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Title: High elastic modulus polymer electrolytes

Patent ·
OSTI ID:1107608

A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1.times.10.sup.7 Pa and an ionic conductivity of at least 1.times.10.sup.-5 Scm.sup.-1. The electrolyte is made under dry conditions to achieve the noted characteristics.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231
Assignee:
The Regents of The University of California (Oakland, CA)
Patent Number(s):
8,563,168
Application Number:
12/225,934
OSTI ID:
1107608
Country of Publication:
United States
Language:
English

References (44)

Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes journal June 2007
Crosslinked polymer electrolyte membranes for heat and moisture exchange devices patent January 2005
Photosensitive cathode for deposition of metal structures within organic polymeric films patent April 1987
Polymer composition for encapsulation of electrode particles patent January 2008
Rubbery Block Copolymer Electrolytes for Solid-State Rechargeable Lithium Batteries journal January 1999
Shutdown battery separator made with a blend of polymer and oligomer patent June 2004
Solid Electrolyte Material Manufacturable by Polymer Processing Methods patent-application March 2009
All Solid-State Lithium-Polymer Battery Using a Self-Cross-Linking Polymer Electrolyte journal January 2003
Crosslinked polymer electrolyte compositions patent-application May 2003
Lithium cell patent June 1993
Ionically conductive composites for protection of active metal anodes patent October 2007
Solid electrolyte material manufacturable by polymer processing methods patent September 2012
Non-crosslinked, amorphous, block copolymer electrolyte for batteries patent April 2006
Lithium ion batteries with improved resistance to sustained self-heating patent August 2002
Preparation of crosslinked solid polymer electrolyte patent November 2001
Protected Lithium Metal Electrodes for Rechargeable Batteries patent-application February 2011
Blended polymer gel electrolytes patent August 1997
Actuator element and production method therefor patent January 2008
Multilayer electrolyte membrane patent-application August 2005
Crosslinked polymer electrolyte compositions patent January 2004
Phase Behavior of Lithium Perchlorate-Doped Poly(styrene- b -isoprene- b -ethylene oxide) Triblock Copolymers journal April 2002
Polymer composition for encapsulation of electrode particles patent-application February 2005
Method for making a polymeric electrolyte patent May 1991
Pentacyclic anion salts or tetrazapentalene derivatives and their uses as ionic conducting materials patent December 2004
Method and apparatus for fine particle liquid suspension feed for thermal spray system and coatings formed therefrom patent-application December 2006
Nanostructured Polymer Electrloytes with High Conductivity and Elastic Modulus for Li ion Batteries journal February 2006
Electrolyte permeable diaphragm patent January 1982
Cross-linked polymer solid electrolyte, method of manufacturing cross-linked solid polymer electrolyte, composite solid electrolyte, and thin solid cell employing composite solid electrolyte patent August 2000
Characteristics of new-type solid polymer electrolyte controlling nano-structure journal August 2005
Block copolymers of poly(ethylene oxide) materials for polymer electrolytes (transport properties) journal April 1993
Additives for extruding polymer electrolytes patent April 1997
Solid polymer electrolyte patent-application November 2005
Polymeric ion conductors patent March 1993
Ionically conductive material having a block copolymer as the solvent patent June 1996
Polyelectrolyte membrane and production method therefor patent-application October 2005
Double current collector cathode design using chemically similar active materials for alkali metal electrochemical patent June 2004
High-impact polyester/styrene-maleic anhydride copolymer blends patent April 1986
Lithium ion battery electrodes patent-application August 2004
Self-doped microphase separated block copolymer electrolyte patent March 2002
Solid electrolyte battery patent March 2003
Fluorinated comb-shaped polymers patent-application November 2006
High elastic modulus polymer electrolytes suitable for preventing thermal runaway in lithium batteries patent-application April 2009
ABA triblock comb copolymers with oligo(oxyethylene) side chains as matrix for ion transport journal May 1989
Ionically conductive polymer gels patent June 1997