Thermodynamic Properties of Supported Catalysts
The goals of this work were to develop Coulometric Titration as a method for characterizing the thermodynamic redox properties of oxides and to apply this technique to the characterization of ceria- and vanadia-based catalysts. The redox properties of ceria and vanadia are a major part of what makes these materials catalytically active but their properties are also dependent on their structure and the presence of other oxides. Quantifying these properties through the measurement of oxidation energetics was the goal of this work.
- Research Organization:
- Raymond J. Gorte/University of Pennsylvania
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-85ER13350
- OSTI ID:
- 1124584
- Report Number(s):
- DE-Penn-13350
- Country of Publication:
- United States
- Language:
- English
Similar Records
A Thermodynamic Investigation of the Redox Properties of Ceria-Titania Mixed Oxides
Nanocrystalline Anatase Titania Supported Vanadia Catalysts: Facet-dependent Structure of Vanadia
(Experimental and kinetic modeling of acid/base redox reactions over metal oxide catalysts)
Journal Article
·
Tue Jan 01 00:00:00 EST 2008
· Applied Catalysis A: General
·
OSTI ID:1124584
Nanocrystalline Anatase Titania Supported Vanadia Catalysts: Facet-dependent Structure of Vanadia
Journal Article
·
Thu Jul 09 00:00:00 EDT 2015
· Journal of Physical Chemistry C, 119(27):15094−15102
·
OSTI ID:1124584
+4 more
(Experimental and kinetic modeling of acid/base redox reactions over metal oxide catalysts)
Technical Report
·
Mon Jan 01 00:00:00 EST 1990
·
OSTI ID:1124584