Fe0.6Pd0.4Te2 : A New Polymorph of FeTe2 and PdTe2 Stable at Ambient Pressure

Wang, Wanping; Tian, Jianjun; Tong, Xiao; Ogunbunmi, Michael O.; Fu, Yang; Hu, Zhixiang; Bobev, Svilen; Sljivancanin, Zeljko; Lei, Hechang; Zhang, Weifeng; Petrovic, Cedomir

doi:10.1021/acs.inorgchem.5c02764

Title: Fe_0.6Pd_0.4Te₂ : A New Polymorph of FeTe₂ and PdTe₂ Stable at Ambient Pressure

Journal Article · Mon Dec 01 00:00:00 UTC 2025 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.5c02764 · OSTI ID:3014634

Wang, Wanping ^[1];

^[2];

^[3];

^[4]; Fu, Yang ^[5]; Hu, Zhixiang ^[5];

^[6];

^[7]; Lei, Hechang ^[8]; Zhang, Weifeng ^[2];

^[9]

Henan Univ., Kaifeng (China); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Beijing (China)
Henan Univ., Kaifeng (China)
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Univ. of Delaware, Newark, DE (United States); Xavier Univ. of Louisiana, New Orleans, LA (United States)
Center for High Pressure Science and Technology Advanced Research (HPSTAR), Beijing (China)
Univ. of Delaware, Newark, DE (United States)
Univ. of Belgrade (Serbia). Institute of Nuclear Science
Renmin Univ. of China, Beijing (China)
Shanghai Advanced Research in Physical Sciences (SHARPS) (China); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Beijing (China); Univ. of Belgrade (Serbia). Institute of Nuclear Science; Brookhaven National Laboratory (BNL), Upton, NY (United States)

Whereas pyrite space group is a high pressure polymorph of FeTe₂, here we report pyrite-type single crystal Fe_0.6Pd_0.4Te₂ prepared using Pd substitution on Fe atomic site with ambient pressure crystal growth methods. Here, Fe_0.6(1)Pd_0.4(1)Te₂ single crystals show metal behavior above 15 K abided by Bloch-Grüneisen relation, and display resistivity upturn below 15 K due to disorder-related scattering of correlated electronic states.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: SC0008885; SC0012704

OSTI ID:: 3014634

Report Number(s):: BNL--229360-2026-JAAM

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 49 Vol. 64; ISSN 0020-1669; ISSN 1520-510X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Fe_0.6Pd_0.4Te₂ : A New Polymorph of FeTe₂ and PdTe₂ Stable at Ambient Pressure