Double Perovskite Interlayer Stabilized Highly Efficient Perovskite Solar Cells

Xiang, Wenjun; Cronk, Ethan; Wall, Jacob; Li, Lin; Zhu, Kai; Berry, Joseph J.; Lad, Robert J.; Yu, Liping; Yan, Feng

doi:10.1021/acsami.4c10378

Title: Double Perovskite Interlayer Stabilized Highly Efficient Perovskite Solar Cells

Journal Article · Mon Aug 19 00:00:00 UTC 2024 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.4c10378 · OSTI ID:3029983

Xiang, Wenjun ^[1]; Cronk, Ethan ^[2]; Wall, Jacob ^[1];

^[1];

^[3];

^[4]; Lad, Robert J. ^[2];

^[5];

^[1]

Arizona State Univ., Tempe, AZ (United States)
Univ. of Maine, Orono, ME (United States)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Univ. of Colorado, Boulder, CO (United States)
Univ. of Maine, Orono, ME (United States); Univ. of Central Florida, Orlando, FL (United States)

Metal halide perovskite solar cell (PSC) technology has an impressive power conversion efficiency (PCE) exceeding 26.1% and demonstrates cost-effective manufacturing. However, the stability of these PSCs poses a significant challenge, hindering their widespread manufacturing and commercialization. To tackle the degradation issue inherent in PSCs, surface passivation techniques, particularly employing a thin layer of two-dimensional (2D) perovskites, create a 2D/3D heterostructure. Beyond this, the exploration of metal halide double perovskites adds a new dimension to the chemical and band gap phase space of materials for optoelectronic applications. In this study, we leverage a wide band gap double perovskite interlayer to enhance the stability of 3D metal halide perovskite. Specifically, the double perovskite nanoparticle Cs₂AgBiBr₆, with its substantial band gap of 2.2 eV and exceptional air stability, is utilized. Through optimization, a Cs₂AgBiBr₆-treated PSC achieves an open-circuit voltage of 1.12 V and an impressive PCE of 19.52%. Additionally, the Cs₂AgBiBr₆ passivation layer proves to be effective in bolstering the stability of PSCs. This work demonstrates an additional strategy and design motif to simultaneously increase the PCE of PSCs along with achieving improved stability.

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Research Organization:: Arizona State Univ., Scottsdale, AZ (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308; EE0009833

OSTI ID:: 3029983

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 34 Vol. 16; ISSN 1944-8244; ISSN 1944-8252

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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