Interfacial Hydrophilicity Controls Mineral Transformation Outcomes for Enstatite and Amorphous MgSiO3

Hardee, Landon J.; Schaef, Herbert Todd; Barpaga, Dushyant; Stanfield, Charles Heath; Crum, Jarrod V.; Anovitz, Lawrence M.; Rosso, Kevin M.; Miller, Quin R. S.; Aguila-Ames, Briana A.

doi:10.1021/acs.estlett.5c00487

Title: Interfacial Hydrophilicity Controls Mineral Transformation Outcomes for Enstatite and Amorphous MgSiO₃

Journal Article · Tue Jul 08 00:00:00 UTC 2025 · Environmental Science & Technology Letters (Online)

DOI: https://doi.org/10.1021/acs.estlett.5c00487 · OSTI ID:3014258

Hardee, Landon J. ^[1];

^[1];

^[2];

^[1];

^[3]

Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
New College of Florida, Sarasota, FL (United States)

Subsurface injection of carbon dioxide (CO₂) into mafic-ultramafic rocks for permanent storage via mineralization is being studied to reduce emissions. Here, we investigated the carbonation products of enstatite (MgSiO₃) to assess its efficiency in sequestering CO₂ for safe and permanent storage as carbonate minerals. This was accomplished by conducting variable temperature carbonation reactions with samples of differing crystallinities and surface chemistries. Reaction progress was monitored utilizing in situ X-ray diffraction, and the presence of carbonate products was confirmed using additional techniques, such as thermogravimetric analysis coupled with mass spectrometry and scanning electron microscopy with energy dispersive spectrometry. Our results show that crystalline enstatite produces small amounts of the anhydrous form of MgCO₃ (magnesite), while amorphous MgSiO₃, which was used to simulate mafic glass, more readily converts to the hydrated/hydroxylated hydromagnesite [Mg₅(CO₃)₄(OH)₂·4H₂O]. These results, supplemented with dynamic vapor sorption experiments, suggest that surface properties play a significant role in the pathway and degree of carbonation. These developments concerning the reactivity of CO₂ with reactive mafic phases will help further our understanding of the reactivity of these mafic-ultramafic minerals with implications for permanent carbon storage and other subsurface engineering scenarios involving reactive reservoirs.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 3014258

Report Number(s):: PNNL-SA--213035

Journal Information:: Environmental Science & Technology Letters (Online), Journal Name: Environmental Science & Technology Letters (Online) Journal Issue: 8 Vol. 12; ISSN 2328-8930

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (200)

Permeability, porosity, and mineral surface area changes in basalt cores induced by reactive transport of CO ₂ -rich brine : PHYSICAL CHANGES FROM REACTION IN BASALT Luhmann, Andrew J.; Tutolo, Benjamin M.; Bagley, Brian C. Water Resources Research, Vol. 53, Issue 3 https://doi.org/10.1002/2016WR019216	journal	March 2017
Kinetics and Mechanisms of ZnO to ZIF‐8 Transformations in Supercritical CO ₂ Revealed by In Situ X‐ray Diffraction Sinnwell, Michael A.; Miller, Quin R. S.; Liu, Lili ChemSusChem, Vol. 13, Issue 10 https://doi.org/10.1002/cssc.202000434	journal	May 2020
The US department of Energy's R&D program to reduce greenhouse gas emissions through beneficial uses of carbon dioxide Damiani, Darin; Litynski, John T.; McIlvried, Howard G. Greenhouse Gases: Science and Technology, Vol. 2, Issue 1 https://doi.org/10.1002/ghg.35	journal	October 2011
Changes in elastic wave velocity and rock microstructure due to basalt-CO₂-water reactions Adam, Ludmila; van Wijk, Kasper; Otheim, Thomas Journal of Geophysical Research: Solid Earth, Vol. 118, Issue 8 https://doi.org/10.1002/jgrb.50302	journal	August 2013
Dissolution Mechanisms of Pyroxenes and Olivines During Weathering Schott, Jacques; Berner, Robert A. The Chemistry of Weathering https://doi.org/10.1007/978-94-009-5333-8_3	book	January 1985
A Comparison of Forsterite and Enstatite Dissolution Rates and Mechanisms Oelkers, Eric H. Growth, Dissolution and Pattern Formation in Geosystems https://doi.org/10.1007/978-94-015-9179-9_12	book	January 1999
Carbon dioxide sequestration by direct mineral carbonation: process mineralogy of feed and products O’Connor, W. K.; Dahlin, D. C.; Rush, G. E. Mining, Metallurgy & Exploration, Vol. 19, Issue 2 https://doi.org/10.1007/BF03403262	journal	May 2002
A Phase-Partitioning Model for CO2–Brine Mixtures at Elevated Temperatures and Pressures: Application to CO2-Enhanced Geothermal Systems Spycher, Nicolas; Pruess, Karsten Transport in Porous Media, Vol. 82, Issue 1 https://doi.org/10.1007/s11242-009-9425-y	journal	July 2009
Modeling and assessment of CO2 geological storage in the Eastern Deccan Basalt of India Liu, Danqing; Agarwal, Ramesh; Liu, Fang Environmental Science and Pollution Research, Vol. 29, Issue 56 https://doi.org/10.1007/s11356-022-21757-y	journal	July 2022
Thermodynamic Modelling and Experimental Validation of CO2 Mineral Sequestration in Mandla Basalt of the Eastern Deccan Volcanic Province, India Kumar, Amit; Shrivastava, J. P. Journal of the Geological Society of India, Vol. 93, Issue 3 https://doi.org/10.1007/s12594-019-1173-1	journal	March 2019
Effect of carbon dioxide sequestration on the mechanical properties of Deccan basalt Guha Roy, Debanjan; Vishal, Vikram; Singh, Trilok Nath Environmental Earth Sciences, Vol. 75, Issue 9 https://doi.org/10.1007/s12665-016-5587-4	journal	April 2016
Mechanism of pyroxene and amphibole weathering—I. Experimental studies of iron-free minerals Schott, Jacques; Berner, Robert A.; Sjöberg, E. Lennart Geochimica et Cosmochimica Acta, Vol. 45, Issue 11 https://doi.org/10.1016/0016-7037(81)90065-X	journal	November 1981
Silicate mineral dissolution at pH 4 and near standard temperature and pressure Siegel, D. I.; Pfannkuch, H. O. Geochimica et Cosmochimica Acta, Vol. 48, Issue 1 https://doi.org/10.1016/0016-7037(84)90362-4	journal	January 1984
Olivine dissolution at 25°C: Effects of pH, CO2, and organic acids Wogelius, Roy A.; Walther, John V. Geochimica et Cosmochimica Acta, Vol. 55, Issue 4 https://doi.org/10.1016/0016-7037(91)90153-V	journal	April 1991
Weathering, plants, and the long-term carbon cycle Berner, Robert A. Geochimica et Cosmochimica Acta, Vol. 56, Issue 8 https://doi.org/10.1016/0016-7037(92)90300-8	journal	August 1992
Diopside dissolution kinetics as a function of pH, CO2, temperature, and time Knauss, Kevin G.; Nguyen, Son N.; Weed, Homer C. Geochimica et Cosmochimica Acta, Vol. 57, Issue 2 https://doi.org/10.1016/0016-7037(93)90431-U	journal	January 1993
A model for water adsorption in activated carbon Do, D. D.; Do, H. D. Carbon, Vol. 38, Issue 5 https://doi.org/10.1016/S0008-6223(99)00159-1	journal	January 2000
Diopside and anthophyllite dissolution at 25° and 90°C and acid pH Chen, Yang; Brantley, Susan L. Chemical Geology, Vol. 147, Issue 3-4 https://doi.org/10.1016/S0009-2541(98)00016-3	journal	May 1998
An experimental study of enstatite dissolution rates as a function of pH, temperature, and aqueous Mg and Si concentration, and the mechanism of pyroxene/pyroxenoid dissolution Oelkers, Eric H.; Schott, Jacques Geochimica et Cosmochimica Acta, Vol. 65, Issue 8 https://doi.org/10.1016/S0016-7037(00)00564-0	journal	April 2001
Mineral carbonation reactions under water-saturated, hydrothermal-like conditions and numerical simulations of CO2 sequestration in tholeiitic basalt of the Eastern Deccan Volcanic Province, India Kumar, Amit; Shrivastava, J. P.; Pathak, Vamdev Applied Geochemistry, Vol. 84 https://doi.org/10.1016/j.apgeochem.2017.05.021	journal	September 2017
Carbon sequestration via enhanced weathering of peridotites and basalts in seawater Rigopoulos, Ioannis; Harrison, Anna L.; Delimitis, Andreas Applied Geochemistry, Vol. 91 https://doi.org/10.1016/j.apgeochem.2017.11.001	journal	April 2018
Migration of transition metals and potential for carbon mineralization during acid leaching of processed kimberlite from Venetia diamond mine, South Africa Wang, Baolin; Zeyen, Nina; Wilson, Sasha Applied Geochemistry, Vol. 166 https://doi.org/10.1016/j.apgeochem.2024.105986	journal	May 2024
Kinetic evaluation of mineral carbonation of natural silicate samples Wang, Fei; Dreisinger, David; Jarvis, Mark Chemical Engineering Journal, Vol. 404 https://doi.org/10.1016/j.cej.2020.126522	journal	January 2021
An integrated process of CO₂ mineralization and selective nickel and cobalt recovery from olivine and laterites Wang, Fei; Dreisinger, David Chemical Engineering Journal, Vol. 451, 139002 https://doi.org/10.1016/j.cej.2022.139002	journal	January 2023
Mechanisms of aqueous wollastonite carbonation as a possible CO2 sequestration process Huijgen, Wouter J. J.; Witkamp, Geert-Jan; Comans, Rob N. J. Chemical Engineering Science, Vol. 61, Issue 13 https://doi.org/10.1016/j.ces.2006.01.048	journal	July 2006
CO2 sequestration by high pressure reaction with olivine in a rocking batch autoclave Turri, Laura; Muhr, Hervé; Rijnsburger, Keesjan Chemical Engineering Science, Vol. 171 https://doi.org/10.1016/j.ces.2017.05.009	journal	November 2017
Basalt weathering laws and the impact of basalt weathering on the global carbon cycle Dessert, Céline; Dupré, Bernard; Gaillardet, Jérôme Chemical Geology, Vol. 202, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2002.10.001	journal	December 2003
Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide Giammar, Daniel E.; Bruant, Robert G.; Peters, Catherine A. Chemical Geology, Vol. 217, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2004.12.013	journal	April 2005
Carbonation of Ca-bearing silicates, the case of wollastonite: Experimental investigations and kinetic modeling Daval, Damien; Martinez, Isabelle; Corvisier, Jérôme Chemical Geology, Vol. 265, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2009.01.022	journal	July 2009
Influence of amorphous silica layer formation on the dissolution rate of olivine at 90°C and elevated pCO2 Daval, Damien; Sissmann, Olivier; Menguy, Nicolas Chemical Geology, Vol. 284, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2011.02.021	journal	May 2011
Reaction path modeling of enhanced in situ CO2 mineralization for carbon sequestration in the peridotite of the Samail Ophiolite, Sultanate of Oman Paukert, Amelia N.; Matter, Jürg M.; Kelemen, Peter B. Chemical Geology, Vol. 330-331 https://doi.org/10.1016/j.chemgeo.2012.08.013	journal	November 2012
In situ sequestration of atmospheric CO2 at low temperature and surface cracking of serpentinized peridotite in mine shafts Beinlich, Andreas; Austrheim, Håkon Chemical Geology, Vol. 332-333 https://doi.org/10.1016/j.chemgeo.2012.09.015	journal	November 2012
Fayalite dissolution and siderite formation in water-saturated supercritical CO2 Qafoku, Odeta; Kovarik, Libor; Kukkadapu, Ravi K. Chemical Geology, Vol. 332-333 https://doi.org/10.1016/j.chemgeo.2012.09.028	journal	November 2012
Microstructure and porosity evolution during experimental carbonation of a natural peridotite Hövelmann, Jörn; Austrheim, Håkon; Jamtveit, Bjørn Chemical Geology, Vol. 334 https://doi.org/10.1016/j.chemgeo.2012.10.025	journal	December 2012
Do carbonate precipitates affect dissolution kinetics? Stockmann, Gabrielle J.; Wolff-Boenisch, Domenik; Gislason, Sigurdur R. Chemical Geology, Vol. 337-338 https://doi.org/10.1016/j.chemgeo.2012.11.014	journal	January 2013
Simultaneous precipitation of magnesite and lizardite from hydrothermal alteration of olivine under high-carbonate alkalinity Lafay, Romain; Montes-Hernandez, German; Janots, Emilie Chemical Geology, Vol. 368 https://doi.org/10.1016/j.chemgeo.2014.01.008	journal	March 2014
Olivine dissolution and carbonation under conditions relevant for in situ carbon storage Johnson, Natalie C.; Thomas, Burt; Maher, Kate Chemical Geology, Vol. 373 https://doi.org/10.1016/j.chemgeo.2014.02.026	journal	May 2014
Whole rock basalt alteration from CO2-rich brine during flow-through experiments at 150 °C and 150 bar Luhmann, Andrew J.; Tutolo, Benjamin M.; Tan, Chunyang Chemical Geology, Vol. 453 https://doi.org/10.1016/j.chemgeo.2017.02.002	journal	March 2017
Dissolution and surface roughening of Columbia River flood basalt at geologic carbon sequestration conditions Wells, Rachel K.; Xiong, Wei; Giammar, Daniel Chemical Geology, Vol. 467 https://doi.org/10.1016/j.chemgeo.2017.07.028	journal	September 2017
Multi-scale characterization of the incipient carbonation of peridotite Peuble, Steve; Andreani, Muriel; Gouze, Philippe Chemical Geology, Vol. 476 https://doi.org/10.1016/j.chemgeo.2017.11.013	journal	January 2018
Olivine dissolution rates: A critical review Oelkers, Eric H.; Declercq, Julien; Saldi, Giuseppe D. Chemical Geology, Vol. 500 https://doi.org/10.1016/j.chemgeo.2018.10.008	journal	November 2018
Reaction of pseudowollastonite with carbonate-bearing fluids: Implications for CO2 mineral sequestration Monasterio-Guillot, Luis; Di Lorenzo, Fulvio; Ruiz-Agudo, Encarnacion Chemical Geology, Vol. 524 https://doi.org/10.1016/j.chemgeo.2019.06.011	journal	October 2019
A comprehensive and internally consistent mineral dissolution rate database: Part I: Primary silicate minerals and glasses Heřmanská, Matylda; Voigt, Martin J.; Marieni, Chiara Chemical Geology, Vol. 597 https://doi.org/10.1016/j.chemgeo.2022.120807	journal	May 2022
Mineral carbonation process for CO2 sequestration Prigiobbe, V.; Hänchen, M.; Werner, M. Energy Procedia, Vol. 1, Issue 1 https://doi.org/10.1016/j.egypro.2009.02.318	journal	February 2009
Basalt Reactivity Variability with Reservoir Depth in Supercritical CO2 and Aqueous Phases Schaef, H. T.; McGrail, B. P.; Owen, A. T. Energy Procedia, Vol. 4 https://doi.org/10.1016/j.egypro.2011.02.468	journal	January 2011
The Wallula basalt sequestration pilot project McGrail, B. P.; Spane, F. A.; Sullivan, E. C. Energy Procedia, Vol. 4 https://doi.org/10.1016/j.egypro.2011.02.557	journal	January 2011
Silicate Carbonation in Supercritical CO2 Containing Dissolved H2O: An in situ High Pressure X-Ray Diffraction and Infrared Spectroscopy Study Schaef, Ht; Miller, Qrs; Thompson, Cj Energy Procedia, Vol. 37 https://doi.org/10.1016/j.egypro.2013.06.514	journal	January 2013
Injection and Monitoring at the Wallula Basalt Pilot Project McGrail, B. P.; Spane, F. A.; Amonette, J. E. Energy Procedia, Vol. 63 https://doi.org/10.1016/j.egypro.2014.11.316	journal	January 2014
Wallula Basalt Pilot Demonstration Project: Post-injection Results and Conclusions McGrail, B. P.; Schaef, H. T.; Spane, F. A. Energy Procedia, Vol. 114 https://doi.org/10.1016/j.egypro.2017.03.1716	journal	July 2017
In situ carbon mineralization in ultramafic rocks: Natural processes and possible engineered methods Kelemen, P. B.; Aines, R.; Bennett, E. Energy Procedia, Vol. 146 https://doi.org/10.1016/j.egypro.2018.07.013	journal	July 2018
A simple model of reaction-induced cracking applied to serpentinization and carbonation of peridotite Rudge, John F.; Kelemen, Peter B.; Spiegelman, Marc Earth and Planetary Science Letters, Vol. 291, Issue 1-4 https://doi.org/10.1016/j.epsl.2010.01.016	journal	March 2010
From serpentinization to carbonation: New insights from a CO2 injection experiment Klein, Frieder; McCollom, Thomas M. Earth and Planetary Science Letters, Vol. 379 https://doi.org/10.1016/j.epsl.2013.08.017	journal	October 2013
Elucidating the differences in the carbon mineralization behaviors of calcium and magnesium bearing alumino-silicates and magnesium silicates for CO2 storage Gadikota, Greeshma; Matter, Juerg; Kelemen, Peter Fuel, Vol. 277 https://doi.org/10.1016/j.fuel.2020.117900	journal	October 2020
CO2 mineral sequestration and nickel recovery from laterite ore by using waste copperas Gao, Yuxiang; Jin, Xi; Teng, Liumei Fuel, Vol. 331 https://doi.org/10.1016/j.fuel.2022.125750	journal	January 2023
Water-Alternating-Gas (WAG) injection scheme for enhancement of carbon dioxide mineralization in basaltic aquifers Awolayo, Adedapo N.; Norton, Heather; de Obeso, Juan Carlos Fuel, Vol. 385 https://doi.org/10.1016/j.fuel.2024.134127	journal	April 2025
Magnesite growth rates as a function of temperature and saturation state Saldi, Giuseppe D.; Jordan, Guntram; Schott, Jacques Geochimica et Cosmochimica Acta, Vol. 73, Issue 19 https://doi.org/10.1016/j.gca.2009.06.035	journal	October 2009
Dissolution kinetics of diopside as a function of solution saturation state: Macroscopic measurements and implications for modeling of geological storage of CO2 Daval, Damien; Hellmann, Roland; Corvisier, Jérôme Geochimica et Cosmochimica Acta, Vol. 74, Issue 9 https://doi.org/10.1016/j.gca.2010.02.003	journal	May 2010
Experimental study of the carbonation of partially serpentinized and weathered peridotites Hövelmann, Jörn; Austrheim, Håkon; Beinlich, Andreas Geochimica et Cosmochimica Acta, Vol. 75, Issue 22 https://doi.org/10.1016/j.gca.2011.08.032	journal	November 2011
Olivine reactivity with CO2 and H2O on a microscale: Implications for carbon sequestration Olsson, J.; Bovet, N.; Makovicky, E. Geochimica et Cosmochimica Acta, Vol. 77 https://doi.org/10.1016/j.gca.2011.11.001	journal	January 2012
Reaction of water-saturated supercritical CO2 with forsterite: Evidence for magnesite formation at low temperatures Felmy, Andrew R.; Qafoku, Odeta; Arey, Bruce W. Geochimica et Cosmochimica Acta, Vol. 91 https://doi.org/10.1016/j.gca.2012.05.026	journal	August 2012
Systematic review of forsterite dissolution rate data Rimstidt, J. Donald; Brantley, Susan L.; Olsen, Amanda A. Geochimica et Cosmochimica Acta, Vol. 99 https://doi.org/10.1016/j.gca.2012.09.019	journal	December 2012
Peridotite dissolution and carbonation rates at fracture surfaces under conditions relevant for in situ mineralization of CO2 van Noort, R.; Spiers, C. J.; Drury, M. R. Geochimica et Cosmochimica Acta, Vol. 106 https://doi.org/10.1016/j.gca.2012.12.001	journal	April 2013
Linking nm-scale measurements of the anisotropy of silicate surface reactivity to macroscopic dissolution rate laws: New insights based on diopside Daval, Damien; Hellmann, Roland; Saldi, Giuseppe D. Geochimica et Cosmochimica Acta, Vol. 107 https://doi.org/10.1016/j.gca.2012.12.045	journal	April 2013
Formation of submicron magnesite during reaction of natural forsterite in H2O-saturated supercritical CO2 Qafoku, Odeta; Hu, Jianzhi; Hess, Nancy J. Geochimica et Cosmochimica Acta, Vol. 134 https://doi.org/10.1016/j.gca.2013.09.024	journal	June 2014
Carbonation rates of peridotite in the Samail Ophiolite, Sultanate of Oman, constrained through 14C dating and stable isotopes Mervine, Evelyn M.; Humphris, Susan E.; Sims, Kenneth W. W. Geochimica et Cosmochimica Acta, Vol. 126 https://doi.org/10.1016/j.gca.2013.11.007	journal	February 2014
Geochemistry and petrology of listvenite in the Samail ophiolite, Sultanate of Oman: Complete carbonation of peridotite during ophiolite emplacement Falk, Elisabeth S.; Kelemen, Peter B. Geochimica et Cosmochimica Acta, Vol. 160 https://doi.org/10.1016/j.gca.2015.03.014	journal	July 2015
Competitive sorption of CO2 and H2O in 2:1 layer phyllosilicates Schaef, Herbert T.; Loring, John S.; Glezakou, Vassiliki-Alexandra Geochimica et Cosmochimica Acta, Vol. 161 https://doi.org/10.1016/j.gca.2015.03.027	journal	July 2015
Temperature trends for reaction rates, hydrogen generation, and partitioning of iron during experimental serpentinization of olivine McCollom, Thomas M.; Klein, Frieder; Robbins, Mark Geochimica et Cosmochimica Acta, Vol. 181 https://doi.org/10.1016/j.gca.2016.03.002	journal	May 2016
Experimental study of carbonate formation in oceanic peridotite Grozeva, Niya G.; Klein, Frieder; Seewald, Jeffrey S. Geochimica et Cosmochimica Acta, Vol. 199 https://doi.org/10.1016/j.gca.2016.10.052	journal	February 2017
Spatially-variable carbonation reactions in polycrystalline olivine Wells, Rachel K.; Xiong, Wei; Sesti, Erika Geochimica et Cosmochimica Acta, Vol. 204 https://doi.org/10.1016/j.gca.2017.02.003	journal	May 2017
Tracing olivine carbonation and serpentinization in CO2-rich fluids via magnesium exchange and isotopic fractionation Přikryl, Jan; Stefánsson, Andri; Pearce, Christopher R. Geochimica et Cosmochimica Acta, Vol. 243 https://doi.org/10.1016/j.gca.2018.09.022	journal	December 2018
Aqueous alteration of pyroxene in sulfate, chloride, and perchlorate brines: Implications for post-Noachian aqueous alteration on Mars Phillips-Lander, Charity M.; Elwood Madden, Andrew S.; Hausrath, Elisabeth M. Geochimica et Cosmochimica Acta, Vol. 257 https://doi.org/10.1016/j.gca.2019.05.006	journal	July 2019
Metastable solubility and local structure of amorphous calcium carbonate (ACC) Mergelsberg, Sebastian T.; De Yoreo, James J.; Miller, Quin R. S. Geochimica et Cosmochimica Acta, Vol. 289 https://doi.org/10.1016/j.gca.2020.06.030	journal	November 2020
In-situ water-immersion experiments on amorphous silicates in the MgO–SiO2 system: implications for the onset of aqueous alteration in primitive meteorites Igami, Yohei; Tsuchiyama, Akira; Yamazaki, Tomoya Geochimica et Cosmochimica Acta, Vol. 293 https://doi.org/10.1016/j.gca.2020.10.023	journal	January 2021
Carbonation of calcium-magnesium pyroxenes: Physical-chemical controls and effects of reaction-driven fracturing Monasterio-Guillot, L.; Fernandez-Martinez, A.; Ruiz-Agudo, E. Geochimica et Cosmochimica Acta, Vol. 304 https://doi.org/10.1016/j.gca.2021.02.016	journal	July 2021
Mineralisation of atmospheric CO2 in hydromagnesite in ultramafic mine tailings – Insights from Mg isotopes Oskierski, Hans C.; Turvey, Connor C.; Wilson, Sasha Geochimica et Cosmochimica Acta, Vol. 309 https://doi.org/10.1016/j.gca.2021.06.020	journal	September 2021
Mineral surface area accessibility and sensitivity constraints on carbon mineralization in basaltic aquifers Awolayo, Adedapo N.; Laureijs, Christiaan T.; Byng, John Geochimica et Cosmochimica Acta, Vol. 334 https://doi.org/10.1016/j.gca.2022.08.011	journal	October 2022
Reactions between olivine and CO2-rich seawater at 300 °C: Implications for H2 generation and CO2 sequestration on the early Earth Ueda, Hisahiro; Sawaki, Yusuke; Maruyama, Shigenori Geoscience Frontiers, Vol. 8, Issue 2 https://doi.org/10.1016/j.gsf.2016.10.002	journal	March 2017
The mechanism of dissolution of forsterite, olivine and minerals of the orthosilicate group Crundwell, F. K. Hydrometallurgy, Vol. 150 https://doi.org/10.1016/j.hydromet.2014.09.006	journal	December 2014
Carbonate mineralization of volcanic province basalts Schaef, H. T.; McGrail, B. P.; Owen, A. T. International Journal of Greenhouse Gas Control, Vol. 4, Issue 2 https://doi.org/10.1016/j.ijggc.2009.10.009	journal	March 2010
Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids Miller, Q. R. S.; Thompson, C. J.; Loring, J. S. International Journal of Greenhouse Gas Control, Vol. 15 https://doi.org/10.1016/j.ijggc.2013.02.005	journal	July 2013
Mineralization of basalts in the CO2–H2O–H2S system Schaef, H. T.; McGrail, B. P.; Owen, A. T. International Journal of Greenhouse Gas Control, Vol. 16 https://doi.org/10.1016/j.ijggc.2013.03.020	journal	August 2013
Offsetting of CO2 emissions by air capture in mine tailings at the Mount Keith Nickel Mine, Western Australia: Rates, controls and prospects for carbon neutral mining Wilson, Siobhan A.; Harrison, Anna L.; Dipple, Gregory M. International Journal of Greenhouse Gas Control, Vol. 25 https://doi.org/10.1016/j.ijggc.2014.04.002	journal	June 2014
Effect of transport limitations and fluid properties on reaction products in fractures of unaltered and serpentinized basalt exposed to high PCO fluids Adeoye, Jubilee T.; Menefee, Anne H.; Xiong, Wei International Journal of Greenhouse Gas Control, Vol. 63 https://doi.org/10.1016/j.ijggc.2017.06.003	journal	August 2017
CO2 mineral trapping in fractured basalt Xiong, Wei; Wells, Rachel K.; Menefee, Anne H. International Journal of Greenhouse Gas Control, Vol. 66 https://doi.org/10.1016/j.ijggc.2017.10.003	journal	November 2017
Fate of transition metals during passive carbonation of ultramafic mine tailings via air capture with potential for metal resource recovery Hamilton, Jessica L.; Wilson, Siobhan A.; Morgan, Bree International Journal of Greenhouse Gas Control, Vol. 71 https://doi.org/10.1016/j.ijggc.2018.02.008	journal	April 2018
Simulation of CO2 mineral trapping and permeability alteration in fractured basalt: Implications for geologic carbon sequestration in mafic reservoirs Wu, Hao; Jayne, Richard S.; Bodnar, Robert J. International Journal of Greenhouse Gas Control, Vol. 109 https://doi.org/10.1016/j.ijggc.2021.103383	journal	July 2021
Evaluation and site selection for carbon storage via shallow CO2 injection into serpentinite in British Columbia, Canada Steinthorsdottir, Katrin; Rahimi, Mana; Dipple, Gregory M. International Journal of Greenhouse Gas Control, Vol. 137 https://doi.org/10.1016/j.ijggc.2024.104222	journal	September 2024
Water-alternating-gas injections for optimized mineral carbon storage in basalt Nelson, Claire J.; Goldberg, David S.; White, Mark D. International Journal of Greenhouse Gas Control, Vol. 141 https://doi.org/10.1016/j.ijggc.2024.104283	journal	February 2025
Nano-scale synthesis of the complex silicate minerals forsterite and enstatite Anovitz, Lawrence M.; Rondinone, Adam J.; Sochalski-Kolbus, Lindsay Journal of Colloid and Interface Science, Vol. 495 https://doi.org/10.1016/j.jcis.2017.01.052	journal	June 2017
Accelerated CO2 mineralization and utilization for selective battery metals recovery from olivine and laterites Wang, Fei; Dreisinger, David; Xiao, Yuchang Journal of Cleaner Production, Vol. 393 https://doi.org/10.1016/j.jclepro.2023.136345	journal	March 2023
Thermodynamic constraints on mineral carbonation of serpentinized peridotite Klein, Frieder; Garrido, Carlos J. Lithos, Vol. 126, Issue 3-4 https://doi.org/10.1016/j.lithos.2011.07.020	journal	October 2011
Carbonation of mantle peridotite by CO2-rich fluids: the formation of listvenites in the Advocate ophiolite complex (Newfoundland, Canada) Menzel, Manuel D.; Garrido, Carlos J.; López Sánchez-Vizcaíno, Vicente Lithos, Vol. 323 https://doi.org/10.1016/j.lithos.2018.06.001	journal	December 2018
A critical meta-analysis of CO2-water-rock interaction in basalt for CO2 storage: A review based on global and Indian perspective Singh, Rahul Kumar; Nayak, Nirlipta P.; Kumar, Sanjeev Marine and Petroleum Geology, Vol. 168 https://doi.org/10.1016/j.marpetgeo.2024.107002	journal	October 2024
CO2 storage in geological media: Role, means, status and barriers to deployment Bachu, S. Progress in Energy and Combustion Science, Vol. 34, Issue 2 https://doi.org/10.1016/j.pecs.2007.10.001	journal	April 2008
Can East African rift basalts sequester CO2? Case study of the Kenya rift Okoko, George Otieno; Olaka, Lydia A. Scientific African, Vol. 13 https://doi.org/10.1016/j.sciaf.2021.e00924	journal	September 2021
Enhanced CO2 mineralization and selective critical metal extraction from olivine and laterites Wang, Fei; Dreisinger, David Separation and Purification Technology, Vol. 321 https://doi.org/10.1016/j.seppur.2023.124268	journal	September 2023
Pressurized in situ X-ray diffraction insights into super/subcritical carbonation reaction pathways of steelmaking slags and constituent silicate minerals Chai, Ye Eun; Miller, Quin R. S.; Schaef, H. Todd The Journal of Supercritical Fluids, Vol. 171 https://doi.org/10.1016/j.supflu.2021.105191	journal	May 2021
Parts-Per-Million Carbonate Mineral Quantification with Thermogravimetric Analysis–Mass Spectrometry Bartels, Madeline F.; Miller, Quin R. S.; Cao, Ruoshi Analytical Chemistry, Vol. 96, Issue 11 https://doi.org/10.1021/acs.analchem.3c03936	journal	February 2024
Critical Water Coverage during Forsterite Carbonation in Thin Water Films: Activating Dissolution and Mass Transport Placencia-Gómez, Edmundo; Kerisit, Sebastien N.; Mehta, Hardeep S. Environmental Science & Technology, Vol. 54, Issue 11 https://doi.org/10.1021/acs.est.0c00897	journal	May 2020
Quantification of CO ₂ Mineralization at the Wallula Basalt Pilot Project White, Signe K.; Spane, Frank A.; Schaef, H. Todd Environmental Science & Technology, Vol. 54, Issue 22 https://doi.org/10.1021/acs.est.0c05142	journal	September 2020
Alkalinity Generation Constraints on Basalt Carbonation for Carbon Dioxide Removal at the Gigaton-per-Year Scale Tutolo, Benjamin M.; Awolayo, Adedapo; Brown, Calista Environmental Science & Technology, Vol. 55, Issue 17 https://doi.org/10.1021/acs.est.1c02733	journal	August 2021
Thin Water Films Enable Low-Temperature Magnesite Growth Under Conditions Relevant to Geologic Carbon Sequestration Kerisit, Sebastien N.; Mergelsberg, Sebastian T.; Thompson, Christopher J. Environmental Science & Technology, Vol. 55, Issue 18 https://doi.org/10.1021/acs.est.1c03370	journal	September 2021
Exotic Carbonate Mineralization Recovered from a Deep Basalt Carbon Storage Demonstration Polites, Ellen G.; Schaef, H. Todd; Horner, Jake A. Environmental Science & Technology, Vol. 56, Issue 20 https://doi.org/10.1021/acs.est.2c03269	journal	September 2022
Facile Metal Release from Pore-Lining Phases Enables Unique Carbonate Zonation in a Basalt Carbon Mineralization Demonstration Lahiri, Nabajit; Miller, Quin R. S.; Cao, Ruoshi Environmental Science & Technology, Vol. 57, Issue 32 https://doi.org/10.1021/acs.est.3c02075	journal	July 2023
The Mining Industry’s Role in Enhanced Weathering and Mineralization for CO₂ Removal Power, Ian M.; Paulo, Carlos; Rausis, Kwon Environmental Science & Technology, Vol. 58, Issue 1 https://doi.org/10.1021/acs.est.3c05081	journal	December 2023
3D Quantification of Pore Networks and Anthropogenic Carbon Mineralization in Stacked Basalt Reservoirs Battu, Anil K.; Miller, Quin R. S.; Cao, Ruoshi Environmental Science & Technology, Vol. 58, Issue 8 https://doi.org/10.1021/acs.est.3c06163	journal	February 2024
Carbon Sequestration in Olivine and Basalt Powder Packed Beds Xiong, Wei; Wells, Rachel K.; Giammar, Daniel E. Environmental Science & Technology, Vol. 51, Issue 4 https://doi.org/10.1021/acs.est.6b05011	journal	January 2017
Tunable Manipulation of Mineral Carbonation Kinetics in Nanoscale Water Films via Citrate Additives Miller, Quin R. S.; Schaef, Herbert T.; Kaszuba, John P. Environmental Science & Technology, Vol. 52, Issue 12 https://doi.org/10.1021/acs.est.8b00438	journal	May 2018
Permanent CO ₂ Trapping through Localized and Chemical Gradient-Driven Basalt Carbonation Menefee, Anne H.; Giammar, Daniel E.; Ellis, Brian R. Environmental Science & Technology, Vol. 52, Issue 15 https://doi.org/10.1021/acs.est.8b01814	journal	June 2018
Nanoscale Mg-Depleted Layers Slow Carbonation of Forsterite (Mg₂SiO₄) When Water Is Limited Mergelsberg, Sebastian T.; Rajan, Bavan P.; Legg, Benjamin A. Environmental Science & Technology Letters, Vol. 10, Issue 1 https://doi.org/10.1021/acs.estlett.2c00866	journal	December 2022
Resolving Nanoscale Processes during Carbon Mineralization Using Identical Location Transmission Electron Microscopy Li, Xiaoxu; Nienhuis, Emily T.; Nagurney, Alexandra B. Environmental Science & Technology Letters, Vol. 11, Issue 2 https://doi.org/10.1021/acs.estlett.3c00699	journal	December 2023
Field Validation of Supercritical CO ₂ Reactivity with Basalts McGrail, B. Peter; Schaef, Herbert T.; Spane, Frank A. Environmental Science & Technology Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acs.estlett.6b00387	journal	November 2016
CO ₂ Mineral Sequestration in Naturally Porous Basalt Xiong, Wei; Wells, Rachel K.; Horner, Jake A. Environmental Science & Technology Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acs.estlett.8b00047	journal	February 2018
Quantitative Review of Olivine Carbonation Kinetics: Reactivity Trends, Mechanistic Insights, and Research Frontiers Miller, Quin R. S.; Schaef, H. Todd; Kaszuba, John P. Environmental Science & Technology Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acs.estlett.9b00301	journal	July 2019
Dissolution Anisotropy of Pyroxenes: A Surrogate Model for Steady-State Enstatite Dissolution Resulting from Stochastic Simulations of the Hydrolysis Process Bouissonnié, Arnaud; Daval, Damien; Ackerer, Philippe The Journal of Physical Chemistry C, Vol. 124, Issue 24 https://doi.org/10.1021/acs.jpcc.0c00962	journal	May 2020
Dissolution Anisotropy of Pyroxenes: Role of Edges and Corners Inferred from Stochastic Simulations of Enstatite Dissolution Bouissonnié, Arnaud; Daval, Damien; Ackerer, Philippe The Journal of Physical Chemistry C, Vol. 125, Issue 14 https://doi.org/10.1021/acs.jpcc.0c11416	journal	April 2021
Surface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films Miller, Quin R. S.; Dixon, David A.; Burton, Sarah D. The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.9b02215	journal	May 2019
Physical Properties of Interfacial Layers Developed on Weathered Silicates: A Case Study Based on Labradorite Feldspar Wild, Bastien; Daval, Damien; Micha, Jean-Sébastien The Journal of Physical Chemistry C, Vol. 123, Issue 40 https://doi.org/10.1021/acs.jpcc.9b05491	journal	October 2019
The Dissolution Anisotropy of Pyroxenes: Experimental Validation of a Stochastic Dissolution Model Based on Enstatite Dissolution Bouissonnié, Arnaud; Daval, Damien; Guyot, François The Journal of Physical Chemistry C, Vol. 124, Issue 5 https://doi.org/10.1021/acs.jpcc.9b10824	journal	January 2020
Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films Miller, Quin R. S.; Ilton, Eugene S.; Qafoku, Odeta The Journal of Physical Chemistry Letters, Vol. 9, Issue 17 https://doi.org/10.1021/acs.jpclett.8b02162	journal	August 2018
Evidence for Carbonate Surface Complexation during Forsterite Carbonation in Wet Supercritical Carbon Dioxide Loring, John S.; Chen, Jeffrey; Bénézeth, Pascale Langmuir, Vol. 31, Issue 27 https://doi.org/10.1021/acs.langmuir.5b01052	journal	July 2015
Pore-Scale Microenvironments Control Anthropogenic Carbon Mineralization Outcomes in Basalt Depp, Charles T.; Miller, Quin R. S.; Crum, Jarrod V. ACS Earth and Space Chemistry, Vol. 6, Issue 12 https://doi.org/10.1021/acsearthspacechem.2c00165	journal	November 2022
Carbon Mineralization and Critical Mineral Resource Evaluation Pathways for Mafic–Ultramafic Assets Stanfield, C. Heath; Miller, Quin R. S.; Battu, Anil K. ACS Earth and Space Chemistry, Vol. 8, Issue 6 https://doi.org/10.1021/acsearthspacechem.4c00005	journal	May 2024
Water Vapor Pressure Dependence of Crystallization Kinetics of Amorphous Forsterite Yamamoto, Daiki; Tachibana, Shogo ACS Earth and Space Chemistry, Vol. 2, Issue 8 https://doi.org/10.1021/acsearthspacechem.8b00047	journal	June 2018
Structure and Properties of Nanosilicates with Olivine (Mg ₂ SiO ₄ ) _N and Pyroxene (MgSiO ₃ ) _N Compositions Escatllar, Antoni Macià; Lazaukas, Tomas; Woodley, Scott M. ACS Earth and Space Chemistry, Vol. 3, Issue 11 https://doi.org/10.1021/acsearthspacechem.9b00139	journal	July 2019
On the Surface Acid–Base Properties of Amorphous and Crystalline Mg₂SiO₄ as Probed by Adsorbed CO, CO₂, and CD₃CN Signorile, Matteo; Zamirri, Lorenzo; Tsuchiyama, Akira ACS Earth and Space Chemistry, Vol. 4, Issue 3 https://doi.org/10.1021/acsearthspacechem.9b00271	journal	February 2020
Carbon Mineralization in Reactive Silicate Zones Menefee, Anne H.; Ellis, Brian R. ACS ES&T Engineering, Vol. 1, Issue 8 https://doi.org/10.1021/acsestengg.1c00066	journal	May 2021
Integrated Recovery of Iron and Nickel from Olivine Ores Using Solvent Extraction: Synergistic Production of Amorphous Silica and Carbonates through pH Adjustment and Carbon Mineralization Zhang, Ning; Yang, Ruoxi; Huang, Haonan Danny ACS ES&T Engineering, Vol. 5, Issue 1 https://doi.org/10.1021/acsestengg.4c00462	journal	September 2024
Technoeconomic Potential for Carbon Mineralization with Enhanced Recovery of Critical Minerals in the Pacific Northwest Jacobs, Joseph E.; Stanfield, C. Heath; Miller, Quin R. S. ACS Sustainable Resource Management, Vol. 2, Issue 5 https://doi.org/10.1021/acssusresmgt.4c00541	journal	April 2025
Optimized Carbonation of Magnesium Silicate Mineral for CO ₂ Storage Eikeland, Espen; Blichfeld, Anders Bank; Tyrsted, Christoffer ACS Applied Materials & Interfaces, Vol. 7, Issue 9 https://doi.org/10.1021/am508432w	journal	February 2015
On the Bimodal Effects of Silicic Acids on Calcite Growth Pina, Carlos M.; Merkel, Casjen; Jordan, Guntram Crystal Growth & Design, Vol. 9, Issue 9 https://doi.org/10.1021/cg900333z	journal	July 2009
Surface Chemistry and Dissolution Kinetics of Divalent Metal Carbonates Pokrovsky, O. S.; Schott, J. Environmental Science & Technology, Vol. 36, Issue 3 https://doi.org/10.1021/es010925u	journal	February 2002
Carbon Sequestration via Aqueous Olivine Mineral Carbonation: Role of Passivating Layer Formation Béarat, Hamdallah; McKelvy, Michael J.; Chizmeshya, Andrew V. G. Environmental Science & Technology, Vol. 40, Issue 15 https://doi.org/10.1021/es0523340	journal	August 2006
Ex Situ Aqueous Mineral Carbonation Gerdemann, Stephen J.; O'Connor, William K.; Dahlin, David C. Environmental Science & Technology, Vol. 41, Issue 7 https://doi.org/10.1021/es0619253	journal	April 2007
In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO ₂ Loring, John S.; Thompson, Christopher J.; Wang, Zheming Environmental Science & Technology, Vol. 45, Issue 14 https://doi.org/10.1021/es201284e	journal	July 2011
Forsterite [Mg ₂ SiO ₄ )] Carbonation in Wet Supercritical CO ₂ : An in Situ High-Pressure X-ray Diffraction Study Todd Schaef, Herbert; McGrail, Bernard P.; Loring, John L. Environmental Science & Technology, Vol. 47, Issue 1 https://doi.org/10.1021/es301126f	journal	June 2012
Co-Location of Air Capture, Subseafloor CO ₂ Sequestration, and Energy Production on the Kerguelen Plateau Goldberg, David S.; Lackner, Klaus S.; Han, Patrick Environmental Science & Technology, Vol. 47, Issue 13 https://doi.org/10.1021/es401531y	journal	June 2013
Enhanced Olivine Carbonation within a Basalt as Compared to Single-Phase Experiments: Reevaluating the Potential of CO ₂ Mineral Sequestration Sissmann, Olivier; Brunet, Fabrice; Martinez, Isabelle Environmental Science & Technology, Vol. 48, Issue 10 https://doi.org/10.1021/es405508a	journal	May 2014
Impacts of Organic Ligands on Forsterite Reactivity in Supercritical CO ₂ Fluids Miller, Quin R. S.; Kaszuba, John P.; Schaef, Herbert T. Environmental Science & Technology, Vol. 49, Issue 7 https://doi.org/10.1021/es506065d	journal	March 2015
Experimental Study of Carbon Sequestration Reactions Controlled by the Percolation of CO ₂ -Rich Brine through Peridotites Andreani, M.; Luquot, L.; Gouze, P. Environmental Science & Technology, Vol. 43, Issue 4 https://doi.org/10.1021/es8018429	journal	February 2009
Effect of Secondary Phase Formation on the Carbonation of Olivine King, Helen E.; Plümper, Oliver; Putnis, Andrew Environmental Science & Technology, Vol. 44, Issue 16 https://doi.org/10.1021/es9038193	journal	August 2010
Molecular Intermediate in the Directed Formation of a Zeolitic Metal–Organic Framework Sinnwell, Michael A.; Miller, Quin R. S.; Palys, Lauren Journal of the American Chemical Society, Vol. 142, Issue 41 https://doi.org/10.1021/jacs.0c07862	journal	September 2020
Mechanical Activation of Diopside in CO2 Kalinkin, A. M.; Politov, A. A.; Boldyrev, V. V. Inorganic Materials, Vol. 38, Issue 2, p. 163-167 https://doi.org/10.1023/A:1014021312359	journal	February 2002
Potential for carbon dioxide sequestration in flood basalts: SEQUESTRATION IN FLOOD BASALTS McGrail, B. Peter; Schaef, H. Todd; Ho, Anita M. Journal of Geophysical Research: Solid Earth, Vol. 111, Issue B12 https://doi.org/10.1029/2005JB004169	journal	December 2006
Carbonate control of H₂and CH₄production in serpentinization systems at elevated P-Ts Jones, L. Camille; Rosenbauer, Robert; Goldsmith, Jonas I. Geophysical Research Letters, Vol. 37, Issue 14 https://doi.org/10.1029/2010GL043769	journal	July 2010
Ultramafic Rock Carbonation: Constraints From Listvenite Core BT1B, Oman Drilling Project Beinlich, A.; Plümper, O.; Boter, E. Journal of Geophysical Research: Solid Earth, Vol. 125, Issue 6 https://doi.org/10.1029/2019JB019060	journal	June 2020
A Mg Isotopic Perspective on the Mobility of Magnesium During Serpentinization and Carbonation of the Oman Ophiolite de Obeso, Juan Carlos; Santiago Ramos, Danielle P.; Higgins, John A. Journal of Geophysical Research: Solid Earth, Vol. 126, Issue 2 https://doi.org/10.1029/2020JB020237	journal	February 2021
Kinetics and Mechanisms of Acid‐pH Weathering of Pyroxenes Monasterio‐Guillot, L.; Rodriguez‐Navarro, C.; Ruiz‐Agudo, E. Geochemistry, Geophysics, Geosystems, Vol. 22, Issue 11 https://doi.org/10.1029/2021GC009711	journal	October 2021
Nutrient Supply to Planetary Biospheres From Anoxic Weathering of Mafic Oceanic Crust Syverson, D. D.; Reinhard, C. T.; Isson, T. T. Geophysical Research Letters, Vol. 48, Issue 19 https://doi.org/10.1029/2021GL094442	journal	October 2021
Major Mineral Fraction and Physical Properties of Carbonated Peridotite (Listvenite) From ICDP Oman Drilling Project Hole BT1B Inferred From X‐Ray CT Core Images Okazaki, Keishi; Michibayashi, Katsuyoshi; Hatakeyama, Kohei Journal of Geophysical Research: Solid Earth, Vol. 126, Issue 12 https://doi.org/10.1029/2021JB022719	journal	November 2021
Mechanism of diopside dissolution from hydrogen depth profiling Petit, Jean-Claude; Delia Mea, Gianantonio; Dran, Jean-Claude Nature, Vol. 325, Issue 6106 https://doi.org/10.1038/325705a0	journal	February 1987
Leaching and reconstruction at the surfaces of dissolving chain-silicate minerals Casey, William H.; Westrich, Henry R.; Banfield, Jillian F. Nature, Vol. 366, Issue 6452 https://doi.org/10.1038/366253a0	journal	November 1993
High-temperature water–rock interactions and hydrothermal environments in the chondrite-like core of Enceladus Sekine, Yasuhito; Shibuya, Takazo; Postberg, Frank Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9604	journal	October 2015
Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation Matter, Jürg M.; Kelemen, Peter B. Nature Geoscience, Vol. 2, Issue 12 https://doi.org/10.1038/ngeo683	journal	November 2009
Multi-scale magnetic mapping of serpentinite carbonation Tominaga, Masako; Beinlich, Andreas; Lima, Eduardo A. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01610-4	journal	November 2017
A comparative study of the dissolution mechanisms of amorphous and crystalline feldspars at acidic pH conditions Cagnon, Benjamin; Daval, Damien; Cabié, Martiane npj Materials Degradation, Vol. 6, Issue 1 https://doi.org/10.1038/s41529-022-00240-6	journal	April 2022
Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films Abdolhosseini Qomi, M. J.; Miller, Q. R. S.; Zare, S. Nature Reviews Chemistry, Vol. 6, Issue 9 https://doi.org/10.1038/s41570-022-00418-1	journal	August 2022
Carbon dioxide storage through mineral carbonation Snæbjörnsdóttir, Sandra Ó.; Sigfússon, Bergur; Marieni, Chiara Nature Reviews Earth & Environment, Vol. 1, Issue 2 https://doi.org/10.1038/s43017-019-0011-8	journal	January 2020
Anomalously low activation energy of nanoconfined MgCO ₃ precipitation Miller, Quin R. S.; Kaszuba, John P.; Schaef, Herbert T. Chemical Communications, Vol. 55, Issue 48 https://doi.org/10.1039/C9CC01337G	journal	January 2019
Emerging investigator series: ion diffusivities in nanoconfined interfacial water films contribute to mineral carbonation thresholds Miller, Quin R. S.; Kaszuba, John P.; Kerisit, Sebastien N. Environmental Science: Nano, Vol. 7, Issue 4 https://doi.org/10.1039/C9EN01382B	journal	January 2020
Low temperature and limited water activity reveal a pathway to magnesite via amorphous magnesium carbonate Mergelsberg, Sebastian T.; Kerisit, Sebastien N.; Ilton, Eugene S. Chemical Communications, Vol. 56, Issue 81 https://doi.org/10.1039/D0CC04907G	journal	January 2020
Activation energy of magnesite (MgCO₃) precipitation: recent insights from olivine carbonation studies Miller, Quin R. S.; Schaef, H. Todd Environmental Science: Advances, Vol. 1, Issue 4 https://doi.org/10.1039/D2VA00066K	journal	January 2022
Mechanistic insights into the co-recovery of nickel and iron via integrated carbon mineralization of serpentinized peridotite by harnessing organic ligands Katre, Shreya; Ochonma, Prince; Asgar, Hassnain Physical Chemistry Chemical Physics, Vol. 26, Issue 12 https://doi.org/10.1039/D3CP04996E	journal	January 2024
Emerging investigator series: kinetics of diopside reactivity for carbon mineralization in mafic–ultramafic rocks Aguila, Briana; Hardee, Landon; Schaef, H. Todd Environmental Science: Nano, Vol. 10, Issue 10 https://doi.org/10.1039/D3EN00087G	journal	January 2023
Chemical and morphological changes during olivine carbonation for CO2 storage in the presence of NaCl and NaHCO3 Gadikota, Greeshma; Matter, Juerg; Kelemen, Peter Physical Chemistry Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1039/c3cp54903h	journal	January 2014
XANES spectra of forsterite in crystal, surface, and amorphous states Takahashi, Osamu; Tamenori, Yusuke; Suenaga, Taiga AIP Advances, Vol. 8, Issue 2 https://doi.org/10.1063/1.5017245	journal	February 2018
A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa Span, Roland; Wagner, Wolfgang Journal of Physical and Chemical Reference Data, Vol. 25, Issue 6 https://doi.org/10.1063/1.555991	journal	November 1996
Carbon dioxide sequestration in deep-sea basalt Goldberg, D. S.; Takahashi, T.; Slagle, A. L. Proceedings of the National Academy of Sciences, Vol. 105, Issue 29 https://doi.org/10.1073/pnas.0804397105	journal	July 2008
In situ carbonation of peridotite for CO2 storage Kelemen, P. B.; Matter, J. Proceedings of the National Academy of Sciences, Vol. 105, Issue 45 https://doi.org/10.1073/pnas.0805794105	journal	November 2008
Potential on-shore and off-shore reservoirs for CO2 sequestration in Central Atlantic magmatic province basalts Goldberg, D. S.; Kent, D. V.; Olsen, P. E. Proceedings of the National Academy of Sciences, Vol. 107, Issue 4 https://doi.org/10.1073/pnas.0913721107	journal	January 2010
Carbon mineralization with concurrent critical metal recovery from olivine Wang, Fei; Dreisinger, David Proceedings of the National Academy of Sciences, Vol. 119, Issue 32 https://doi.org/10.1073/pnas.2203937119	journal	August 2022
Fizzy ore processing sequesters CO ₂ while supplying critical metals Wilson, Sasha; Hamilton, Jessica L. Proceedings of the National Academy of Sciences, Vol. 119, Issue 39 https://doi.org/10.1073/pnas.2212424119	journal	September 2022
Crystallization Experiments on Amorphous Magnesium Silicate. i. Estimation of the Activation Energy of Enstatite Crystallization Murata, K.; Chihara, H.; Koike, C. The Astrophysical Journal, Vol. 697, Issue 1 https://doi.org/10.1088/0004-637X/697/1/836	journal	May 2009
Crystallization Experiments on Amorphous Magnesium Silicate. ii. Effect of Stacking Faults on Infrared Spectra of Enstatite Murata, K.; Chihara, H.; Koike, C. The Astrophysical Journal, Vol. 698, Issue 2 https://doi.org/10.1088/0004-637X/698/2/1903	journal	June 2009
Evidence from ²⁹ Si Solid-State Nuclear Magnetic Resonance of Dissolution Reactions of Forsterite Cui, Jinlei; Sesti, Erika L.; Moore, Jeremy K. Environmental Engineering Science, Vol. 33, Issue 10 https://doi.org/10.1089/ees.2016.0004	journal	October 2016
Survivability of presolar oxygen isotopic signature of amorphous silicate dust in the protosolar disk Yamamoto, Daiki; Tachibana, Shogo; Kawasaki, Noriyuki Meteoritics & Planetary Science, Vol. 55, Issue 6 https://doi.org/10.1111/maps.13365	journal	August 2019
Dissolution of Pyroxenes and Amphiboles During Weathering Berner, Robert A.; Sjöberg, E. L.; Velbel, Michael A. Science, Vol. 207, Issue 4436 https://doi.org/10.1126/science.207.4436.1205	journal	March 1980
Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions Matter, J. M.; Stute, M.; Snaebjornsdottir, S. O. Science, Vol. 352, Issue 6291 https://doi.org/10.1126/science.aad8132	journal	June 2016
Susceptibility of mineral phases of steel slags towards carbonation: mineralogical, morphological and chemical assessment [Susceptibility of mineral phases of steel slags towards carbonation: mineralogical, morphological and chemical assessment] Bodor, Marius; Santos, Rafael M.; Kriskova, Lubica European Journal of Mineralogy, Vol. 25, Issue 4 https://doi.org/10.1127/0935-1221/2013/0025-2300	journal	December 2013
Rates and Mechanisms of Mineral Carbonation in Peridotite: Natural Processes and Recipes for Enhanced, in situ CO ₂ Capture and Storage Kelemen, Peter B.; Matter, Juerg; Streit, Elisabeth E. Annual Review of Earth and Planetary Sciences, Vol. 39, Issue 1 https://doi.org/10.1146/annurev-earth-092010-152509	journal	May 2011
Dissolution of diopside and basaltic glass: the effect of carbonate coating Stockmann, G.; Wolff-Boenisch, D.; Gíslason, S. R. Mineralogical Magazine, Vol. 72, Issue 1 https://doi.org/10.1180/minmag.2008.072.1.135	journal	February 2008
Effect of solution saturation state and temperature on diopside dissolution Dixit, Suvasis; Carroll, Susan A. Geochemical Transactions, Vol. 8, Issue 1 https://doi.org/10.1186/1467-4866-8-3	journal	March 2007
Prevention experiences (pre-treatment with drugs) and/or follow-up/ Esperienze di prevenzione (pre-trattamento con farmaci) e/o follow-up Aa Vv, Aa Vv Dental Cadmos, Vol. 01, Issue 01 https://doi.org/10.19256/abstract.ONJ.03.2024	journal	March 2024
Mineral Carbonation of CO2 Oelkers, E. H.; Gislason, S. R.; Matter, J. Elements, Vol. 4, Issue 5 https://doi.org/10.2113/gselements.4.5.333	journal	October 2008
Mineralogical evolution of Fe–Si-rich layers at the olivine-water interface during carbonation reactions Saldi, Giuseppe D.; Daval, Damien; Guo, Hua American Mineralogist, Vol. 100, Issue 11-12 https://doi.org/10.2138/am-2015-5340	journal	November 2015
Field-based accounting of CO ₂ sequestration in ultramafic mine wastes using portable X-ray diffraction Turvey, Connor C.; Wilson, Siobhan A.; Hamilton, Jessica L. American Mineralogist, Vol. 102, Issue 6 https://doi.org/10.2138/am-2017-5953	journal	June 2017
Continuous time-resolved X-ray diffraction of the biocatalyzed reduction of Mn oxide Fischer, T. B.; Heaney, P. J.; Jang, J. -H. American Mineralogist, Vol. 93, Issue 11-12 https://doi.org/10.2138/am.2008.3038	journal	November 2008
A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling Palandri, James L.; Kharaka, Yousif K. U.S. Geological Survey (USGS) https://doi.org/10.3133/ofr20041068	report	January 2004
Synthetic Fluid Inclusions XXIV. In situ Monitoring of the Carbonation of Olivine Under Conditions Relevant to Carbon Capture and Storage Using Synthetic Fluid Inclusion Micro-Reactors: Determination of Reaction Rates Sendula, Eszter; Lamadrid, Héctor M.; Rimstidt, J. Donald Frontiers in Climate, Vol. 3 https://doi.org/10.3389/fclim.2021.722447	journal	October 2021
An Experimental Study of the Carbonation of Serpentinite and Partially Serpentinised Peridotites Lacinska, Alicja M.; Styles, Michael T.; Bateman, Keith Frontiers in Earth Science, Vol. 5 https://doi.org/10.3389/feart.2017.00037	journal	June 2017
Nickel Extraction from Olivine: Effect of Carbonation Pre-Treatment Santos, Rafael; Van Audenaerde, Aldo; Chiang, Yi Metals, Vol. 5, Issue 3 https://doi.org/10.3390/met5031620	journal	September 2015
Experimental Investigation and Simplistic Geochemical Modeling of CO2 Mineral Carbonation Using the Mount Tawai Peridotite Rahmani, Omeid; Highfield, James; Junin, Radzuan Molecules, Vol. 21, Issue 3 https://doi.org/10.3390/molecules21030353	journal	March 2016
Valorisation of mine waste as carbon mineralisation feedstock Gazzetti, Edward; Bandstra, Jz; Diedrich, Tr Proceedings of the International Conference on Mine Closure https://doi.org/10.36487/ACG_repo/2315_094	conference	January 2023
Exposure Experiments of Amorphous Silicates and Organics to Cometary Ice and Vapor Analogs Takigawa, Aki; Furukawa, Yoshihiro; Kimura, Yuki The Astrophysical Journal, Vol. 881, Issue 1 https://doi.org/10.3847/1538-4357/ab27c6	journal	August 2019
Structural Characterization and Thermal Decomposition Behavior of Microsized and Nanosized CaCO₃ Yan-Jun, Tang; You-Ming, Li; Jing, Song Acta Physico-Chimica Sinica, Vol. 23, Issue 05 https://doi.org/10.3866/PKU.WHXB20070518	journal	January 2007
Pervasive carbonation of peridotite to listvenite (Semail Ophiolite, Sultanate of Oman): clues from iron partitioning and chemical zoning Decrausaz, Thierry; Godard, Marguerite; Menzel, Manuel D. European Journal of Mineralogy, Vol. 35, Issue 2 https://doi.org/10.5194/ejm-35-171-2023	journal	March 2023
Progressive veining during peridotite carbonation: insights from listvenites in Hole BT1B, Samail ophiolite (Oman) Menzel, Manuel D.; Urai, Janos L.; Ukar, Estibalitz Solid Earth, Vol. 13, Issue 8 https://doi.org/10.5194/se-13-1191-2022	journal	August 2022
Generating porosity during olivine carbonation via dissolution channels and expansion cracks Xing, Tiange; Zhu, Wenlu; Fusseis, Florian Solid Earth, Vol. 9, Issue 4 https://doi.org/10.5194/se-9-879-2018	journal	January 2018
Accelerating Mineral Carbonation in Ultramafic Mine Tailings via Direct CO2 Reaction and Heap Leaching with Potential for Base Metal Enrichment and Recovery Hamilton, Jessica L.; Wilson, Siobhan A.; Morgan, Bree Economic Geology, Vol. 115, Issue 2 https://doi.org/10.5382/econgeo.4710	journal	March 2020

Similar Records

An integrated experimental–modeling approach to identify key processes for carbon mineralization in fractured mafic and ultramafic rocks

Journal Article · Wed Sep 18 00:00:00 UTC 2024 · PNAS Nexus · OSTI ID:2447529

Neil, Chelsea Wren; Yang, Yun; Nisbet, Haylea Dawn; +6 more

Carbon Mineralization in Fractured Mafic and Ultramafic Rocks: A Review

Journal Article · Sun Nov 17 00:00:00 UTC 2024 · Reviews of Geophysics (1985) · OSTI ID:2477709

Nisbet, H.; Buscarnera, G.; Carey, J. W.; +16 more

Subsurface mafic and ultramafic rock mapping and analysis for carbon mineralization in the United States (SubMAP-CO₂)

Technical Report · Wed Apr 29 00:00:00 UTC 2026 · OSTI ID:3101845

Ukar, Estibalitz

Related Subjects

basalt
glass dissolution
hydromagnesite
interfacial water film
mafic-ultramafic
peridotite
pyroxene

Title: Interfacial Hydrophilicity Controls Mineral Transformation Outcomes for Enstatite and Amorphous MgSiO3

Citation Formats

References (200)

Similar Records

Related Subjects

Title: Interfacial Hydrophilicity Controls Mineral Transformation Outcomes for Enstatite and Amorphous MgSiO₃