A Guide to Nonaqueous Electrochemistry of f-Element Complexes

Niklas, Julie E.; Duffy, Matilda I.; La Pierre, Henry S.

doi:10.1021/acs.inorgchem.5c05041

Title: A Guide to Nonaqueous Electrochemistry of f-Element Complexes

Journal Article · Mon Feb 09 00:00:00 UTC 2026 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.5c05041 · OSTI ID:3020520

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Georgia Institute of Technology, Atlanta, GA (United States)
Georgia Institute of Technology, Atlanta, GA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Electrochemistry is a powerful tool for assessing and understanding the redox chemistry of molecular complexes. Cyclic voltammetry enables the f-element community to study molecules in unusually high or low oxidation states, which potentially pose important broad-scope questions of electronic structure. In the pursuit of boundary-pushing compounds, reactive air- and moisture-sensitive species are often encountered, which can be challenging to characterize, especially when they are chemically incompatible with certain solvents, electrolytes, or electrodes or when their potentials lie outside of common electrochemical windows. Nonaqueous solvents and pseudo reference electrodes complicate many of the standard practices in acquiring high-quality and reproducible electrochemical data. This guide presents a detailed discussion of selecting appropriate cell conditions and referencing and addresses metrics for evaluating electrochemical and chemical reversibility. These methodological approaches have been extended to best practices for the electrochemical analysis of radioactive transuranic complexes.

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Research Organization:: Georgia Inst. of Technology, Atlanta, GA (United States); Georgia Tech Research Corporation, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019385

OSTI ID:: 3020520

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 7 Vol. 65; ISSN 0020-1669; ISSN 1520-510X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: A Guide to Nonaqueous Electrochemistry of f-Element Complexes

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