The Effects of Iron and Manganese Doping on the Carbonation of Brucite [Mg(OH)2]

Chung, Dong Youn; Weber, Juliane; Anovitz, Lawrence M.; Evans, Barbara R.; Yuan, Ke; Adapa, Sai Krishna Reddy; Boebinger, Matthew G.; McGuire, Michael A.; Hermann, Raphaël P.; Yumnam, George; Stubbs, Joanne E.; Eng, Peter J.; Heaney, Peter J.; Stack, Andrew G.

doi:10.1021/acs.jpcc.5c06987

Title: The Effects of Iron and Manganese Doping on the Carbonation of Brucite [Mg(OH)₂]

Journal Article · Mon Feb 02 00:00:00 UTC 2026 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.5c06987 · OSTI ID:3030335

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources (CARS)
Univ. of Chicago, IL (United States)
Pennsylvania State Univ., University Park, PA (United States)

Brucite [Mg(OH)₂] is a promising sorbent for carbon dioxide removal (CDR) due to its availability and low calcination temperatures. However, natural and synthetic brucites tend to contain metal impurities, such as iron or manganese, and how these impurities affect the interfacial chemical reactivity is uncertain. Here, in this study, the impact of low concentrations of iron and manganese impurities on the carbonation efficiency of Mg(OH)₂ was examined. Mg(OH)₂ with small amounts (1–5 mol %) of Fe and Mn was synthesized. The increasing substitution of Fe into Mg(OH)₂ was accompanied by the oxidation of Fe. The phase transformation sequence during the carbonation was found to be brucite [Mg(OH)₂] → amorphous magnesium carbonate (MgCO₃·nH₂O) → nesquehonite (MgCO₃·3H₂O), regardless of impurity concentration. Both the Fe- and Mn-doped Mg(OH)₂ samples were more reactive than endmember Mg(OH)₂, possibly due to their higher surface areas and lower stabilities. During carbonation, 3 mol % Fe- and Mn-doped Mg(OH)₂ showed the highest reactivity. The variance in reactivity for Mn-doped Mg(OH)₂ was less than that of Fe-doped Mg(OH)₂. These results suggest that natural or industrial waste Mg(OH)₂ with less than 5 mol % Fe and Mn impurities may be targeted as more effective CDR sorbents than endmember Mg(OH)₂.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

OSTI ID:: 3030335

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 6 Vol. 130; ISSN 1932-7455; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (89)

Hydroxylation Induced Alignment of Metal Oxide Nanocubes Thomele, Daniel; Bourret, Gilles R.; Bernardi, Johannes Angewandte Chemie International Edition, Vol. 56, Issue 5 https://doi.org/10.1002/anie.201608538	journal	December 2016
Next generation models of carbonate mineral growth and dissolution: Modeling and Analysis: Next generation models of carbonate mineral growth and dissolution Stack, Andrew G. Greenhouse Gases: Science and Technology, Vol. 4, Issue 3 https://doi.org/10.1002/ghg.1400	journal	January 2014
Valorisation of Ca and Mg by‐products from mining and seawater desalination brines for water treatment applications Casas, Sandra; Aladjem, Carlos; Larrotcha, Enric Journal of Chemical Technology & Biotechnology, Vol. 89, Issue 6 https://doi.org/10.1002/jctb.4326	journal	May 2014
Crystal‐field properties of Fe in brucite Mg(OH)₂ Blaauw, C.; Stroink, G.; Leiper, W. physica status solidi (b), Vol. 92, Issue 2 https://doi.org/10.1002/pssb.2220920238	journal	April 1979
Mossbauer study of brucite (Mg, Fe) (OH)2 Binfu, Xu; Yilong, Chen Wuhan University Journal of Natural Sciences, Vol. 4, Issue 1 https://doi.org/10.1007/BF02827620	journal	March 1999
Hydration of periclase at 350 ∘ C to 620 ∘ C and 200 MPa: experimental calibration of reaction rate Kuleci, H.; Schmidt, C.; Rybacki, E. Mineralogy and Petrology, Vol. 110, Issue 1 https://doi.org/10.1007/s00710-015-0414-2	journal	December 2015
The crystal structure of nesquehonite, MgCO 3 · 3H 2 O, from Lavrion, Greece Giester, G.; Lengauer, C. L.; Rieck, B. Mineralogy and Petrology, Vol. 70, Issue 3-4 https://doi.org/10.1007/s007100070001	journal	December 2000
Influence of additives, temperature, and pressure on the morphology of nesquehonite– results from three synthesis routes Back, Jens; Ismailov, Arnold; Sreenivasan, Harisankar Emergent Materials, Vol. 8, Issue 4 https://doi.org/10.1007/s42247-024-00968-8	journal	January 2025
Carbon dioxide disposal in carbonate minerals Lackner, Klaus S.; Wendt, Christopher H.; Butt, Darryl P. Energy, Vol. 20, Issue 11, p. 1153-1170 https://doi.org/10.1016/0360-5442(95)00071-N	journal	January 1995
Mechanisms of formation and structure of green rust one in aqueous corrosion of iron in the presence of chloride ions Refait, Ph.; Abdelmoula, M.; GÉnin, J. -M. R. Corrosion Science, Vol. 40, Issue 9 https://doi.org/10.1016/S0010-938X(98)00066-3	journal	September 1998
Impurities and nonstoichiometry in the bulk and on the (101̄4) surface of dolomite Wright, Kate; Cygan, Randall T.; Slater, Ben Geochimica et Cosmochimica Acta, Vol. 66, Issue 14 https://doi.org/10.1016/S0016-7037(02)00846-3	journal	July 2002
Progress on binding CO₂ in mineral substrates Lackner, Klaus S.; Butt, Darryl P.; Wendt, Christopher H. Energy Conversion and Management, Vol. 38, p. S259-S264 https://doi.org/10.1016/S0196-8904(96)00279-8	journal	January 1997
Thermal decomposition of dolomite and the extraction of its constituents Caceres, P. G.; Attiogbe, E. K. Minerals Engineering, Vol. 10, Issue 10 https://doi.org/10.1016/S0892-6875(97)00101-5	journal	October 1997
Physical and chemical effects of H2O on mineral carbonation reactions in supercritical CO2 Dong, Sijia; Xing, Tiange; Zhao, Liang Applied Geochemistry, Vol. 155 https://doi.org/10.1016/j.apgeochem.2023.105668	journal	August 2023
Nesquehonite as a carbon sink in ambient mineral carbonation of ultramafic mining wastes Entezari Zarandi, Ali; Larachi, Faïçal; Beaudoin, Georges Chemical Engineering Journal, Vol. 314 https://doi.org/10.1016/j.cej.2017.01.003	journal	April 2017
Controlled synthesis of MgO with diverse basic sites and its CO2 capture mechanism under different adsorption conditions Gao, Wanlin; Zhou, Tuantuan; Wang, Qiang Chemical Engineering Journal, Vol. 336 https://doi.org/10.1016/j.cej.2017.12.025	journal	March 2018
Direct formation of hierarchically porous MgO-based sorbent bead for enhanced CO2 capture at intermediate temperatures Jin, Seongmin; Ko, Kwang-Jun; Lee, Chang-Ha Chemical Engineering Journal, Vol. 371 https://doi.org/10.1016/j.cej.2019.04.020	journal	September 2019
Regenerable MgO-based sorbents for CO2 capture at elevated temperature and pressure: Experimental and DFT study Pang, Hua; Sun, Anwei; Xu, Haoran Chemical Engineering Journal, Vol. 425 https://doi.org/10.1016/j.cej.2021.130675	journal	December 2021
On the carbonation of brucite: Effects of Mg-acetate on the precipitation of hydrated magnesium carbonates in aqueous environment Nguyen, Hoang; Santos, Hellen; Sreenivasan, Harisankar Cement and Concrete Research, Vol. 153 https://doi.org/10.1016/j.cemconres.2021.106696	journal	March 2022
Thermochemical monitoring of brucite carbonation using passive infrared thermography Larachi, F.; Aksenova, D.; Yousefi, B. Chemical Engineering and Processing - Process Intensification, Vol. 130 https://doi.org/10.1016/j.cep.2018.05.019	journal	August 2018
Properties and applications of halloysite nanotubes: recent research advances and future prospects Yuan, Peng; Tan, Daoyong; Annabi-Bergaya, Faïza Applied Clay Science, Vol. 112-113 https://doi.org/10.1016/j.clay.2015.05.001	journal	August 2015
FeIII-substituted brucite: Hydrothermal synthesis from (Mg0.8FeII0.2)-brucite, crystal chemistry and relevance to the alteration of ultramafic rocks Carlin, William; Malvoisin, Benjamin; Lanson, Bruno Applied Clay Science, Vol. 234 https://doi.org/10.1016/j.clay.2023.106845	journal	March 2023
Carbon dioxide adsorption characteristics of synthesized MgO with various porous structures achieved by varying calcination temperature Song, Gan; Ding, Yu-Dong; Zhu, Xun Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 470 https://doi.org/10.1016/j.colsurfa.2015.01.061	journal	April 2015
Energy-saving calcination of hydromagnesite for sustainable magnesia-based cement: A new route towards MgO production Hu, Chuanlin; Liu, Yedongyang; Qian, Xiong Construction and Building Materials, Vol. 419 https://doi.org/10.1016/j.conbuildmat.2024.135593	journal	March 2024
Brucite [Mg(OH2)] carbonation in wet supercritical CO2: An in situ high pressure X-ray diffraction study Schaef, H. T.; Windisch, C. F.; McGrail, B. P. Geochimica et Cosmochimica Acta, Vol. 75, Issue 23 https://doi.org/10.1016/j.gca.2011.09.029	journal	December 2011
Influence of surface passivation and water content on mineral reactions in unsaturated porous media: Implications for brucite carbonation and CO2 sequestration Harrison, Anna L.; Dipple, Gregory M.; Power, Ian M. Geochimica et Cosmochimica Acta, Vol. 148 https://doi.org/10.1016/j.gca.2014.10.020	journal	January 2015
Multivariate study of the dynamics of CO 2 reaction with brucite-rich ultramafic mine tailings Entezari Zarandi, Ali; Larachi, Faïçal; Beaudoin, Georges International Journal of Greenhouse Gas Control, Vol. 52 https://doi.org/10.1016/j.ijggc.2016.06.022	journal	September 2016
Rates of atmospheric CO2 capture using magnesium oxide powder Rausis, Kwon; Stubbs, Amanda R.; Power, Ian M. International Journal of Greenhouse Gas Control, Vol. 119 https://doi.org/10.1016/j.ijggc.2022.103701	journal	September 2022
Passive direct air capture using calcium oxide powder: The importance of water vapor Dostie, Lance; Rausis, Kwon; Power, Ian M. Journal of Cleaner Production, Vol. 457 https://doi.org/10.1016/j.jclepro.2024.142394	journal	June 2024
Techno-economic study of a direct air capture system based on the carbonation of Ca(OH)2 plates integrated into cooling towers Hosseinpour, Mohammad; Hejazi, Bijan; Criado, Yolanda A. Journal of Cleaner Production, Vol. 486 https://doi.org/10.1016/j.jclepro.2024.144545	journal	January 2025
Carbon dioxide supply and scaling constraints on direct air capture using calcium oxide powder Dostie, Lance; Power, Ian M.; Rausis, Kwon Journal of Cleaner Production, Vol. 527 https://doi.org/10.1016/j.jclepro.2025.146635	journal	October 2025
Phase evolution during accelerated CO2 mineralization of brucite under concentrated CO2 and simulated flue gas conditions Rausis, Kwon; Ćwik, Agnieszka; Casanova, Ignasi Journal of CO2 Utilization, Vol. 37 https://doi.org/10.1016/j.jcou.2019.12.007	journal	April 2020
Microwave-driven carbonation of brucite Campione, Marcello; Corti, Mattia; D’Alessio, Daniela Journal of CO2 Utilization, Vol. 80 https://doi.org/10.1016/j.jcou.2024.102700	journal	February 2024
Efficient MgO-based mesoporous CO2 trapper and its performance at high temperature Han, Kun Kun; Zhou, Yu; Chun, Yuan Journal of Hazardous Materials, Vol. 203-204 https://doi.org/10.1016/j.jhazmat.2011.12.036	journal	February 2012
Brucite-driven CO2 uptake in serpentinized dunites (Ligurian Ophiolites, Montecastelli, Tuscany) Boschi, Chiara; Dini, Andrea; Baneschi, Ilaria Lithos, Vol. 288-289 https://doi.org/10.1016/j.lithos.2017.07.005	journal	September 2017
Mineralogy and geochemistry of hydrothermal sediments from the serpentinite-hosted Saldanha hydrothermal field (36°34′N; 33°26′W) at MAR Dias, Ágata S.; Barriga, Fernando J. A. S. Marine Geology, Vol. 225, Issue 1-4 https://doi.org/10.1016/j.margeo.2005.07.013	journal	January 2006
Synthesis and characterization of amorphous magnesium carbonate nanoparticles Yang, Jiaojiao; Han, Yuanyuan; Luo, Jun Materials Chemistry and Physics, Vol. 224 https://doi.org/10.1016/j.matchemphys.2018.12.037	journal	February 2019
Thermal decomposition process of dypingite Mg5(CO3)4(OH)2·5H2O Yamamoto, Gen-ichiro; Kyono, Atsushi; Okada, Satoru Materials Letters, Vol. 308 https://doi.org/10.1016/j.matlet.2021.131125	journal	February 2022
One-pot synthesis of foam-like magnesia and its performance in CO2 adsorption Han, Kun Kun; Zhou, Yu; Lin, Wei Gang Microporous and Mesoporous Materials, Vol. 169 https://doi.org/10.1016/j.micromeso.2012.11.004	journal	March 2013
Characteristics and optical properties of MgO nanowires synthesized by solvothermal method Hadia, N. M. A.; Mohamed, Hussein Abdel-Hafez Materials Science in Semiconductor Processing, Vol. 29 https://doi.org/10.1016/j.mssp.2014.03.049	journal	January 2015
The calcium looping cycle for large-scale CO2 capture Blamey, J.; Anthony, E. J.; Wang, J. Progress in Energy and Combustion Science, Vol. 36, Issue 2 https://doi.org/10.1016/j.pecs.2009.10.001	journal	April 2010
CO 2 utilization: Developments in conversion processes Alper, Erdogan; Yuksel Orhan, Ozge Petroleum, Vol. 3, Issue 1 https://doi.org/10.1016/j.petlm.2016.11.003	journal	March 2017
A review of mineral carbonation technology in sequestration of CO2 Olajire, Abass A. Journal of Petroleum Science and Engineering, Vol. 109 https://doi.org/10.1016/j.petrol.2013.03.013	journal	September 2013
Synthesis and characterization of nesquehonite (MgCO3·3H2O) powders from natural talc Ding, Wenjin; Ouyang, Jing; Yang, Huaming Powder Technology, Vol. 292 https://doi.org/10.1016/j.powtec.2016.01.037	journal	May 2016
Characterization of Mg(OH)2 powders produced from real saltworks bitterns at a pilot scale Battaglia, G.; Ventimiglia, L.; Vicari, F. Powder Technology, Vol. 443 https://doi.org/10.1016/j.powtec.2024.119918	journal	July 2024
Reviewing direct air capture startups and emerging technologies Wang, Eryu; Navik, Rahul; Miao, Yihe Cell Reports Physical Science, Vol. 5, Issue 2 https://doi.org/10.1016/j.xcrp.2024.101791	journal	February 2024
The Role of Operating Conditions in the Precipitation of Magnesium Hydroxide Hexagonal Platelets Using NaOH Solutions Romano, Salvatore; Trespi, Silvio; Achermann, Ramona Crystal Growth & Design, Vol. 23, Issue 9 https://doi.org/10.1021/acs.cgd.3c00462	journal	August 2023
Water Activity Controls the Stability of Amorphous Ca–Mg- and Mg-Carbonates Patel, Avni S.; Raudsepp, Maija J.; Wilson, Sasha Crystal Growth & Design, Vol. 24, Issue 5 https://doi.org/10.1021/acs.cgd.3c01283	journal	February 2024
CO₂ Capture at Medium to High Temperature Using Solid Oxide-Based Sorbents: Fundamental Aspects, Mechanistic Insights, and Recent Advances Dunstan, Matthew T.; Donat, Felix; Bork, Alexander H. Chemical Reviews, Vol. 121, Issue 20 https://doi.org/10.1021/acs.chemrev.1c00100	journal	August 2021
Armoring of MgO by a Passivation Layer Impedes Direct Air Capture of CO₂ Weber, Juliane; Starchenko, Vitalii; Yuan, Ke Environmental Science & Technology, Vol. 57, Issue 40 https://doi.org/10.1021/acs.est.3c04690	journal	September 2023
Influence of Iron Substitution and Solution Composition on Brucite Carbonation Vessey, Colton J.; Raudsepp, Maija J.; Patel, Avni S. Environmental Science & Technology, Vol. 58, Issue 18 https://doi.org/10.1021/acs.est.3c08708	journal	April 2024
Evolution Process of Ferroan Brucite under Humid Conditions with CO₂ and O₂ Zhao, Shifeng; Zhao, Yanping; Wu, Zhiming The Journal of Physical Chemistry C, Vol. 127, Issue 33 https://doi.org/10.1021/acs.jpcc.3c03422	journal	August 2023
Influence of Dissolved Iron in Solution on MgO Hydroxylation and Carbonation Weber, Juliane; Moseley, Brittany; Yuan, Ke The Journal of Physical Chemistry C, Vol. 129, Issue 1 https://doi.org/10.1021/acs.jpcc.4c04953	journal	December 2024
Water Film-Driven Brucite Nanosheet Growth and Stacking Luong, N. Tan; Boily, Jean-François Langmuir, Vol. 39, Issue 31 https://doi.org/10.1021/acs.langmuir.3c01411	journal	July 2023
Reaction Layer Formation on MgO in the Presence of Humidity Bracco, Jacquelyn N.; Camacho Meneses, Gabriela; Colón, Omar ACS Applied Materials & Interfaces, Vol. 16, Issue 1 https://doi.org/10.1021/acsami.3c14823	journal	December 2023
Synthetic Architecture of MgO/C Nanocomposite from Hierarchical-Structured Coordination Polymer toward Enhanced CO₂ Capture Li, Ping; Liu, Wen; Dennis, John S. ACS Applied Materials & Interfaces, Vol. 9, Issue 11 https://doi.org/10.1021/acsami.6b14960	journal	March 2017
Carbon Sequestration Kinetic and Storage Capacity of Ultramafic Mining Waste Pronost, Julie; Beaudoin, Georges; Tremblay, Joniel Environmental Science & Technology, Vol. 45, Issue 21 https://doi.org/10.1021/es203063a	journal	October 2011
Accelerated Carbonation of Brucite in Mine Tailings for Carbon Sequestration Harrison, Anna L.; Power, Ian M.; Dipple, Gregory M. Environmental Science & Technology, Vol. 47, Issue 1 https://doi.org/10.1021/es3012854	journal	July 2012
Aqueous Carbonation of Natural Brucite: Relevance to CO ₂ Sequestration Zhao, Liang; Sang, Liqin; Chen, Jun Environmental Science & Technology, Vol. 44, Issue 1 https://doi.org/10.1021/es9017656	journal	January 2010
Thermodynamic Equilibria in Aqueous Suspensions of Synthetic and Natural Fe(II)−Fe(III) Green Rusts: Occurrences of the Mineral in Hydromorphic Soils Génin, Jean-Marie R.; Bourrié, Guilhem; Trolard, Fabienne Environmental Science & Technology, Vol. 32, Issue 8 https://doi.org/10.1021/es970547m	journal	April 1998
CO ₂ Capture Capacity of CaO in Long Series of Carbonation/Calcination Cycles Grasa, Gemma S.; Abanades, J. Carlos Industrial & Engineering Chemistry Research, Vol. 45, Issue 26 https://doi.org/10.1021/ie0606946	journal	December 2006
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide Loring, John S.; Thompson, Christopher J.; Zhang, Changyong The Journal of Physical Chemistry A, Vol. 116, Issue 19 https://doi.org/10.1021/jp210020t	journal	May 2012
Structural, Electronic, and Mechanical Properties of Single-Walled Chrysotile Nanotube Models Lourenço, Maicon P.; de Oliveira, Claudio; Oliveira, Augusto F. The Journal of Physical Chemistry C, Vol. 116, Issue 17 https://doi.org/10.1021/jp301048p	journal	April 2012
A fossil, serpentinization-related hydrothermal vent, Ocean Drilling Program Leg 173, Site 1068 (Iberia Abyssal Plain): Some aspects of mineral and fluid chemistry Beard, James S.; Hopkinson, Laurence Journal of Geophysical Research: Solid Earth, Vol. 105, Issue B7 https://doi.org/10.1029/2000JB900073	journal	July 2000
Mixed‐Mode Strain Localization Generated by Hydration Reaction at Crustal Conditions Zheng, Xiaojiao; Cordonnier, Benoît; McBeck, Jessica Journal of Geophysical Research: Solid Earth, Vol. 124, Issue 5 https://doi.org/10.1029/2018JB017008	journal	May 2019
The negative emission potential of alkaline materials Renforth, Phil Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09475-5	journal	March 2019
Ambient weathering of magnesium oxide for CO2 removal from air McQueen, Noah; Kelemen, Peter; Dipple, Greg Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16510-3	journal	July 2020
Effect of multiple calcination cycles on CO2 capture efficiency during carbonation of MgO in a mineral looping process Tajuelo Rodriguez, Elena; Anovitz, Lawrence M.; Adapa, Sai Scientific Reports, Vol. 15, Issue 1 https://doi.org/10.1038/s41598-025-23708-2	journal	November 2025
Importance of Mineralogy in the Geoenvironmental Characterization and Treatment of Chromite Ore Processing Residue Chrysochoou, Maria; Dermatas, Dimitris; Grubb, Dennis G. Journal of Geotechnical and Geoenvironmental Engineering, Vol. 136, Issue 3 https://doi.org/10.1061/(ASCE)GT.1943-5606.0000233	journal	March 2010
Manganese oxide minerals: Crystal structures and economic and environmental significance Post, J. E. Proceedings of the National Academy of Sciences, Vol. 96, Issue 7 https://doi.org/10.1073/pnas.96.7.3447	journal	March 1999
Dana's System of Mineralogy. 7. Ed Palache, Ch.; Berman, H.; Frondel, C. Geologiska Föreningen i Stockholm Förhandlingar, Vol. 74, Issue 2 https://doi.org/10.1080/11035895209453366	journal	January 1952
Reactive crystallisation process for magnesium recovery from concentrated brines Cipollina, A.; Bevacqua, M.; Dolcimascolo, P. Desalination and Water Treatment, Vol. 55, Issue 9 https://doi.org/10.1080/19443994.2014.947771	journal	September 2014
A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future McQueen, Noah; Gomes, Katherine Vaz; McCormick, Colin Progress in Energy, Vol. 3, Issue 3 https://doi.org/10.1088/2516-1083/abf1ce	journal	April 2021
Formation and loss of metastable brucite: does Fe(II)-bearing brucite support microbial activity in serpentinizing ecosystems? Templeton, A. S.; Ellison, E. T. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 378, Issue 2165 https://doi.org/10.1098/rsta.2018.0423	journal	January 2020
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Isothermal Time-Series Determination of the Rate of Diffusion of Water in Pachuca Obsidian* Anovitz, L. M.; Elam, J. M.; Riciputi, L. R. Archaeometry, Vol. 46, Issue 2 https://doi.org/10.1111/j.1475-4754.2004.00159.x	journal	May 2004
The Stability of Brucite in the Weathering Zone of the New Idria Serpentinite Mumpton, F. A.; Thompson, C. S. Clays and Clay Minerals, Vol. 14 https://doi.org/10.1346/CCMN.1966.0140122	journal	February 1966
Critical review of analytical applications of Mössbauer spectroscopy illustrated by mineralogical and geological examples (IUPAC Technical Report) Kuzmann, E.; Nagy, S.; Vértes, A. Pure and Applied Chemistry, Vol. 75, Issue 6 https://doi.org/10.1351/pac200375060801	journal	January 2003
Deposits of the manganese oxides Hewett, Donnel Foster; Fleischer, Michael Economic Geology, Vol. 55, Issue 1 https://doi.org/10.2113/gsecongeo.55.1.1	journal	January 1960
The nuclear and magnetic structure of “white rust”—Fe(OH _0.86 D _0.14 ) ₂ Parise, John B.; Marshall, William G.; Smith, Ronald I. American Mineralogist, Vol. 85, Issue 1 https://doi.org/10.2138/am-2000-0118	journal	January 2000
The crystal structure of feitknechtite (β-MnOOH) and a new MnOOH polymorph Post, Jeffrey E.; Heaney, Peter J.; Ilton, Eugene S. American Mineralogist, Vol. 108, Issue 11 https://doi.org/10.2138/am-2022-8729	journal	November 2023
Carbon Mineralization: From Natural Analogues to Engineered Systems Power, I. M.; Harrison, A. L.; Dipple, G. M. Reviews in Mineralogy and Geochemistry, Vol. 77, Issue 1 https://doi.org/10.2138/rmg.2013.77.9	journal	January 2013
Pore-Scale Controls on Reaction-Driven Fracturing Røyne, Anja; Jamtveit, Bjørn Reviews in Mineralogy and Geochemistry, Vol. 80, Issue 1 https://doi.org/10.2138/rmg.2015.80.02	journal	January 2015
MgO-based cements – Current status and opportunities Bernard, Ellina; Nguyen, Hoang; Kawashima, Shiho RILEM Technical Letters, Vol. 8 https://doi.org/10.21809/rilemtechlett.2023.177	journal	November 2023
Assessment of the physical and chemical qualities of brine and the application of nano zerovalent iron for the treatment of brine effluent Alegbe, M. J.; Ayanda, O. S.; Ndungu, P. Desalination and Water Treatment, Vol. 102 https://doi.org/10.5004/dwt.2018.21862	journal	January 2018

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Carbon dioxide removal
Mg(OH)2 (brucite)
carbon sequestration
direct air capture via enhanced weathering
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mineral looping

Title: The Effects of Iron and Manganese Doping on the Carbonation of Brucite [Mg(OH)2]

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Title: The Effects of Iron and Manganese Doping on the Carbonation of Brucite [Mg(OH)₂]