Hydration and transport properties of cesium hydroxide and mixed cesium hydroxide–sodium nitrite aqueous solutions

Reynolds, Jacob G.; Nienhuis-Marcial, Emily T.; Graham, Trent R.; Kennedy, Ashley R.; Mergelsberg, Sebastian T.; Bazak, Jonathan David; Pearce, Carolyn I.

doi:10.1063/5.0316284

Title: Hydration and transport properties of cesium hydroxide and mixed cesium hydroxide–sodium nitrite aqueous solutions

Journal Article · Mon Feb 23 00:00:00 UTC 2026 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/5.0316284 · OSTI ID:3028288

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Hanford Site (HNF), Richland, WA (United States). Central Plateau Cleanup Company (CPCCo)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)

Here, this study explores the hydration and transport properties of aqueous cesium hydroxide (CsOH) solution, with or without 1 molar (M) sodium nitrite (NaNO₂). Historic studies of electrolyte solutions indicate that Cs⁺ ions decrease viscosity and increase diffusion rates, whereas OH⁻ ions have the opposite effect. Here, the influence of OH⁻ was dominant in CsOH solutions, leading to increased viscosity and reduced diffusion rates. There was a linear relationship between diffusion coefficients and water activity, emphasizing the significant role of ion–water interactions in determining transport properties. This may be because the interaction between Cs⁺ and the anions is weak even when they are in direct contact with each other. The weakness of the ion-pairing was established through thermodynamic analysis. The findings suggest that ion-pairing is not the only important interaction controlling transport properties when ion-pairing is weak. Nonetheless, ion-pairing or obstructions did result in more sluggish transport properties as electrolyte concentrations increased. Overall, the research enhances the understanding of the complexities underlying ion interactions in multicomponent solutions.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Environmental Management (EM); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 3028288

Report Number(s):: PNNL-SA-219458

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 8 Vol. 164; ISSN 1089-7690; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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