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Title: Substantial Cd-Cd Bonding in Ca6PtCd11: A Condensed Intermetallic Phase Built of Pentagonal Cd7 and Rectangular Cd4/2Pt Pyramids

The new trail-breaking compound Ca6PtCd11 has been synthesized and its structural and bonding properties investigated. This unusual phase features an unprecedented degree of cadmium aggregation, including linear chains, novel Cd7 PBP aggregates, and edge-shared chains of PtCd4/2 square pyramids. Manifestations of this chemistry elsewhere has evidently been precluded in earlier work by the inclusion of larger amounts of the strong d-metal bonding Au or Pt. Under the right conditions Cd seems quite effective as an open s,p-band metal.
Authors:
 [1] ;  [1] ;  [1]
  1. Ames Laboratory
Publication Date:
OSTI Identifier:
1132055
Report Number(s):
IS-J 8179
Journal ID: ISSN 0020-1669
DOE Contract Number:
DE-AC02-07CH11358
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 52; Journal Issue: 17
Publisher:
American Chemical Society (ACS)
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE Crystallography, Liquid Crystals