Solid-state coexistence of {Zr12} and {Zr6} zirconium oxocarboxylate clusters
- RWTH Aachen Univ. (Germany)
- Iowa State Univ., Ames, IA (United States)
Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- AC02-07CH11358
- OSTI ID:
- 1134147
- Report Number(s):
- IS-J 8212
- Journal Information:
- CrystEngComm (Online), Vol. 16, Issue 1 2014; ISSN 1466-8033
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
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