane Coordinated Porphyrin Nanotubes with Enhanced Singlet Oxygen Generation Efficiency Zhao, Qiang; Wang, Yao; Xu, Yanshuang Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep31339	journal	August 2016
Why Design Matters: From Decorated Metal Oxide Clusters to Functional Metal–Organic Frameworks Schoedel, Alexander; Rajeh, Sahar Topics in Current Chemistry, Vol. 378, Issue 1 https://doi.org/10.1007/s41061-020-0281-0	journal	February 2020
Metal–organic and covalent organic frameworks as single-site catalysts Rogge, S. M. J.; Bavykina, A.; Hajek, J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00033b	journal	January 2017
Coordination polymers constructed from a tripodal phosphoryl carboxylate ligand: synthesis, structures and physical properties Yang, Yan-Yan; Lin, Zu-Jin; Liang, Jun CrystEngComm, Vol. 17, Issue 24 https://doi.org/10.1039/c5ce00430f	journal	January 2015
Improving MOF stability: approaches and applications Ding, Meili; Cai, Xuechao; Jiang, Hai-Long Chemical Science, Vol. 10, Issue 44 https://doi.org/10.1039/c9sc03916c	journal	January 2019
Structures and multiple properties of two polar metal–organic frameworks based on achiral N,O-coordinated ligands: toward multifunctional materials Liu, Guang-Ning; Zhang, Ming-Jian; Liu, Wan-Qing Dalton Transactions, Vol. 44, Issue 43 https://doi.org/10.1039/c5dt02374b	journal	January 2015
Applications of water stable metal–organic frameworks Wang, Chenghong; Liu, Xinlei; Keser Demir, Nilay Chemical Society Reviews, Vol. 45, Issue 18 https://doi.org/10.1039/c6cs00362a	journal	January 2016
Self-confined synthesis of HKUST-1 membranes from CuO nanosheets at room temperature Guo, Yi; Mao, Yiyin; Hu, Pan ChemistrySelect, Vol. 1, Issue 1 https://doi.org/10.1002/slct.201500010	journal	January 2016
Core-Shell Self-Doped Polyaniline Coated Metal-Organic-Framework (SPAN@UIO-66-NH ₂ ) Screen Printed Electrochemical Sensor for Cd ²⁺ Ions Zhao, Xiaoyu; Bai, Wenlong; Yan, Yujia Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0251912jes	journal	January 2019
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Chemical, thermal and mechanical stabilities of metal–organic frameworks Howarth, Ashlee J.; Liu, Yangyang; Li, Peng Nature Reviews Materials, Vol. 1, Issue 3 https://doi.org/10.1038/natrevmats.2015.18	journal	February 2016
A robust large-pore zirconium carboxylate metal–organic framework for energy-efficient water-sorption-driven refrigeration Wang, Sujing; Lee, Ji Sun; Wahiduzzaman, Mohammad Nature Energy, Vol. 3, Issue 11 https://doi.org/10.1038/s41560-018-0261-6	journal	October 2018
A robust indium–porphyrin framework for CO ₂ capture and chemical transformation Xu, Lei; Zhai, Meng-Ke; Lu, Xin-Chao Dalton Transactions, Vol. 45, Issue 46 https://doi.org/10.1039/c6dt03651a	journal	January 2016
A superstable 3p-block metal–organic framework platform towards prominent CO ₂ and C1/C2-hydrocarbon uptake and separation performance and strong Lewis acid catalysis for CO ₂ fixation Zhang, Jian-Wei; Ji, Wen-Juan; Hu, Man-Cheng Inorganic Chemistry Frontiers, Vol. 6, Issue 3 https://doi.org/10.1039/c8qi01396a	journal	January 2019
Mesoporous Metal-Organic Frameworks with Exceptionally High Working Capacities for Adsorption Heat Transformation Mo, Zong-Wen; Zhou, Hao-Long; Zhou, Dong-Dong Advanced Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adma.201704350	journal	December 2017
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A Comparison of Drug Delivery Systems of Zr‐Based MOFs and Halloysite Nanotubes: Evaluation of β‐Estradiol Encapsulation Luo, Ting; Liu, Hao; Liang, Yong ChemistrySelect, Vol. 4, Issue 31 https://doi.org/10.1002/slct.201901307	journal	August 2019
A complex metal-organic framework catalyst for microwave-assisted radical polymerization Nguyen, Ha L.; Vu, Thanh T.; Nguyen, Dinh-Khoi Communications Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s42004-018-0071-6	journal	October 2018
A stable and porous iridium( iii )-porphyrin metal–organic framework: synthesis, structure and catalysis Cui, Hao; Wang, Yingxia; Wang, Yanhu CrystEngComm, Vol. 18, Issue 12 https://doi.org/10.1039/c6ce00358c	journal	January 2016
Five new 3D transition MOFs based on 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid displaying unique luminescence sensing towards Fe ³⁺ and magnetic properties Liu, Wei-Ni; Tong, Wen-Quan; Ma, Lu-Lu Dalton Transactions, Vol. 48, Issue 22 https://doi.org/10.1039/c9dt00933g	journal	January 2019
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework Islamoglu, Timur; Otake, Ken-ichi; Li, Peng CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/c8ce00455b	journal	January 2018
A Water‐Stable Terbium(III)–Organic Framework as a Chemosensor for Inorganic Ions, Nitro‐Containing Compounds and Antibiotics in Aqueous Solutions Wei, Jun‐Hua; Yi, Jing‐Wei; Han, Min‐Le Chemistry – An Asian Journal, Vol. 14, Issue 20 https://doi.org/10.1002/asia.201900706	journal	July 2019
Mixed-linker strategy for the construction of multifunctional metal–organic frameworks Qin, Jun-Sheng; Yuan, Shuai; Wang, Qi Journal of Materials Chemistry A, Vol. 5, Issue 9 https://doi.org/10.1039/c6ta10281f	journal	January 2017
Hierarchical Porous Zr-Based MOFs Synthesized by a Facile Monocarboxylic Acid Etching Strategy Yang, Pengfei; Mao, Fangxin; Li, Yongsheng Chemistry - A European Journal, Vol. 24, Issue 12 https://doi.org/10.1002/chem.201705020	journal	February 2018
Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups Xu, Weixia; Zhang, Zengqi; Zhao, Xin Taylor & Francis https://doi.org/10.6084/m9.figshare.4286270.v1	text	January 2016
A Comparison of Two Isoreticular Metal–Organic Frameworks with Cationic and Neutral Skeletons: Stability, Mechanism, and Catalytic Activity Huang, Ge; Yang, Li; Yin, Qi Angewandte Chemie International Edition, Vol. 59, Issue 11 https://doi.org/10.1002/anie.201916649	journal	March 2020
Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups Xu, Weixia; Zhang, Zengqi; Zhao, Xin Taylor & Francis https://doi.org/10.6084/m9.figshare.4286270	text	January 2016

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