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Title: Development of the Basis for an Analytical Protocol for Feeds and Products of Bio-oil Hydrotreatment

Journal Article · · Energy and Fuels
DOI:https://doi.org/10.1021/ef300252y· OSTI ID:1040669

Methods for easily following the main changes in the composition, stability, and acidity of bio-oil in hydrotreatment are presented. The correlation to more conventional methods is provided. Depending on the final use the upgrading requirement is different. This will create challenges also for the analytical protocol. Polar pyrolysis liquids and their products can be divided into five main groups with solvent fractionation the change in which is easy to follow. This method has over ten years been successfully used for comparison of fast pyrolysis bio-oil quality, and the changes during handling, and storage, provides the basis of the analytical protocol presented in this paper. The method has most recently been used also for characterisation of bio-oil hydrotreatment products. Discussion on the use of gas chromatographic and spectroscopic methods is provided. In addition, fuel oil analyses suitable for fast pyrolysis bio-oils and hydrotreatment products are discussed.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1040669
Report Number(s):
PNNL-SA-86357; ENFUEM; BM0101010; TRN: US201211%%33
Journal Information:
Energy and Fuels, Vol. 26, Issue 4; ISSN 0887-0624
Country of Publication:
United States
Language:
English