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Unlike nanostructured metal catalysts, supported single-atom catalysts (SACs) contain only atomically dispersed metal atoms, hinting at much more pronounced metal–support effects. Furthermore, we take a series of polyoxometalate-supported Pt catalysts as examples to quantitatively investigate the stability of Pt atoms on oxide supports and how the Pt–support interaction influences the catalytic performance. For this entire series, we show that the Pt atoms prefer to stay at a 4-fold hollow site of one polyoxometalate molecule and that the least adsorption energy to obtain sintering-resistant Pt SACs is 5.50 eV, which exactly matches the cohesive energy of bulk Pt metal. Further, wemore » compared their catalytic performance in several hydrogenation reactions and simulated the reaction pathways of propene hydrogenation by density functional theory (DFT) calculations. Both experimental and theoretical approaches suggest that despite the Pt₁–support interactions being different, the reaction pathways of various Pt₁–polyoxometalate catalysts are very similar and their effective reaction barriers are close to each other and as low as 24 kJ/mol, indicating the possibility of obtaining SACs with improved stability without compromising activity. DFT calculations show that all reaction elementary steps take place only on the Pt atom without involving neighboring O atoms and that hydrogenation proceeds from the molecularly adsorbed H₂ species. Pt SACs give a weaker H₂ adsorption energy than Pt clusters or surfaces, resulting in small adsorption equilibrium constants and small apparent activation barriers, which agree between experiment and theory.« less

Single-atom catalysts have recently been applied in many applications such as CO oxidation. Experimental in situ investigations into this reaction, however, are limited. Hereby, we present a suite of operando/in situ spectroscopic experiments for structurally well-defined atomically dispersed Rh on phosphotungstic acid during CO oxidation. The identification of several key intermediates and the steady-state catalyst structure indicate that the reactions follow an unconventional Mars-van Krevelen mechanism and that the activation of O₂ is rate-limiting. In situ XPS confirms the contribution of the heteropoly acid support while in situ DRIFT spectroscopy consolidates the oxidation state and CO adsorption of Rh. Asmore » such, direct observation of three key components, i.e., metal center, support and substrate, is achieved, providing a clearer picture on CO oxidation on atomically dispersed Rh sites. The obtained information are used to engineer structurally similar catalysts that exhibit T₂₀ values up to 130 °C below the previously reported Rh1/NPTA.« less