Probing Surface/Bulk Structural Chemistry of Key Components of Solid Oxide Electrochemical Cells with In Situ/Operando Raman Spectroscopy

Kumar, Neelesh; Najimu, Musa O.; Cho, Yoon Jin; Gilliard-AbdulAziz, Kandis Leslie; Nikolla, Eranda; Wu, Zili; Wachs, Israel E.

doi:10.1021/acs.chemrev.5c00222

Title: Probing Surface/Bulk Structural Chemistry of Key Components of Solid Oxide Electrochemical Cells with In Situ/Operando Raman Spectroscopy

Journal Article · Thu Aug 28 00:00:00 UTC 2025 · Chemical Reviews

DOI: https://doi.org/10.1021/acs.chemrev.5c00222 · OSTI ID:2997752

^[1]; Najimu, Musa O. ^[2];

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Lehigh Univ., Bethlehem, PA (United States)
Univ. of Southern California, Los Angeles, CA (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

The remarkable attributes of solid oxide electrochemical cell technology (e.g., energy efficiency, low cost, scalability, low emissions, and operational flexibility, etc.) drive the wider adoption of electrochemical conversion routes for sustainability. It is critical for the codevelopment of solid oxide cell materials and processes to establish the mechanistic understanding of the underlying chemical phenomena at the molecular level. Herein, we summarize the advancements in Raman spectroscopy that provide structural/molecular information on electrode/electrolyte materials typically used in solid oxide cells for energy conversion. In particular, we discuss the multifactorial environment induced chemical processes that govern the performance and longevity of solid oxide electrochemical devices. The in situ/operando Raman spectroscopic investigations on the electrode/electrolyte materials reported in the literature are summarized with the emphasis on identification of key material properties that control the functional aspects of the solid oxide cells. The molecular level understanding of the electrochemical processes will allow advancement of the rational design of electrochemical materials for process level deployment of solid oxide cell technology.

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Research Organization:: American Chemical Society (ACS-C), Washington, DC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012577

OSTI ID:: 2997752

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 18 Vol. 125; ISSN 1520-6890; ISSN 0009-2665

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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