Materials Data on Sn2OF2 by Materials Project
Sn2OF2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two Sn2OF2 ribbons oriented in the (0, 0, 1) direction. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a rectangular see-saw-like geometry to two equivalent O2- and two equivalent F1- atoms. Both Sn–O bond lengths are 2.13 Å. Both Sn–F bond lengths are 2.41 Å. In the second Sn2+ site, Sn2+ is bonded in a 3-coordinate geometry to one O2- and two equivalent F1- atoms. The Sn–O bond length is 2.09 Å. Both Sn–F bond lengths are 2.18 Å. O2- is bonded in a distorted trigonal planar geometry to three Sn2+ atoms. F1- is bonded in a distorted bent 150 degrees geometry to two Sn2+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1201699
- Report Number(s):
- mp-27480
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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