Direct Oxidation of Primary Alcohols to Carboxylic Acids

Williams, Travis J.; Cherepakhin, Valeriy

doi:10.1055/s-0040-1706102

Title: Direct Oxidation of Primary Alcohols to Carboxylic Acids

Journal Article · Thu Dec 17 00:00:00 UTC 2020 · Synthesis

DOI: https://doi.org/10.1055/s-0040-1706102 · OSTI ID:3021435

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University of Southern California, Los Angeles, CA (United States)

Oxidation of primary alcohols to carboxylic acids is a fundamental transformation in organic chemistry, yet despite its simplicity, extensive use, and relationship to pH, it remains a subject of active research for synthetic organic chemists. Since 2013, a great number of new methods have emerged that utilize transition-metal compounds as catalysts for acceptorless dehydrogenation of alcohols to carboxylates. The interest in this reaction is explained by its atom economy, which is in accord with the principles of sustainability and green chemistry. Furthermore, the methods for the direct synthesis of carboxylic acids from alcohols is ripe for a modern survey, which we provide in this review.

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Research Organization:: University of Southern California, Los Angeles, CA (United States)

Sponsoring Organization:: US National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008825

OSTI ID:: 3021435

Journal Information:: Synthesis, Journal Name: Synthesis Journal Issue: 06 Vol. 53; ISSN 1437-210X; ISSN 0039-7881

Publisher:: Georg Thieme Verlag KGCopyright Statement

Country of Publication:: United States

Language:: English

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