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Title: Solid-state coexistence of {Zr12} and {Zr6} zirconium oxocarboxylate clusters

Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [1]
  1. RWTH Aachen Univ. (Germany)
  2. Iowa State Univ., Ames, IA (United States)
Publication Date:
OSTI Identifier:
1134147
Report Number(s):
IS--J 8212
Journal ID: ISSN 1466-8033
DOE Contract Number:
AC02-07CH11358
Resource Type:
Journal Article
Resource Relation:
Journal Name: CrystEngComm (Online); Journal Volume: 16; Journal Issue: 1 2014
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE